The Rich Inner Life of the Hydrogen ChainA one-dimensional chain of hydrogen atoms displays a wide variety of many-body effects-suggesting that the chain can be a useful model system for condensed-matter physics.
Condensed matter physics is a rich field with a wide variety of phenomena. In condensed matter, we consider systems composed of many electrons and nuclei, with the only fundamental interaction being electromagnetism. Nuclei of a given charge and mass are considered as point particles. The relevant fundamental physics that we use as our foundations is the quantum many-body problem. That is, just standard many-body quantum mechanics, but formulated in terms of a useful second quantized field theory, which can deal with an arbitrary number of particles within a single Hilbert space. In general, this many-body problem is essentially intractable for numbers of particles as large as those we must consider for materials. Thus we must look for simplifications and look at easily measurable aspects which allow us to make predictions still. We employ the trick of phrasing the questions differently. Rather than look at the time evolution of an arbitrary many-body wavefunction for the fundamental degrees of freedom, we look at transport in scenarios where the starting point is a relatively simple assumed equilibrium state of the material, consisting of a ground state with postulated quasiparticle excitations.
Accurate and predictive computations of the quantum-mechanical behavior of many interacting electrons in realistic atomic environments are critical for the theoretical design of materials with desired properties, and they require solving the grand-challenge problem of the many-electron Schrödinger equation.An infinite chain of equispaced hydrogen atoms is perhaps the simplest realistic model for a bulk material, embodying several central themes of modern condensed-matter physics and chemistry while retaining a connection to the paradigmatic Hubbard model.Here, we report a combined application of cutting-edge computational methods to determine the properties of the hydrogen chain in its quantummechanical ground state.Varying the separation between the nuclei leads to a rich phase diagram, including a Mott phase with quasi-long-range antiferromagnetic order, electron density dimerization with power-law correlations, an insulator-to-metal transition, and an intricate set of intertwined magnetic orders.
The thermalization of isolated quantum many-body systems is deeply related to fundamental questions of quantum information theory. While integrable or many-body localized systems display non-ergodic behavior due to extensively many conserved quantities, recent theoretical studies have identified a rich variety of more exotic phenomena in between these two extreme limits. The tilted one-dimensional Fermi-Hubbard model, which is readily accessible in experiments with ultracold atoms, emerged as an intriguing playground to study non-ergodic behavior in a clean disorder-free system. While non-ergodic behavior was established theoretically in certain limiting cases, there is no complete understanding of the complex thermalization properties of this model. In this work, we experimentally study the relaxation of an initial charge-density wave and find a remarkably long-lived initial-state memory over a wide range of parameters. Our observations are well reproduced by numerical simulations of a clean system. Using analytical calculations we further provide a detailed microscopic understanding of this behavior, which can be attributed to emergent kinetic constraints.