The following dissertation consists of three parts. The first two concern ground - state properties of one - dimensional matter, while the third describes an experimental realization of the Zel'dovich effect in Rydberg atoms. Motivated by emerging experimental possibilities to confine atoms and molecules in quasi - one -dimensional geometries, in Chapters 1 and 2 we analyze ground - state properties of strictly onedimensional molecular matter comprised of identical particles of mass m interacting by a Morse potential between nearest neighbors. We find that due to zero - point motion, the system first undergoes a discontinuous evaporation transition into a diatomic gas followed by a continuous dissociation transition into a monoatomic gas. In particular we find that spin - polarized isotopes of hydrogen and 3He are monoatomic gases, 4H6 is a diatomic gas, while molecular hydrogen and heavier substances are Luttinger liquids. We also investigate the effect of finite pressure on the properties of the liquid and monoatomic gas phases. In particular we estimate a pressure at which molecular hydrogen undergoes an inverse Peierls transition into a metallic state which is a one - dimensional analog of the transition predicted by Wigner and Huntington in 1935. In Chapter 2, we show that dissociar tion of the Luttinger liquid is a process initiated at the system edge. The latter becomes unstable against quantum fluctuations at a value of De Boer's number which is smaller than that of the bulk instability which parallels the classical phenomenon of surface melting. In 1959 Ya. B. Zel'dovich predicted that the bound - state spectrum of the non - relativistic Coulomb problem distorted at small distances by a short - range potential undergoes a peculiar reconstruction whenever this potential alone supports a low - energy scattering resonance. However documented experimental evidence of this effect has been lacking. In Chapter 3 we demonstrate that along the Periodic Table of elements the Zel'dovich effect manifests itself as a systematic periodic variation of the Rydberg spectra with a period proportional to the cubic root of the atomic number. This dependence, which is supported by analysis of experimental and numerical data, has its origin in the binding properties of the ionic core of the atom. Note: Abstract extracted from PDF file via OCR
The following dissertation consists of three parts. The first two concern ground - state properties of one - dimensional matter, while the third describes an experimental realization of the Zel'dovich effect in Rydberg atoms. Motivated by emerging experimental possibilities to confine atoms and molecules in quasi - one -dimensional geometries, in Chapters 1 and 2 we analyze ground - state properties of strictly onedimensional molecular matter comprised of identical particles of mass m interacting by a Morse potential between nearest neighbors. We find that due to zero - point motion, the system first undergoes a discontinuous evaporation transition into a diatomic gas followed by a continuous dissociation transition into a monoatomic gas. In particular we find that spin - polarized isotopes of hydrogen and 3He are monoatomic gases, 4H6 is a diatomic gas, while molecular hydrogen and heavier substances are Luttinger liquids. We also investigate the effect of finite pressure on the properties of the liquid and monoatomic gas phases. In particular we estimate a pressure at which molecular hydrogen undergoes an inverse Peierls transition into a metallic state which is a one - dimensional analog of the transition predicted by Wigner and Huntington in 1935. In Chapter 2, we show that dissociar tion of the Luttinger liquid is a process initiated at the system edge. The latter becomes unstable against quantum fluctuations at a value of De Boer's number which is smaller than that of the bulk instability which parallels the classical phenomenon of surface melting. In 1959 Ya. B. Zel'dovich predicted that the bound - state spectrum of the non - relativistic Coulomb problem distorted at small distances by a short - range potential undergoes a peculiar reconstruction whenever this potential alone supports a low - energy scattering resonance. However documented experimental evidence of this effect has been lacking. In Chapter 3 we demonstrate that along the Periodic Table of elements the Zel'dovich effect manifests itself as a systematic periodic variation of the Rydberg spectra with a period proportional to the cubic root of the atomic number. This dependence, which is supported by analysis of experimental and numerical data, has its origin in the binding properties of the ionic core of the atom. Note: Abstract extracted from PDF file via OCR
Motivated by emerging experimental possibilities to confine atoms and molecules in quasi-one-dimensional geometries, we analyze ground-state properties of strictly one-dimensional molecular matter comprised of identical particles of mass m. Such a class of systems can be described by an additive two-body potential whose functional form is common to all substances which only differ in the energy $\ensuremath{\epsilon}$ and range l scales of the potential. With this choice De Boer's quantum theorem of corresponding states holds and the ground-state properties expressed in appropriate reduced form are only determined by the dimensionless parameter ${\ensuremath{\lambda}}_{0}^{2}\ensuremath{\sim}{\ensuremath{\Elzxh}}^{2}{/ml}^{2}\ensuremath{\epsilon},$ measuring the strength of zero-point motion in the system. The presence of a minimum in the two-body interaction potential leads to a many-body bound state which is a Luttinger liquid stable for not very large ${\ensuremath{\lambda}}_{0}.$ As ${\ensuremath{\lambda}}_{0}$ increases, the asymmetry of the two-body potential causes quantum expansion, softening, and eventual evaporation of the Luttinger liquid into a gas phase. Selecting the pair interaction potential in the Morse form we analytically compute the properties of the Luttinger liquid and its range of existence. We find that as ${\ensuremath{\lambda}}_{0}$ increases, the system first undergoes a discontinuous evaporation transition into a diatomic gas followed by a continuous dissociation transition into a monoatomic gas. In particular we find that spin-polarized isotopes of hydrogen and 3He are monoatomic gases, 4He is a diatomic gas, while molecular hydrogen and heavier substances are Luttinger liquids. We also investigate the effect of finite pressure on the properties of the liquid- and monoatomic gas phases. In particular we estimate a pressure at which molecular hydrogen undergoes an inverse Peierls transition into a metallic state which is a one-dimensional analog of the transition predicted by Wigner and Huntington in 1935 [E. Wigner and H.B. Huntington, J. Chem Phys. 3, 764 (1935)].
Combining ultracold atomic gases with the peculiar properties of Rydberg excited atoms gained a lot of theoretical and experimental attention in recent years. Embedded in the ultracold gas, an interaction between the Rydberg atom and the surrounding ground state atoms arises through the scattering of the Rydberg electron from an intruding perturber atom. This peculiar interaction gives rise to a plenitude of previously unobserved effects. Within the framework of the present thesis, this interaction is studied in detail for Rydberg P-states in rubidium. Due to their long lifetime, atoms in Rydberg states are subject to scattering with the surrounding ground state atoms in the ultracold cloud. By measuring their lifetime as a function of the ground state atom flux, we are able to obtain the total inelastic scattering cross section as well as the partial cross section for associative ionisation. The fact that the latter is three orders of magnitude larger than the size of the formed molecular ion indicates the presence of an efficient mass transport mechanism that is mediated by the Rydberg–ground state interaction. The immense acceleration of the collisional process shows a close analogy to a catalytic process. The increase of the scattering cross section renders associative ionisation an important process that has to be considered for experiments in dense ultracold systems. The interaction of the Rydberg atom with a ground state perturber gives rise to a highly oscillatory potential that supports molecular bound states. These so-called ultralong-range Rydberg molecules are studied with high resolution time-of-flight spectroscopy, where we are able to determine the binding energies and lifetimes of the molecular states between the two fine structure split 25P-states. Inside an electric field, we observe a broadening of the molecular lines that indicates the presence of a permanent electric dipole moment, induced by the mixing with high angular momentum states. Due to the mixing of the ground state atom’s hyperfine states by the molecular interaction, we are able to observe a spin-flip of the perturber upon creation of a Rydberg molecule. Furthermore, an incidental near-degeneracy in the underlying level scheme of the 25P-state gives rise to highly entangled states between the Rydberg fine structure state and the perturber’s hyperfine structure. These mechanisms can be used to manipulate the quantum state of a remote particle over distances that exceed by far the typical contact interaction range. Apart from the ultralong-range Rydberg molecules that predominantly consist of only one low angular momentum state, a class of Rydberg molecules is predicted to exist that strongly mixes the high angular momentum states of the degenerate hydrogenic manifolds. These states, the so-called trilobite- and butterfly Rydberg molecules, show very peculiar properties that cannot be observed for conventional molecules. Here we present the first experimental observation of butterfly Rydberg molecules. In addition to an extensive spectroscopy that reveals the binding energy, we are also able to observe the rotational structure of these exotic molecules. The arising pendular states inside an electric field allow us, in comparison to the model of a dipolar rotor, to extract the precise bond length and dipole moment of the molecule. With the information obtained in the present study, it is possible to photoassociate butterfly molecules with a selectable bond length, vibrational state, rotational state, and orientation inside an electric field. By shedding light on various previously unrevealed aspects, the experiments presented in this thesis significantly deepen our knowledge on the Rydberg–ground state interaction and the peculiar effects arising from it. The obtained spectroscopic information on Rydberg molecules and the changed reaction dynamics for molecular ion creation will surely provide valuable data for quantum chemical simulations and provide necessary data to plan future experiments. Beyond that, our study reveals that the hyperfine interaction in Rydberg molecules and the peculiar properties of butterfly states provide very promising new ways to alter the short- and long-range interactions in ultracold many-body systems. In this sense the investigated Rydberg–ground state interaction not only lies right at the interface between quantum chemistry, quantum many-body systems, and Rydberg physics, but also creates many new and fascinating possibilities by combining these fields.
The coherence of a quantum system is one of the key signatures of many-body physics. While a three-dimensional Bose-Einstein condensate (BEC) exhibits true long-range coherence, a Bose gas confined in a one-dimensional (1D) potential displays quasi-long-range order. Experimentally, these coherence properties are typically probed via the momentum distribution, which corresponds to the Fourier transform of the one-body correlation function. In two-dimensional (2D) systems, for example, momentum distribution enables the observation of the Berezinskii-Kosterlitz-Thouless (BKT) transition from a thermal cloud to a superfluid. With trimodal distribution fitting, an intermediate quasicondensate phase is also revealed. In 1D systems, the momentum distribution of a quenched Tonks-Girardeau (TG) Bose gas can be mapped to that of a non-interacting Fermi gas at a specific evolution time, achieving the rapidity distribution. On the other hand, spin-orbit coupling (SOC) has emerged as one of the central topics in ultracold atomic physics. In additional to creating an artificial electric or magnetic field, researchers also observe negative-mass dynamics in a spin-orbit-coupled BEC by engineering the curvature of the band dispersion. This phenomenon is directly observable in the density distribution of the system. In 1D systems, SOC also introduces rich physical phenomena; while low-energy 1D quantum systems are conventionally described by Tomonaga-Luttinger liquid (TLL) theory, SOC notably alters the energy-momentum dispersion. This modification gives rise to unconventional Luttinger liquids whose properties are governed by the spin-orbit coupling strength.In this work, we first investigate the qualitative properties of a 1D Bose gas and demonstrate the temperature dependence of the momentum distribution, revealing how the thermal fluctuations destroy the quasi-long-range order. In the second part, we probe the effects of 1D SOC on a 1D Bose gas, focusing on how SOC modifies the energy-momentum dispersion and the resulting momentum distribution. We demonstrate that within a specific parameter regime, the momentum distribution and its associated coherence properties undergo distinct qualitative changes. The occupied higher momentum states induce phase fluctuations and destroy the coherence of the system, showing signals of the non-Luttinger liquid physics. We probe the coherence properties of a 1D system along these two parameter axes.
In this dissertation I investigate cold Rydberg atoms and molecules in which the angular-momentum character of the quantum states involved strongly influences their properties and dynamics. In the first part I focus on long-range diatomic Rydberg molecules formed by a rubidium D-state Rydberg atom and a second rubidium atom in its ground state. Spectroscopic measurements of molecular binding energies are presented showing the effect of the Rydberg atom size and fine-structure coupling on the molecular potentials. A theoretical model is introduced that takes into account all relevant angular-momentum couplings between the molecular constituents, successfully reproducing experimental observations. Calculations of adiabatic potentials and binding energies, molecular-state lifetimes, electric and magnetic dipole moments are also presented. In the second part, I describe the production and magnetic trapping of cold circular Rydberg atoms. The circular Rydberg atoms are generated out of a cold gas of rubidium using the crossed-fields method and magnetically trapped. The trapping force is employed to induce center-of-mass oscillations of the trapped atom sample. Trap parameters and observed oscillation frequencies are used to measure the magnetic moments of the circular Rydberg atoms. Trap losses and the atomic internal-state evolution in the 300 Kelvin thermal background are also investigated.
This dissertation is devoted to theoretical studies of strongly interacting one-dimensional and quasi one-dimensional electron systems. The properties of one-dimensional electron systems can be studied within the bosonization technique, which presents fermions as collective bosonic density excitations. The power of this approach is the ability to treat electron-electron interaction exactly in the low-energy limit. The approach predicts the failure of Fermi liquid and an absence of long-range order in one-dimensions. The low-energy description of one-dimensional interacting systems is called the Tomonaga-Luttinger liquid theory. For example, the edges of quantum Hall systems are one-dimensional and described by a chiral Tomonaga-Luttinger liquid. Another example is a quantum spin Hall system with helical edge states, which are also described by a Tomonaga-Luttinger liquid. In our first work, a study of magnetized edge states of quantum spin-Hall system is presented. A magnetic field dependent signature of such edges is obtained, which can be verified in a Coulomb drag experiment. The second part of the dissertation is devoted to quasi-one dimensional antiferromagnetic lattices. A spatially anisotropic lattice antiferromagnet can be viewed as an array of one dimensional spin chains coupled in a way to match the lattice symmetry. This allows to use the non-Abelian bosonization technique to describe the low-energy physics of spin chains and study the inter-chain interactions perturbatively. The work presented in the dissertation studies the effect of Dzyaloshinskii-Moriya interaction on the magnetic phase diagram of the spatially anisotropic kagome antiferromagnet. We predict a Dzyaloshinskii-Moriya interaction driven phase transition from Neel to Neel+dimer state. In the third work, a novel model of the fractional quantum Hall effect is given. Wave functions of two-dimensional electrons in strong and quantizing magnetic field are essentially one-dimensional. That invites one to use the one-dimensional phenomenological bosonization to describe the density fluctuations of the two-dimensional interacting electrons in magnetic field. Remarkably, the constructed trial bosonized fermion operator describing the electron states with a fixed Landau gauge momentum is effectively two-dimensional.
The Schrödinger equation is nearly a century old, yet we are still in the midst of uncovering the remarkable phenomena emerging in many-body quantum systems. From superconductivity to anyonic quasiparticles, nature consistently surprises with its rich self-organization. To elucidate and grasp this variety, it is paramount to understand the phases of matter that can occur in many-body ground states, as well as their emergent collective excitations. Of particular interest are topological phases of matter, characterized by exotic excitations or edge phenomena. There exist by now several universal frameworks for gapped systems, i.e., those with an energy gap above the ground state. However, in the last decade, a multitude of gapless quantum wires---effectively one-dimensional systems---have been reported to be topologically non-trivial. A framework for their understanding and classification is missing. In addition to ground state order---topological or otherwise---a more complete picture involves the properties of excitations above the ground state. Alas, little is known about excitations beyond the universal low-energy regime. In part, this is due to a lack of analytical and numerical methods able to describe excitations at finite energies, especially in strongly-interacting systems beyond one dimension. In this thesis, we address these issues: firstly, we build a general understanding of topological phases in one dimension, including both gapped and gapless cases. In particular, we unify previously studied examples into a single framework. Secondly, we develop a novel numerical method for obtaining spectral functions in two dimensions---these give direct insight into the properties of excitations and are moreover experimentally measurable. Using this numerical method, we uncover a variety of robust properties of excitations at finite energies. Part I of this thesis concerns gapped and gapless topological phases in one dimension. In Chapter 2, we first treat the case of non-interacting fermions. Therein, we review the known classification of gapped phases before extending it to the gapless case, showing that exponentially-localized Majorana zero modes can still emerge at the edge when the bulk is gapless. Interacting gapped phases are discussed in Chapter 3, with a focus on symmetry-protected topological order. These have already been classified; our contribution is to provide a non-technical review of this classification as well as showing that many paradigmatic model Hamiltonians can be related to one another. Finally, Chapter 4 introduces the notion of symmetry-enriched quantum criticality, which we propose as a framework for classifying gapless phases. The key message is that in the presence of symmetries, a universality class can divide into distinct phases, characterized by the symmetry action on the low-energy scaling operators. This includes gapless topological phases, with examples hiding in plain sight; we clarify their stability and reinterpret previously studied examples. Part II studies the excitations above the ground states of two-dimensional quantum spin models. The main object of our study is the dynamic spin structure factor; this type of spectral function is reviewed in the first part of Chapter 5. The second part of this chapter introduces a novel matrix-product-state-based algorithm to efficiently compute it, opening a new window on the dynamics of two-dimensional quantum systems. We benchmark this numerical method in Chapter 6 on the exactly-solvable Kitaev model---a paradigmatic topological model realizing a quantum spin liquid. By adding non-integrable Heisenberg perturbations, we identify the first unequivocal theoretical realization of a proximate spin liquid: the ground state becomes conventionally ordered, yet the high-energy spectral properties are structurally similar to those of the nearby Kitaev spin liquid. The latter agrees with aspects of recent inelastic neutron scattering experiments on alpha-RuCl3. In Chapter 7, we turn to one of the oldest models in many-body quantum physics: the spin-1/2 Heisenberg antiferromagnet on the square lattice. Despite its venerable history, there is still disagreement about the physical origin of high-energy spectral features which low-order spin wave theory cannot account for. We provide a simple picture for this strongly-interacting-magnon feature by connecting it to a simple Ising limit. Lastly, Chapter 8 discusses the stability of quasiparticles---collective excitations behaving like a single emergent entity, of which magnons are a prime example. These are often known to be stable at the lowest energies and are presumed to decay whenever this is seemingly allowed by energy and momentum conservation. However, we show that strong interactions can prevent this from happening. We numerically confirm this principle of avoided decay in the (slightly-detuned) Heisenberg antiferromagnet on the triangular lattice. Moreover, we can even identify its fingerprints in existing experimental data on Ba3CoSb2O9 and superfluid helium. In this thesis, we thus enlarge our understanding of quantum phases and their excitations. The identification of the key principles of gapless topological phases in one dimension calls for direct analogues in higher dimensions, waiting to be uncovered. With regard to the robust properties of the excitations identified in this thesis, we are hopeful that these can be extended into a theory of quasiparticle properties away from the universal low-energy regime.