6. Spontaneous Emission, Stimulated Emission, and Absorption

Robert P. Davis

Hai-Woong Lee

Travis S. Taylor

This chapter discusses the details of what stimulated emission of radiation is, why it is the major physical phenomenon at the heart of the laser, and how it is exploited in ways to create laser light beams. It describes the Bohr model of the atom and how electrons can only make quantized leaps in energy levels from one atomic orbital or shell to the next. The chapter considers Pauli’s Exclusion Principle and singlet, doublet, and triplet states of the atom. It also describes the interaction of light with atoms through absorption, spontaneous emission, and stimulated emission. The chapter shows that the quantum mechanical harmonic oscillator and the ground state of the universe is a nonzero electromagnetic field and therefore is the trigger for spontaneous emission. It looks at the models for absorption, spontaneous and stimulated emission, and vibrational states.

Markus Pollnau

In the literature one finds several conflicting accounts of the phase difference of stimulated and spontaneous emission, as well as absorption, with respect to an existing (triggering) electromagnetic field. One of these approaches proposes that stimulated emission and absorption occur in phase and out of phase with their driving field, respectively, whereas spontaneous emission occurs under an arbitrary phase difference with respect to an existing field. It has served as a basis for explaining quantum-mechanically the laser linewidth, its narrowing by a factor of 2 around the laser threshold, as well as its broadening due to amplitude-phase coupling, resulting in Henry’s α-factor. Assuming the validity of Maxwell’s equations, all three processes would, thus, violate the law of energy conservation. In semi-classical approaches, we investigate stimulated emission in a Fabry-Pérot resonator, analyze the Lorentz oscillator model, apply the Kramers-Kronig relations to the complex susceptibility, understand the summation of quantized electric fields, and quantitatively interpret emission and absorption in the amplitude-phase diagram. In all cases, we derive that the phase of stimulated emission is 90o in lead of the driving field, and the phase of absorption lags 90o behind the transmitted field. Also spontaneous emission must obey energy conservation, hence it occurs with 90o phase in lead of an existing field. These semi-classical findings agree with recent experimental investigations regarding the interaction of attosecond pulses with an atom, thereby questioning the physical explanation of the laser linewidth and its narrowing or broadening.

H.-G. Unger