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University Chemistry

Boundary Conditions and Wave Functions of the Particle in a Box

Lan Chen, Hongwei Sun, Cheng-Ming LAI

Published Jan 1, 2017• 0 citations
Publisher
DOI
10.3866/pku.dxhx201608030

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In (1+1) space-time dimensions, we can have two particles that are Weyl and Majorana particles at the same time---1D Weyl-Majorana particles. That is, the right-chiral and left-chiral parts of the two-component Dirac wave function that satisfies the Majorana condition, in the Weyl representation, describe these particles, and each satisfies their own Majorana condition. Naturally, the nonzero component of each of these two two-component wave functions satisfies a Weyl equation. We investigate and discuss this issue and demonstrate that for a 1D Weyl-Majorana particle in a box, the nonzero components, and therefore the chiral wave functions, only admit the periodic and antiperiodic boundary conditions. From the latter two boundary conditions, we can only construct four boundary conditions for the entire Dirac wave function. Then, we demonstrate that these four boundary conditions are also included within the most general set of self-adjoint boundary conditions for a 1D Majorana particle in a box.
This chapter discusses the problem of one particle in a one-dimensional box free of the potential energy inside the box, that is, no external force is exerted on the particle inside the box. The corresponding Schrödinger equation is given along with the boundary conditions which yields an elliptic second-order differential equation and the solutions are given next: the wave function, quantum numbers and corresponding energy. The normalized wave function is also given which is similar to that of the one-particle harmonic oscillator. Afterwards, the Hamiltonian function of the particle in a bidimensional box is given along with its wave function that is the product of two wave function of the particle in a one-dimensional box and the energy is the sum of two energy components, x and y, of the particle in a one-dimensional box. Finally, there is a couple of exercises to plot the wave functions of a rectangular box to find the probability density of the wave function for a symmetrical box. (164 words).