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IntechOpen eBooks

Exactly Solvable Problems in Quantum Mechanics

Lourdhu Bruno Chandrasekar, Kanagasabapathi Gnanasekar, Marimuthu Karunakaran

Published Aug 26, 2020• 0 citations
Publisher

Abstract

Some of the problems in quantum mechanics can be exactly solved without any approximation. Some of the exactly solvable problems are discussed in this chapter. Broadly there are two main approaches to solve such problems. They are (i) based on the solution of the Schrödinger equation and (ii) based on operators. The normalized eigen function, eigen values, and the physical significance of some of the selected problems are discussed.

DOI
10.5772/intechopen.93317

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Some of the problems in quantum mechanics can be exactly solved without any approximation. Some of the exactly solvable problems are discussed in this chapter. Broadly there are two main approaches to solve such problems. They are (i) based on the solution of the Schrödinger equation and (ii) based on operators. The normalized eigen function, eigen values, and the physical significance of some of the selected problems are discussed.
In the previous chapters, we have shown how to solve the Schrodinger equation for several systems as a particle in an infinite and finite potential well, scattering, harmonic oscillator, and hydrogen atom. For all these systems, we were able to solve Schrodinger's equation exactly. However, there are complicated potentials for which Schrodinger's equation cannot be solved exactly. For such situations, we resort to approximation methods for finding approximate solutions to the Schrodinger equation. In this chapter, we discuss several approximate methods for solving Schrodinger's equation.
Abstract Quantum mechanical problems capable of exact solution are traditionally solved in a few instances only (such as the harmonic oscillator and angular momentum) by operator methods, but mainly by means of Schrodinger's wave mechanics. The present volume shows that a large range of one- and three-dimensional problems, including certain relativistic ones, are solvable by algebraic, representation-independent methods using commutation relations, shift operators, the virial, hypervirial, and Hellman-Feyman theorems. Applications of these operator methods to the calculation of eigenvalues, matrix elements, and wavefunctions are discussed in detail. This book is an introduction to the use of operator methods in quantum mechanics and also a reference work with numerous problmes solved. It is suitable for use by students of intermediate quantum mechanics and also more advanced postgraduate students who wish to study the algebraic method of solving quantum mechanical problems.
Many physical systems cannot be solved exactly. In this case, we look for approximate methods to gain insight into their properties. Perturbation theory is one such method. When the Hamiltonian of the system doesn't change over time, one approximate method is the Time Independent Perturbation Theory, which is the subject of Chapter 10 . The infinite square well, the harmonic oscillator, and the hydrogen atom are among the few physical systems for which the Schrodinger equation can be solved exactly. For this reason, they are described in detail in most of the introductory quantum mechanics textbooks. However, most physical systems are not exactly solvable, i.e., they are described by the Schrodinger equation, whose solutions cannot be expressed in terms of commonly used functions. In order to study such systems, we try to decompose the corresponding Hamiltonian into a solvable Hamiltonian plus a small perturbation. For such cases, we say that the Hamiltonian is “close enough” to an exactly solvable Hamiltonian to warrant using perturbative methods to approximate its eigenenergies and eigenfunctions.
The number of exactly solvable eigenvalue problems has been rapidly increasing since the advent of quantum mechanics and there are many efficient ways to treat them. As a general rule, it is possible to write exactly solvable abstract eigenvalue equations in terms of the generators of finite-dimensional Lie algebras and solve them by means of purely algebraic methods. Matrix elements are commonly necessary for the application of perturbation theory and variational principles, among other approximate methods. The chapter discusses examples of three-dimensional Lie algebras with well-known quantum-mechanical realizations. Typically, exactly solvable quantum-mechanical problems are either onedimensional models or lead to separable equations in many dimensions. In the coordinate representation both cases reduce to ordinary differential equations of second order that determine the eigenvalues and separation constants compatible with the physical boundary conditions. In its purest form, a Lie algebraic method is representation-independent. Extensive application of algebraic methods to selected physical problems is already available elsewhere.
The starting point in a quantum mechanical problem is the construction of a Schrödinger equation. We try to solve it exactly to obtain wave function. A Schrödinger equation is exactly solvable only for a certain number of simple potentials. In most of the cases the Schrödinger equation cannot be solved exactly. The solution of the Schrödinger equation for the real systems is usually complicated and often exact solutions are very difficult to find or solutions not exist. Examples include as anharmonic oscillator, hydrogen atom in an electric field, a plane rotator in the presence of an applied electric field and so on. Therefore, we need to rely on approximation methods. The simple and most interesting and powerful approximate method is the perturbation theory developed by Schrödinger in 1926 [1]. Earlier Lord Rayleigh [2] analysed harmonic vibrations of a string perturbed by small inhomogeneities. The work of Rayleigh was pointed out by Schrödinger. Consequently, the method is also called Rayleigh-Schrödinger perturbation theory. This method is powerful for determining the changes in the discrete energy values and the associated eigenfunctions of a system due to a weak perturbation, provided the eigenpairs of the undisturbed system are available. The approximations obtained from the perturbation theory are used to calculate energy level diagrams and to understand the splitting and assignments of atomic and molecular spectra [35]. The perturbation theory has been proven to be useful in several fields of theoretical physics and also in chemistry. It provides considerable insight into various phenomena. The main disadvantage of this method is that in certain problems the perturbation series converges slowly or diverges.