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Entropy

Thermalization in a Quantum Harmonic Oscillator with Random Disorder

Ya-Wei Hsueh, Che-Hsiu Hsueh, W. C. Wu

Published Jul 31, 2020• 9 citations
Publisher

Abstract

We propose a possible scheme to study the thermalization in a quantum harmonic oscillator with random disorder. Our numerical simulation shows that through the effect of random disorder, the system can undergo a transition from an initial nonequilibrium state to a equilibrium state. Unlike the classical damped harmonic oscillator where total energy is dissipated, total energy of the disordered quantum harmonic oscillator is conserved. In particular, at equilibrium the initial mechanical energy is transformed to the thermodynamic energy in which kinetic and potential energies are evenly distributed. Shannon entropy in different bases are shown to yield consistent results during the thermalization.

DOI
10.3390/e22080855

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We propose a possible scheme to study the thermalization in a quantum harmonic oscillator with random disorder. Our numerical simulation shows that through the effect of random disorder, the system can undergo a transition from an initial nonequilibrium state to a equilibrium state. Unlike the classical damped harmonic oscillator where total energy is dissipated, total energy of the disordered quantum harmonic oscillator is conserved. In particular, at equilibrium the initial mechanical energy is transformed to the thermodynamic energy in which kinetic and potential energies are evenly distributed. Shannon entropy in different bases are shown to yield consistent results during the thermalization.
Previously we numerically showed that thermalization can occur in an oscillating Bose-Einstein condensate (BEC) with a disordered harmonic trap when healing length ξξξ of the condensate is shorter than the correlation length σDσ_{D}σD​ of the disorder [see, for example, the experiment reported in Phys. Rev. A \textbf{82}, 033603 (2010)]. In this work, we investigate the weakly interacting or Anderson localization regime ξ>σDξ>σ_{D}ξ>σD​ and show that the oscillating BEC can also exhibit a relaxation process from nonequilibrium to equilibrium. In such an isolated quantum system, energy and particle number are conserved and the irreversible evolution towards thermodynamic equilibrium is induced by the disorder. The thermodynamic equilibrium is evidenced by the maximized entropy S[nk]S\left[n_{k}\right]S[nk​] in which the waveaction spectrum nkn_{k}nk​ follows the Rayleigh-Jeans distribution. Besides, unlike a monotonic irreversible process of thermalization to equilibrium, the Fermi-Pasta-Ulam-Tsingou recurrence arises in this system, manifested by the oscillation of the non-equilibrium entropy.
Simulations are performed of a small quantum system interacting with a quantum environment. The system consists of various initial states of two harmonic oscillators coupled to give normal modes. The environment is "designed" by its level pattern to have a thermodynamic temperature. A random coupling causes the system and environment to become entangled in the course of time evolution. The approach to a Boltzmann distribution is observed, and effective fitted temperatures close to the designed temperature are obtained. All initial pure states of the system are driven to equilibrium at very similar rates, with quick loss of memory of the initial state. The time evolution of the von Neumann entropy is calculated as a measure of equilibration and of quantum coherence. It is pointed out using spatial density distribution plots that quantum interference is eliminated only with maximal entropy, which corresponds thermally to infinite temperature. Implications of our results for the notion of "classicalizing" behavior in the approach to thermal equilibrium are briefly considered.
We study a quantum harmonic oscillator undergoing thermalization. To describe the thermalization process, we generalize the Ermakov-Lewis-Riesenfeld (ELR) invariant method for the oscillator. After imposing appropriate conditions on the thermalization process, we introduce an ansatz equation that describes the time evolution effectively. We write down the first law for thermalization in the same form as that for ordinary thermodynamics. Here, the thermalization effect appears through a change of the ELR frequency. Finally, we obtain the oscillator's energy undergoing thermalization as a function of entropy and its time derivative.
We develop an exact analytical framework for studying the nonequilibrium dynamics of interacting quantum harmonic oscillators coupled to a modelled thermal reservoir and driven by external classical fields. The total Hamiltonian is diagonalized via successive Bogoliubov transformations, enabling a nonperturbative treatment of dissipation and driving. For two coupled oscillators with an external source applied to the first, we derive explicit energy expressions and analyze their dependence on coupling and bath parameters. The phase-space structure is characterized through Husimi QQQ-functions for initial separable coherent and number states. We obtain the reduced density matrix elements in the number-state basis and demonstrate that, in the absence of driving and at zero temperature, the reduced density matrix of the main system satisfies the Lindblad master equation. A generating function for the Husimi function is introduced to facilitate computation of higher-order correlations. The analysis is then generalized to nnn interacting oscillators, with analytical energy expressions provided and the case n=3n=3n=3 examined in detail. Our results establish a versatile and exact framework for driven-dissipative quantum systems, with potential applications in quantum thermodynamics, open quantum systems, and many-body physics.
The in-in formalism and its influence functional generalization are widely used to describe the out-of-equilibrium dynamics of unitary and open quantum systems, respectively. In this paper, we build on these techniques to develop an effective theory of a quantum damped harmonic oscillator and use it to study initial state-dependence, decoherence, and thermalization. We first consider a Gaussian initial state and quadratic influence functional and obtain general equations for the Green's functions of the oscillator. We solve the equations in the specific case of time-local dissipation and use the resulting Green's functions to obtain the purity and unequal-time two-point correlations of the oscillator. We find that the dynamics must include a nonvanishing noise term to yield physical results for the purity and that the oscillator decoheres in time such that the late-time density operator is thermal. We show that the frequency spectrum or unequal-time correlations can, however, distinguish between the damped oscillator and an isolated oscillator in thermal equilibrium and obtain a generalized fluctuation-dissipation relation for the damped oscillator. We briefly consider time-nonlocal dissipation as well, to show that the fluctuation-dissipation is satisfied for a specific choice of dissipation kernels. Lastly, we develop a double in-out path integral approach to go beyond Gaussian initial states and show that our equal-time results for time-local dissipation are in fact nonperturbative in the initial state.
Abstract We reveal a new face of the old clichéd system: a dissipative quantum harmonic oscillator. We formulate and study a quantum counterpart of the energy equipartition theorem satisfied for classical systems. Both mean kinetic energy Ek and mean potential energy Ep of the oscillator are expressed as Ek = 〈εk〉 and Ep = 〈εp〉, where 〈εk〉 and 〈εp〉 are mean kinetic and potential energies per one degree of freedom of the thermostat which consists of harmonic oscillators too. The symbol 〈...〉 denotes two-fold averaging: (i) over the Gibbs canonical state for the thermostat and (ii) over thermostat oscillators frequencies ω which contribute to Ek and Ep according to the probability distribution Pk(ω){{\mathbb{P}}}_{k}(\omega )Pk​(ω) ℙ k ( ω ) and Pp(ω){{\mathbb{P}}}_{p}(\omega )Pp​(ω) ℙ p ( ω ) , respectively. The role of the system-thermostat coupling strength and the memory time is analysed for the exponentially decaying memory function (Drude dissipation mechanism) and the algebraically decaying damping kernel.