This thesis concerns quantum states that are superpositions of discrete or of continuum energy levels. It develops mathematical methods to characterize the physical properties of these states and finds important consequences. Regarding rational extensions of the harmonic oscillator, no other authors had constructed the coherent states associated with the ladder operators of Marquette and Quesne. It was our aim to proceed with this construction, then to calculate physical properties of these coherent states, looking for classical or quantum behaviour. The method of partial wave analysis was known to be not applicable to the Coulomb potential for the scattering of plane waves. It was my aim to repeat the calculation for wavepacket scattering, to investigate whether the method became applicable. Other authors have constructed relativistic probability amplitudes and compared them to the scalar Klein-Gordon amplitude. In this context, it was my aim to question the conclusion of a minimum width for a massive particle. In the same context, I investigated the possibility of a four-vector probability current with the Newton-Wigner position probability density as the zero component. In Chapter 12, my aim was to construct a measure of localization for the photon, knowing from the work of other authors that a point-localized photon state is not possible.In Chapters 3, 4 and 5, our measures of classicality for the Barut-Girardello coherent states included plotting energy expectations as functions of the magnitude of the coherent state para- meter, z, position probability densities for the coherent states and the even and odd cat states, the Wigner functions for particular choices of z, the two-photon number probability distribu- tion and the linear entropy for a coherent state on a beamsplitter, position spreads to look for squeezing and the Mandel Q parameter. In Chapter 6, it was necessary to approximate an integral containing a particular Wigner rotation matrix. An approximation of general Wigner rotation matrices, at low angle, was derived and its precision evaluated numerically in Chapter 7. The exact values for the Coulomb phase shifts were used to construct the incoming wavefunction. Time reversal and a rotation were used to construct the outgoing wavefunction. The sums over l were evaluated numerically. In Chapter 10, four arguments were used against the minimum width. Comparison of the scalar amplitude and the relativistic probability amplitude for a Newton-Wigner localized state showed the root of the problem. A Lorentz transformation was applied to the scalar function to see if the “minimum” width became even smaller. A simple construction produced scalar functions with arbitrarily small widths. A relevant argument from Almeida and Jabs was included here. In Chapter 11, the algebra involving the four components of a four-vector current (at the origin) and the boost generators was derived. All of these commutators must be satisfied by a four-vector, providing a test for the claimed four-vector probability currents of other authors. In Chapter 12, field expectations were taken in a coherent state with a mean photon number of unity, built from identical single-photon states.In Chapters 3, 4 and 5, we found a mix of classical and quantum behaviour for the coherent states. In none of the systems studied did we see the high degree of classicality of the unmodified harmonic oscillator. The investigation of cat states was relevant to the fundamental problem of measurement in quantum mechanics. In Chapter 6, the use of wavepackets introduced a convergence factor into the sum over l, which diverges in the plane wave treatment. The elimination of a divergence is the most significant result of this thesis. Scattering probabilities remained finite at all angles, in disagreement with the diverging Rutherford formula, but only on small angular regions around forward scattering. Future work will investigate the measurability of the phenomena predicted here. In Chapter 10, all four arguments pointed to no minimum width for a massive particle. In Chapter 11, it was found that there can be no four-vector current density with the Newton-Wigner position probability density as the zero component, for any spin. Other authors were found to be in error when they claimed to have produced such a four-vector current density. This result strengthens the position of the Dirac current as the appropriate current for an electron. In Chapter 12, the coherent state field expectations were found to provide a meaningful measure of localization. In summary, wavepackets give a realism to the description of a scattering experiment that is absent with the use of plane waves. Phenomena not captured by the plane wave scattering amplitude, such as time delays, are calculable in the wavepacket context. Relativistic probability amplitudes provide a complete description of free particles, consistent with quantum mechanics and with special relativity. They predict agreement with the Heisenberg uncertainty principle and relativistic effects such as Lorentz contraction. The absence of relativistic probability amplitudes from standard textbooks on relativistic quantum mechanics is a serious omission.
This thesis concerns quantum states that are superpositions of discrete or of continuum energy levels. It develops mathematical methods to characterize the physical properties of these states and finds important consequences. Regarding rational extensions of the harmonic oscillator, no other authors had constructed the coherent states associated with the ladder operators of Marquette and Quesne. It was our aim to proceed with this construction, then to calculate physical properties of these coherent states, looking for classical or quantum behaviour. The method of partial wave analysis was known to be not applicable to the Coulomb potential for the scattering of plane waves. It was my aim to repeat the calculation for wavepacket scattering, to investigate whether the method became applicable. Other authors have constructed relativistic probability amplitudes and compared them to the scalar Klein-Gordon amplitude. In this context, it was my aim to question the conclusion of a minimum width for a massive particle. In the same context, I investigated the possibility of a four-vector probability current with the Newton-Wigner position probability density as the zero component. In Chapter 12, my aim was to construct a measure of localization for the photon, knowing from the work of other authors that a point-localized photon state is not possible.In Chapters 3, 4 and 5, our measures of classicality for the Barut-Girardello coherent states included plotting energy expectations as functions of the magnitude of the coherent state para- meter, z, position probability densities for the coherent states and the even and odd cat states, the Wigner functions for particular choices of z, the two-photon number probability distribu- tion and the linear entropy for a coherent state on a beamsplitter, position spreads to look for squeezing and the Mandel Q parameter. In Chapter 6, it was necessary to approximate an integral containing a particular Wigner rotation matrix. An approximation of general Wigner rotation matrices, at low angle, was derived and its precision evaluated numerically in Chapter 7. The exact values for the Coulomb phase shifts were used to construct the incoming wavefunction. Time reversal and a rotation were used to construct the outgoing wavefunction. The sums over l were evaluated numerically. In Chapter 10, four arguments were used against the minimum width. Comparison of the scalar amplitude and the relativistic probability amplitude for a Newton-Wigner localized state showed the root of the problem. A Lorentz transformation was applied to the scalar function to see if the “minimum” width became even smaller. A simple construction produced scalar functions with arbitrarily small widths. A relevant argument from Almeida and Jabs was included here. In Chapter 11, the algebra involving the four components of a four-vector current (at the origin) and the boost generators was derived. All of these commutators must be satisfied by a four-vector, providing a test for the claimed four-vector probability currents of other authors. In Chapter 12, field expectations were taken in a coherent state with a mean photon number of unity, built from identical single-photon states.In Chapters 3, 4 and 5, we found a mix of classical and quantum behaviour for the coherent states. In none of the systems studied did we see the high degree of classicality of the unmodified harmonic oscillator. The investigation of cat states was relevant to the fundamental problem of measurement in quantum mechanics. In Chapter 6, the use of wavepackets introduced a convergence factor into the sum over l, which diverges in the plane wave treatment. The elimination of a divergence is the most significant result of this thesis. Scattering probabilities remained finite at all angles, in disagreement with the diverging Rutherford formula, but only on small angular regions around forward scattering. Future work will investigate the measurability of the phenomena predicted here. In Chapter 10, all four arguments pointed to no minimum width for a massive particle. In Chapter 11, it was found that there can be no four-vector current density with the Newton-Wigner position probability density as the zero component, for any spin. Other authors were found to be in error when they claimed to have produced such a four-vector current density. This result strengthens the position of the Dirac current as the appropriate current for an electron. In Chapter 12, the coherent state field expectations were found to provide a meaningful measure of localization. In summary, wavepackets give a realism to the description of a scattering experiment that is absent with the use of plane waves. Phenomena not captured by the plane wave scattering amplitude, such as time delays, are calculable in the wavepacket context. Relativistic probability amplitudes provide a complete description of free particles, consistent with quantum mechanics and with special relativity. They predict agreement with the Heisenberg uncertainty principle and relativistic effects such as Lorentz contraction. The absence of relativistic probability amplitudes from standard textbooks on relativistic quantum mechanics is a serious omission.
This thesis addresses aspects of quantum phase and sets out to draw attention to a collection of new and extend some not so new techniques utilizing Weyl's correspondence rule and its inverse. The phase formulation of quantum mechanics is as old as quantum mechanics itself and evolved over a period of two decades due to the contributions of H. Weyl \cite{Weyl1950}, E. P. Wigner \cite{Wigner1932}, H. Groenewold \cite{Groenewold1946} and J. E. Moyal \cite{Moyal1949}. Over the ensuing years the phase picture has matured into a practical analytical tool, and has generated a multitude of technical papers, reports, reviews, and expositions from many authors and commentators. One reason for its success is that it offers an intuitive picture of quantum mechanics owing to its \it{classical look and feel}, and it has made an impression, in one way or another, in many fields such as mathematical physics, quantum optics, and physical chemistry.The thesis opens with a brief history of classical phase space, tracing the possible origin of the term ``phase space itself, and chronicles the events leading to the conceptualization (and generalization) of quantum phase space. In Chapter 2 the Weyl correspondence is recast in terms of von Neumann's integral kernel transform and a heuristic analysis is given from this perspective. A characteristic of Weyl's correspondence rule and its inverse is that there are two inherent representations of the same operator. These have been referred to as the Weyl representation and Wigner representation and are related by a symplectic Fourier transform. For an arbitrary outer dyadic operator it is shown that the Weyl representation leads to the \it{modified} Gabor transform (known to Signal Processing), while the Wigner representation specializes to the Bargmann transform and a representation in terms of analytic functions. Calculating Weyl-Wigner (WW) transforms of products of n operators, from first principles, has proved to be a technically difficult problem. However, with the machinery developed in Chapter 2 the problem is reduced to a straightforward algebraic exercise. Finally, forming an s-parametrized generalization of Weyl's correspondence rule and focusing on the Weyl representation it is shown to lead to an intimate relationship with the relative state formalism \cite{Ban1998}. Weyl's correspondence rule is only applicable to operators and consequently state vectors ∣ψ⟩ are not represented in the usual formulation of quantum phase space. This problem is circumvented in Chapter 3 by introducing the notion of a normalized fixed state (or window) vector ∣φ0⟩ to form an outer dyadic product $\wh{\Psi} = |\psi\rangle\langle\varphi_0|$. The WW transform of this product under the action of the Weyl's rule is a complex valued function of real variables called a phase amplitude and denoted by the symbol Ψ. The phase amplitudes have many (and sometimes surprising) properties. For example they: \begin{itemize} \item form the building blocks of Wigner functions W by admitting a generalized Born rule W=Ψ⋆Ψˉ, and as such can be considered to be a more fundamental objects than Wigner functions; \item superpose and interfere like the state vectors they represent; \item specialize to the Bargmann and Gabor transforms when a Gaussian window is chosen; \end{itemize} \ni In Chapter 4 further aspects of phase amplitudes are explored and discussed. For example it is shown that they: \begin{itemize} \item define phase state vectors which form an over complete set and are elements of a reproducing kernel Hilbert space; \item allow unitary ray representations of the group symmetries of translation, rotation and time reversal; \item evolve in phase under the influence of a propagator R which is intimately related to the Wigner propagator P. \end{itemize} Chapter 5 considers an extension of phase amplitudes to include systems with finitely many degrees of freedom. These are called spin amplitudes and are obtained by first forming the outer dyadic product of a spin state vector with an arbitrary fixed spin state vector, and then applying a finite-dimensional analogue of the WW transform. The spin amplitude operator is represented as an n×n matrix, whose elements are products of the spin components of the spin and fixed state vectors. Two kinds of spin amplitudes are considered, arising on the sphere S2 or on a (2j+1) dimensional lattice. In the special case of spin-$\half$ systems it is shown that the spin amplitudes transform as spinors under rotations on both the sphere and lattice. As a physical application the spin amplitudes for a spin-$\half$ magnetic dipole are found for a Nuclear Magnetic Resonance (NMR) environment. Chapter 6 considers Schwinger's abstract approach to quantum mechanics which takes into account the inability to indefinitely compensate for fluctuations in the measurement process. The resulting measurement algebra provides a symbolic representation of the physical laws as opposed to the mathematical abstraction (of von Neumann and Dirac) that was justified \it{\'a posteriori} by being in agreement with experiment. Despite Schwinger's prolific work on the subject of measurement algebra, its interpretation in quantum phase remained an open issue. It is shown that the key to formulating a quantum phase in terms of the measurement operators and transformation functions is the determination of a suitable set of basis operators for an arbitrary measurement operator. Many new results follow as a consequence of expanding an arbitrary measurement operator in this basis. In Chapter 7 the quantum-classical interface is explored by considering Hamilton's principal function or action S(q,v,t). Starting from a purely heuristic classical argument, a phase function U(p,q,t) is derived in terms of the classical action and is shown to be proportional to the WW transform of the quantum evolution operator. This association leads to the transform \be U(p,q,t) = A(t) \int e^{ipv/\hbar} e^{iS(q,v,t)/\hbar} \; \rm{d}v, \ee which enables one, in principle, to deduce the Wigner functions of a given system when only the classical action is known. Simple physical systems are used to provide examples illustrating this approach.
The goal of Quantum Mechanics I, A Problem Text, is to enable students to solve problems appropriate to their first course in quantum mechanics. Significantly detailed solutions to traditionally posed problems dominate. Theory and rationale are addressed in prescript and postscript narratives and/or within the solved problems to guide students; and clarify vocabulary, symbology, and terminology. Applications of the postulates are presented initially using arguments from linear algebra appropriate to discrete systems with low-dimensional vectors and matrix operators, introducing orthogonality, orthonormality, Hermiticity, eigenvectors, eigenvalues, probability, expectation value, and degeneracy. These arguments blend into infinite-dimensional vectors and operators, and calculus-based arguments for continuous systems where delta functions, theta functions, and Fourier transforms are initially discussed. Dirac notation is fully developed within these first five chapters. Chapter six discusses Ehrenfest’s theorem, the Heisenberg uncertainty relations, and Gaussian wave functions and wave packets. Increasingly sophisticated potential energy functions are then treated to include the free particle, the infinite square well, the one-dimensional scattering state, the simple harmonic oscillator, the finite square well, orbital angular momentum, and the hydrogen atom. Ladder operators are featured in the developments of the simple harmonic oscillator and orbital angular momentum. The diversity of narratives and detailed solutions intend
The goal of Quantum Mechanics I, A Problem Text, is to enable students to solve problems appropriate to their first course in quantum mechanics. Significantly detailed solutions to traditionally posed problems dominate. Theory and rationale are addressed in prescript and postscript narratives and/or within the solved problems to guide students; and clarify vocabulary, symbology, and terminology. Applications of the postulates are presented initially using arguments from linear algebra appropriate to discrete systems with low-dimensional vectors and matrix operators, introducing orthogonality, orthonormality, Hermiticity, eigenvectors, eigenvalues, probability, expectation value, and degeneracy. These arguments blend into infinite-dimensional vectors and operators, and calculus-based arguments for continuous systems where delta functions, theta functions, and Fourier transforms are initially discussed. Dirac notation is fully developed within these first five chapters. Chapter six discusses Ehrenfest’s theorem, the Heisenberg uncertainty relations, and Gaussian wave functions and wave packets. Increasingly sophisticated potential energy functions are then treated to include the free particle, the infinite square well, the one-dimensional scattering state, the simple harmonic oscillator, the finite square well, orbital angular momentum, and the hydrogen atom. Ladder operators are featured in the developments of the simple harmonic oscillator and orbital angular momentum. The diversity of narratives and detailed solutions intend
The goal of Quantum Mechanics I, A Problem Text, is to enable students to solve problems appropriate to their first course in quantum mechanics. Significantly detailed solutions to traditionally posed problems dominate. Theory and rationale are addressed in prescript and postscript narratives and/or within the solved problems to guide students; and clarify vocabulary, symbology, and terminology. Applications of the postulates are presented initially using arguments from linear algebra appropriate to discrete systems with low-dimensional vectors and matrix operators, introducing orthogonality, orthonormality, Hermiticity, eigenvectors, eigenvalues, probability, expectation value, and degeneracy. These arguments blend into infinite-dimensional vectors and operators, and calculus-based arguments for continuous systems where delta functions, theta functions, and Fourier transforms are initially discussed. Dirac notation is fully developed within these first five chapters. Chapter six discusses Ehrenfest’s theorem, the Heisenberg uncertainty relations, and Gaussian wave functions and wave packets. Increasingly sophisticated potential energy functions are then treated to include the free particle, the infinite square well, the one-dimensional scattering state, the simple harmonic oscillator, the finite square well, orbital angular momentum, and the hydrogen atom. Ladder operators are featured in the developments of the simple harmonic oscillator and orbital angular momentum. The diversity of narratives and detailed solutions intend
The goal of Quantum Mechanics I, A Problem Text, is to enable students to solve problems appropriate to their first course in quantum mechanics. Significantly detailed solutions to traditionally posed problems dominate. Theory and rationale are addressed in prescript and postscript narratives and/or within the solved problems to guide students; and clarify vocabulary, symbology, and terminology. Applications of the postulates are presented initially using arguments from linear algebra appropriate to discrete systems with low-dimensional vectors and matrix operators, introducing orthogonality, orthonormality, Hermiticity, eigenvectors, eigenvalues, probability, expectation value, and degeneracy. These arguments blend into infinite-dimensional vectors and operators, and calculus-based arguments for continuous systems where delta functions, theta functions, and Fourier transforms are initially discussed. Dirac notation is fully developed within these first five chapters. Chapter six discusses Ehrenfest’s theorem, the Heisenberg uncertainty relations, and Gaussian wave functions and wave packets. Increasingly sophisticated potential energy functions are then treated to include the free particle, the infinite square well, the one-dimensional scattering state, the simple harmonic oscillator, the finite square well, orbital angular momentum, and the hydrogen atom. Ladder operators are featured in the developments of the simple harmonic oscillator and orbital angular momentum. The diversity of narratives and detailed solutions intend
The goal of Quantum Mechanics I, A Problem Text, is to enable students to solve problems appropriate to their first course in quantum mechanics. Significantly detailed solutions to traditionally posed problems dominate. Theory and rationale are addressed in prescript and postscript narratives and/or within the solved problems to guide students; and clarify vocabulary, symbology, and terminology. Applications of the postulates are presented initially using arguments from linear algebra appropriate to discrete systems with low-dimensional vectors and matrix operators, introducing orthogonality, orthonormality, Hermiticity, eigenvectors, eigenvalues, probability, expectation value, and degeneracy. These arguments blend into infinite-dimensional vectors and operators, and calculus-based arguments for continuous systems where delta functions, theta functions, and Fourier transforms are initially discussed. Dirac notation is fully developed within these first five chapters. Chapter six discusses Ehrenfest’s theorem, the Heisenberg uncertainty relations, and Gaussian wave functions and wave packets. Increasingly sophisticated potential energy functions are then treated to include the free particle, the infinite square well, the one-dimensional scattering state, the simple harmonic oscillator, the finite square well, orbital angular momentum, and the hydrogen atom. Ladder operators are featured in the developments of the simple harmonic oscillator and orbital angular momentum. The diversity of narratives and detailed solutions intend