Ushered forth by advances in time and frequency metrology, atom interferometry remains an indispensable measurement tool in atomic physics due to its precision and versatility. A sequence of four
pi/2 beam splitter pulses can create either an interferometer sensitive to the atom's recoil frequency when the momentum imparted by the light reverses direction between pulse pairs or, when constructed from pulses without such reversal, sensitive to the perturbing potential from an external optical field. Here, we demonstrate the first atom interferometer with laser-cooled lithium, advantageous for its low mass and simple atomic structure. We study both a recoil-sensitive Ramsey-Bord\\'e interferometer and interferometry sensitive to the dynamic polarizability of the ground state of lithium. Recoil-sensitive Ramsey-Bord\\'e interferometry benefits from lithium's high recoil frequency, a consequence of its low mass. At an interrogation time of 10 ms, a Ramsey-Bord\\'e lithium interferometer could achieve sensitivities comparable to those realized at much longer times with heavier alkali atoms. However, in contrast with other atoms that are used for atom interferometry, lithium's unresolved excited-state hyperfine structure precludes the the cycling transition necessary for efficient cooling. Without sub-Doppler cooling techniques. As as result, a lithium atomic gas is typically laser cooled to temperatures around 300
muK, above the Doppler limit, and well above the recoil temperature of 6
muK. This higher temperature gas expands rapidly during the operation of an atom interferometer, limiting the experimental interrogation time and preventing spatially resolved detection. In this work, a light-pulse lithium matter-wave interferometer is demonstrated in spite of these limitation. Two-photon Raman interferometer pulses coherently couple the atom's spin and momentum and are thus able to spectrally resolve the outputs. These fast pulses drive conjugate interferometers simultaneously which beat with a fast frequency component proportional to the atomic recoil frequency and an envelope modulated by the two-photon detuning of the Raman transition. We detect the summed signal at short experimental times, preventing perturbation of the signal from vibration noise. This demonstration of a sub-recoil measurement with a super-recoil sample opens the door to similar scheme with other particles that are difficult to trap and cool well, like electrons. An interferometer instead composed of
pi/2-pulses with a single direction of momentum transfer, can be sensitive to the dynamic polarizability of the atomic ground state. By scanning the frequency of an external driving field, such a measurement can be used to determine the atom's tune-out wavelength. This is the wavelength at which the frequency-dependent polarizability vanishes due to compensating ac-Stark shifts from other atomic states. Lithium's simple atomic structure allows for a precise computation of properties with only {\\em ab initio} wave functions and spectroscopic data. A direct interferometric measurement of lithium's red tune-out wavelength at 670.971626(1) nm, is a precise comparison to existing `all-order' atomic theory computations. It also provides another way to experimentally determine the
S− to
P− transitions matrix elements, for which large correlations and small values complicate computations. Finally, a future measurement of lithium's ultraviolet tune-out wavelength of at 324.192(2) nm would be sensitive to relativistic approximations in the atomic structure description.Atom interferometry simultaneously verifies existing atomic theory with measurements of atomic properties and searches for exotic physics lurking in plain sight. The techniques developed here broaden the applicability of interferometry and increase measurement sensitivity by simplifying cooling, increasing atom number and reducing the cycle time. Overcoming the current experimental limitations on interrogation time would allow for ultra-precise measurements of both the tune-out wavelength and the fine structure constant.
We discuss details of momentum transfer in the interaction between localized atoms and localized optical fields which are relevant to precision atom interferometry. Specifically, we consider a $\ensuremath{\Lambda}$-type atom coherently driven between its ground states by a bichromatic optical field. We assume that the excited state can be eliminated adiabatically from the time evolution. It is shown that the average recoil momentum is given by the phase gradient of the two-photon field at the ``position'' of the atom, provided that the optical field can be described by a function which is separable in position and time and that the atomic wave function is symmetric and well localized within the optical field envelope. The result does not require the optical fields to have a Gaussian spatial dependence. Our discussion provides the basis for the analysis of systematic errors in precision atom interferometry arising from optical wave-front curvature, wave-front distortion, and the Gouy phase shift of Gaussian beams. We apply our result to the atom interferometer experiment of Chu and co-workers which measures the fine-structure constant.