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Bulletin of the American Physical Society

Controlling van der Waals Phenomena at the Interface of Atomic and Two-Dimensional Dirac Quantum Matter

Aaditya Dimri, Joseph Turner, Adrian Del Maestro, Valeri N. Kotov

Published Mar 3, 2020• 0 citations
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Abstract

We discuss how the presence of two-dimensional (2D) materials, such as graphene, can significantly affect two intrinsically quantum phenomena that have traditionally served as probes of the fundamental van der Waals (VDW) interaction. First, we show theoretically that Quantum Reflection (QR) of slow atoms off attractive VDW potential tails (due to interactions with 2D materials) is very strongly dependent on material characteristics (such as band structure, doping and screening level, etc). Secondly, we analyze manifestations of such 2D effects for many atoms forming a confined Bose-Einstein condensate (BEC) placed near 2D materials, which in turn makes the BEC frequency sensitive to the interface. In both cases we find that relatively small 2D material changes (either by external factors such as strain or doping, or by using gapped 2D materials instead of graphene) can have a profound effect on the above phenomena. In particular, Quantum Reflection at a given energy can experience a significant enhancement or supression (relative to conventionally used bulk materials) making 2D quantum materials an attractive playground for the study of many-body phenomena at the interface of atomic and solid state physics. *This work received support under NASA grant number 80NSSC19M0143.

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We discuss how the presence of two-dimensional (2D) materials, such as graphene, can significantly affect two intrinsically quantum phenomena that have traditionally served as probes of the fundamental van der Waals (VDW) interaction. First, we show theoretically that Quantum Reflection (QR) of slow atoms off attractive VDW potential tails (due to interactions with 2D materials) is very strongly dependent on material characteristics (such as band structure, doping and screening level, etc). Secondly, we analyze manifestations of such 2D effects for many atoms forming a confined Bose-Einstein condensate (BEC) placed near 2D materials, which in turn makes the BEC frequency sensitive to the interface. In both cases we find that relatively small 2D material changes (either by external factors such as strain or doping, or by using gapped 2D materials instead of graphene) can have a profound effect on the above phenomena. In particular, Quantum Reflection at a given energy can experience a significant enhancement or supression (relative to conventionally used bulk materials) making 2D quantum materials an attractive playground for the study of many-body phenomena at the interface of atomic and solid state physics. *This work received support under NASA grant number 80NSSC19M0143.
Novel two-dimensional, atomically thin materials, notably graphene and transition-metal dichalcogenides, exhibit exotic Dirac quasiparticle spectra and can serve as experimental and theoretical laboratories for understanding fundamental physical phenomena, such as the nature of the van der Waals force between atoms and material surfaces. van der Waals forces are the most common manifestations of electromagnetism in Nature and govern the interactions between neutral objects on mesoscopic scales. Yet they are very hard to “engineer” and manipulate effectively, and here the newly-discovered graphene-type materials can lead to fundamental progress. I will discuss recent progress and my results in the following main directions: (1) I will describe how van der Waals interactions between cold atoms and graphene arise and the way physicists calculate them. The atoms have to be fairly “cold” so that thermal motion and other dissipation effects do not interfere with the main phenomenon. (2) I will present recent results on how we can effectively change the strength of these interactions. In particular I will discuss how changing the number of electrons in the graphene sheet (via application of voltage) can lead to changes in the van der Waals force. Other ways of manipulating, or “quantum engineering” such forces will also be mentioned, namely effects of strain and using other atomically thin materials instead of graphene.
Abstract Novel two-dimensional atomically flat materials, such as graphene and transition-metal dichalcogenides, exhibit unconventional Dirac electronic spectra. We propose to effectively engineer their interactions with cold atoms in microgravity, leading to a synergy between complex electronic and atomic collective quantum phases and phenomena. Dirac materials are susceptible to manipulation and quantum engineering via changes in their electronic properties by application of strain, doping with carriers, adjustment of their dielectric environment, etc. Consequently the interaction of atoms with such materials, namely the van der Waals/Casimir–Polder interaction, can be effectively manipulated, leading to the potential observation of physical effects such as quantum reflection off atomically thin materials and confined Bose–Einstein condensate frequency shifts.
Abstract Atoms deposited on 2D electronic materials, such as graphene, can exhibit unconventional many‐body correlations, not accessible in other settings. All of these are driven by van der Waals forces: between the atoms themselves and atom‐material interactions. For example 4He atoms on 2D materials can potentially form a variety of exotic quantum states of matter, such as 2D supersolids and superfluids, in addition to solid phases. For the “most quantum” case of a single helium layer we discuss, from a theoretical perspective, how the effective low‐energy (Bose–Hubbard) description can take advantage of the extreme sensitivity of this unique system to the interplay between the atomic (helium) and solid‐state (graphene) components. Due to the extraordinary variety and tunability of 2D electronic materials, it is envisaged that a wide range of correlated atomic phases can be realized under favorable conditions. Exciting possibilities in the opposite extreme of many atomic layers forming a liquid on top of graphene are also outlined —in this case a so‐called “spinodal dewetting” pattern can form at the liquid–vapor interface which reflects the presence and electronic properties of graphene underneath. Such patterns could be manipulated by choosing different atoms and materials, with potential technological applications.
In the field of cavity quantum materials, vacuum fluctuations of optical cavities are used for modifying ground-state properties of quantum materials without external driving. Here, one example is the van der Waals (vdW)/dispersion interaction in layered 2D vdW materials, where non-additive long-range correlations can dominate the interlayer binding. While cavity-induced changes of such interactions have been predicted and described using ab initio methods for molecular systems, no efficient description exists yet for extended materials. In this Letter, we close this gap by introducing a periodic formulation of the photon many-body dispersion (pMBD) functional within quantum electrodynamical density-functional theory (QEDFT). Applying this method with efficient q\textbf{q}q-point sampling to bilayer hBN and graphene, we predict cavity-modified stacking, increased equilibrium interlayer distances, and softened layer breathing modes with increasing light-matter coupling strength. Our results establish cavity vacuum fluctuations as a tuning knob for the structural properties of vdW materials.
We aim to understand how the van der Waals force between neutral adatoms and a graphene layer is modified by uniaxial strain and electron correlation effects. A detailed analysis is presented for three atoms (He, H, and Na) and graphene strain ranging from weak to moderately strong. We show that the van der Waals potential can be significantly enhanced by strain, and present applications of our results to the problem of elastic scattering of atoms from graphene. In particular, we find that quantum reflection can be significantly suppressed by strain, meaning that dissipative inelastic effects near the surface become of increased importance. Furthermore, we introduce a method to independently estimate the Lennard-Jones parameters used in an effective model of He interacting with graphene, and determine how they depend on strain. At short distances, we find that strain tends to reduce the interaction strength by pushing the location of the adsorption potential minima to higher distances above the deformed graphene sheet. This opens up the exciting possibility of mechanically engineering an adsorption potential, with implications for the formation and observation of anisotropic low-dimensional superfluid phases.
An exciting development in the field of correlated systems is the possibility of realizing two-dimensional (2D) phases of quantum matter. For a system of bosons, an example of strong correlations manifesting themselves in a 2D environment is provided by helium adsorbed on graphene. We construct the effective Bose-Hubbard model for this system which involves hard-core bosons $(U\ensuremath{\approx}\ensuremath{\infty})$, repulsive nearest-neighbor (V>0)(V>0)(V>0) and small attractive $({V}^{\ensuremath{'}}<0)$ next-nearest-neighbor interactions. The mapping onto the Bose-Hubbard model is accomplished by a variety of many-body techniques which take into account the strong He-He correlations on the scale of the graphene lattice spacing. Unlike the case of dilute ultracold atoms where interactions are effectively pointlike, the detailed microscopic form of the short-range electrostatic and long-range dispersion interactions in the helium-graphene system is crucial for the emergent Bose-Hubbard description. The result places the ground state of the first layer of 4He^{4}\mathrm{He}4He adsorbed on graphene deep in the commensurate solid phase with 1/31/31/3 of the sites on the dual triangular lattice occupied. Because the parameters of the effective Bose-Hubbard model are very sensitive to the exact lattice structure, this opens up an avenue to tune quantum phase transitions in this solid-state system.