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Journal of Physics Conference Series

Quantum oscillators model to derive an ideal gas in Bose-Einstein condensates under gravitation of earth

Teguh Budi Prayitno

Published Jun 1, 2020• 0 citations
Publisher

Abstract

Abstract Considering a set of condensates as N indistinguishable noninteracting quantum oscillators and replacing an available volume with a harmonic volume, we derived an ideal gas model by applying the canonical partition function via the thermodynamic relation. In this case, we take a longitudinal part of the three-dimensional Gross-Pitaevskii equation in which the effect of gravitation of earth works. Since we used the time-independent perturbation theory, to include gravity effect, we must put the higher coefficient in the formulation of each energy state whose value is determined by the separated amplitude formula in each state. It will also be shown that even though the equation of state represents an ideal gas, the appropriate heat capacity approaches Einstein’s solid-like model if the certain conditions are employed.

DOI
10.1088/1742-6596/1567/2/022006

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Abstract Considering a set of condensates as N indistinguishable noninteracting quantum oscillators and replacing an available volume with a harmonic volume, we derived an ideal gas model by applying the canonical partition function via the thermodynamic relation. In this case, we take a longitudinal part of the three-dimensional Gross-Pitaevskii equation in which the effect of gravitation of earth works. Since we used the time-independent perturbation theory, to include gravity effect, we must put the higher coefficient in the formulation of each energy state whose value is determined by the separated amplitude formula in each state. It will also be shown that even though the equation of state represents an ideal gas, the appropriate heat capacity approaches Einstein’s solid-like model if the certain conditions are employed.
Abstract By using the one-dimensional canonical partition function, we modelled an ideal gas-like form of a set of Bose-Einstein condensates confined by a three-dimensional anisotropic parabolic trap. The model itself was constructed by taking the eigenenergies of the one-dimensional Gross-Pitaevskii equation in the longitudinal direction and enabling the harmonic volume as the inverse cube of average geometric trapping frequency to substitute the real volume. In this paper, we showed that the condensates form an ideal gas represented by its equation of state and have similar mature to Einstein’s solid-like model with the corrections in both the low and high temperatures in the internal energy formulations.
We have studied the ground state energy of one-dimensional macroscopic quantum oscillator by adding gravity term as a time-independent external potential. The macroscopic quantum oscillator itself is based on discussion about Gross-Pitaevskii equation (GPE) describing Bose-Einstein condensate in anisotropic parabolic trap. That gravitational potential displaces the symmetry axis of Bose-Einstein condensation (BEC) with respect to symmetry axis of magnetic field that creates trapping potential of the Bose-Einstein condensate (BECs) in research on atomic lasers. Since the Gross-Pitaevskii equation can be treated as macroscopic quantum oscillator, we use time-independent perturbation theory as in ordinary quantum mechanics to find the ground state energy correction by assuming that other terms are very small. We also formulate the appropriate coefficients of expansion in the solution of one-dimensional GPE by considering the characteristics of harmonic oscillator eigenfunctions and find that the existence of the gravity can only be included if the higher coefficients are considered. Keywords: Gravitational potential, Gross-Pitaevskii, Quantum Oscillator.
A single condensate partition function in the canonical ensemble of the one-dimensional Gross-Pitaevskii equation has been used to construct the partition function of N noninteracting condensates. In this paper, we employed the appropriate transformation in order to make the partition function of a single condensate to be an extensive quantity by introducing a harmonic volume as the inverse cube of the average geometric trapping frequency. We found that some expressions of the thermodynamic quantities must be corrected to keep the consistency of the thermodynamic expressions based on the Gibbs paradox in the statistical mechanics. This only can be done if a set of condensates is considered as the indistinguishable macroscopic quantum oscillators with a weak nonlinearity instead of the distinguishable ones.
Normal 0 false false false IN X-NONE X-NONE MicrosoftInternetExplorer4 We have discussed the partition function of the Bose-Einstein condensation in parabolic trap associated to the one-dimensional Gross-Pitaevskii equation. The partition function itself is constructed by considering all the energy levels of the macroscopic quantum oscillator which is similar to statistical mechanics. The solutions of the energy levels for this case can be derived by pursuing the method proposed by Kivshar et al. that applies the time-independent perturbation theory. In their paper, they demonstrated that the one-dimensional Gross Pitaevskii equation can be treated as the one-dimensional macroscopic quantum oscillator on condition that the nonlinearity is very small. Moreover, they found the analytical expression for the ground state energy by applying the method. However, the higher level states were not explicitly provided. In this research we followed up on their former work to derive explicitly the other states in order to formulate the partition function. However, we did not find the closed form of the partition function since the results of nonlinear term integral could not form the recursion relation. As a consequence, not only should the partition function but also the Helmholtz free energy and entropy should be reevaluated to check their convergences. Normal 0 false false false IN X-NONE X-NONE MicrosoftInternetExplorer4 Keywords: Gross-Pitaevskii equation, partition function, quantum oscillator, thermodinamical properties.
We present theoretical aspects concerning the thermodynamics of an ideal bosonic gas trapped by a harmonic potential. Working in the Grand Canonical ensemble we are able to properly identify the extensive thermodynamic variable equivalent to the volume and the intensive thermodynamic variable equivalent to the pressure. These are called the "harmonic volume" and the "harmonic pressure" and their physical meaning is discussed. With these variables, the problem of Bose-Einstein condensation is studied in terms of the behavior of the corresponding equation of state and in terms of measurable susceptibilities such as the heat capacities, the isothermal compressibility and the coefficient of thermal expansion. From the analysis, an interesting analogy with Black-Body radiation emerges, showing that at and below the critical temperature, the non-condensate fraction of atoms behaves thermodynamically like a gas of massless particles.
We have derived some excitation states of the one-dimensional Gross-Pitaevskii equation coupled by the gravitational potential. The methods that we have used here are taken by pursuing the recent work of Kivshar et. al. by considering the equation as a macroscopic quantum oscillator. To obtain the states, we have made the appropriate transformation to reduce the three-dimensional Gross-Pitaevskii equation into the one-dimensional Gross-Pitaevskii equation and applying the time-independent perturbation theory in the general solution of the one-dimensional Gross-Pitaevskii equation as a linear superposition of the normalized eigenfunctions of the Schrödinger equation for the harmonic oscillator potential. Moreover, we also impose the condition by assuming that some terms in the equation should be so small in order to preserve the use of the perturbation method.