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Applied Magnetic Resonance

Many-Spin Entanglement in Zigzag Spin Chain in Multiple Quantum NMR

G. A. Bochkin, Sergey G. Vasil’ev, Serge I. Doronin, E. I. Kuznetsova, I. D. Lazarev, Edward B. Fel’dman

Published Jun 23, 2020• 5 citations
Publisher
DOI
10.1007/s00723-020-01206-0

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In this paper, we aim to provide a theoretical study of thermal entanglement of two qubits coupled to a spin chain with considering multiple-spin correlations which accompanies decay in multiple quantum nuclear magnetic resonance (MQ NMR) system. We show an explicit connection between the coherence factor and entanglement, and numerically and analytically study the dynamical process of entanglement in weak coupling cases for dipolar ordered initial states. We provide results that the entanglement evolution depends not only on the coupling constant between central two qubits and the system-environment couplings but also on temperature and the number of spins in chain.
A phenomenological theory of spin-lattice relaxation of multiple-quantum coherences in systems of two dipolar coupled spins at low temperatures is developed. Intensities of multiple-quantum NMR coherences depending on the spin-lattice relaxation time are obtained. It is shown that the theory is also applicable to finite spin chains when the approximation of nearest neighbour interaction is used. An application of this theory to an estimation of the influence of decoherence processes on quantum entanglement and its fluctuations is briefly discussed.
We investigate numerically the time dependence of the multiple quantum coherences and entanglement in linear chains up to nine nuclear spins of 1∕21∕21∕2 coupled by the dipole-dipole interactions. Two models are considered: (1) a spin chain with nearest-neighbor dipole-dipole interactions and (2) a more realistic model with interactions between all spins. It is shown that the entangled states appear between remote particles which do not interact directly (model 1), while the interaction between all spins (model 2) not always results in entanglement between remote spins.