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Springer Proceedings in Materials

Equation for Density Matrix Systems of Identical Particles

Boris Volodumurovich Bondarev

Published Jan 1, 2020• 0 citations
Publisher
DOI
10.1007/978-3-030-45120-2_14

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Cambridge University Press eBooks•Jun 23, 2005•0 citations
We consider an open quantum many-particle system in which there are dissipative processes. The evolution of this system is described by a kinetic equation for the density matrix. From the equation describing a random Markov process in this system, we obtain an equation for the single-particle statistical operator. This equation describes the evolution of a system of identical particles in a mean-field approximation. The equation for interacting particles in thermodynamic equilibrium was obtained. The distribution function of a system of interacting electrons in metals has multivalence in a certain region of wave vectors. Among many solutions one is isotropic. Other solutions have the anisotropy of the electron distribution over the wave vectors. The anisotropy arises as a result of repulsion and attraction between electrons.
While the dynamic state of a single particle can be specified quantum mechanically in terms of its state function, any rigorous description of the state of a many-particle system would require the complete knowledge of the dynamic state functions of all the particles. That is not always possible. On the other hand, for a large number of particles in, or near, thermal equilibrium in a uniform sample, the principles of statistical mechanics may be invoked to describe the averaged expectation values of the physically observable properties of such a many-particle system. The basic concepts of the density-matrix formalism and the quantum mechanic analog of the classical Boltzmann equation commonly used for optical and magnetic resonance problems of many-particle quantum systems are introduced in this chapter. Applications of this approach to such specific problems as the resonant interaction of electromagnetic radiation with optical media of two-level atoms, nonlinear optics, and the laser rate equations and transient dynamics are discussed in this chapter. Definitions of the density operator and the density matrix Up to this point, in studying the dynamics of quantum mechanic systems, we have assumed that the state of the system can be specified in terms of a precisely known state function |Ψ〉. On the other hand, for a macroscopic medium containing many particles, it is not always possible to know the exact dynamic states of all the particles in the medium, even for physically identical particles.