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Consequences of the renormalization group for the thermodynamics of fluids near the critical point

Marcos Ley-Koo

Published Apr 1, 1979• 1 citation
OpenAlex

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We employ a novel real-time formulation of the functional renormalization group (FRG) to compute universal scaling functions of the thermal diffusivity and the shear viscosity in the vicinity of the liquid-gas critical point, i.e., for the dynamic universality class of Model H from the Halperin-Hohenberg classification. We map out the universal dependence of the transport coefficients on temperature, external magnetic field, and wavenumber, and provide a detailed comparison with the Kawasaki approximation, which is here obtained from a perturbative one-loop approximation to our real-time FRG flow. In contrast to the Kawasaki approximation, the non-perturbative scaling functions from the full real-time FRG flow show a mild dependence on the thermodynamic path towards the critical point. We further compare our FRG results for the universal wavenumber and temperature dependence of the thermal diffusivity with experimental data from critical fluids.
Abstract Using the quantum renormalization group approach, we have investigated the entanglement and critical behavior of an anisotropic XXZ Heisenberg spin chain. The resolution of the quantum renormalization equations yields stable and unstable fixed points, corresponding respectively to the phases and critical point of the system. It is shown that a quantum phase transition exists at a critical anisotropy parameter , separating the Néel phase from the spin-fluid phase. Then, the concurrence between two blocks of sites and the quantum coherence have been calculated and presented for various renormalization group iterations. In the thermodynamic limit, i.e. , for higher renormalization steps, the concurrence and coherence exhibit two different saturated values in the two regions separated by Δ c . The first derivative of concurrence diverges at the critical point as the size of the chain increases, showing nonanalytic behavior. Moreover, the scaling behavior has been examined near the critical point with some universal exponential scaling laws.
In this chapter, we investigate the concept of scaling, in particular the scaling hypothesis that has proved so important in the development of the modern theory of critical phenomena. Scaling refers to the way in which properties such as the susceptibility behave in the critical region as they approach infinity (or zero). In this discussion, it is important to be specific about the thermodynamic field variables used to represent the system as well as the direction in which the critical point is approached. A useful schematic in this regard is shown in figure 9.1, which shows phase coexistence diagrams for both an Ising-type magnet and a typical fluid. The fields for the magnet are (H, T ) while for the fluid they are (μ, T ). We note immediately from this figure that the magnet’s coexistence curve is coincident with the H = 0 axis and symmetric about the M = 0 axis. However, these features do not reflect in the corresponding diagrams for the fluid, with important implications for a scaling analysis in this system, which we take up later in this chapter. We illustrate the basic critical scaling laws using the Ising (magnet) system; however, the fact that similar scaling laws also apply to fluids is an important consequence of critical-point universality, a topic we have often alluded to in this text and which is discussed in more detail in chapter 10 dealing with the renormalization-group method.