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Journal of Physics Conference Series

Collisions between cold molecules in a superconducting magnetic trap

Martin Pitzer, Yair Segev, Michael Karpov, N Akerman, Julia Narevicius, Edvardas Narevicius

Published Jan 1, 2020• 5 citations
Publisher

Abstract

Synopsis We decelerate and trap molecular oxygen using time-dependent magnetic fields and superconducting magnets. The density-dependent, non-exponential decay in particle number provides a clear proof of molecule-molecule collisions within the trapped ensemble. The spatial distribution of molecules in the trap is found to change over time, allowing to set limits on the ratio between the elastic and inelastic collision cross sections. Our experimental scheme opens up new possibilities for studying quantum effects in chemistry as well as for evaporative cooling of molecules.

DOI
10.1088/1742-6596/1412/12/122001

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Abstract Collisions between cold molecules are essential for studying fundamental aspects of quantum chemistry, and may enable the formation of quantum degenerate molecular matter by evaporative cooling. However, collisions between trapped, naturally occurring molecules have not been directly observed so far owing to the low collision rates of dilute samples. Here we report the direct observation of collisions between cold trapped molecules, without the need for laser cooling. We magnetically capture molecular oxygen in an 800-millikelvin-deep superconducting trap and set bounds on the ratio between the elastic- and inelastic-scattering rates—the key parameter determining the feasibility of evaporative cooling. We further co-trap atoms and molecules and identify collisions between them, paving the way for studies of cold interspecies collisions in a magnetic trap.

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We present a theoretical study of molecular-trap loss induced by collisions with slow atomic beams based on an explicit analysis of collision kinematics in the laboratory frame and a rigorous quantum description of atom-molecule scattering in external fields. The theory is applied to elucidate the effects of nonuniform magnetic and optical trapping fields on low-temperature collisions of OH ($J=3/2,{M}_{J}=3/2,f$) molecules with $^{4}\mathrm{He}$ atoms. Our calculations quantify the extent to which both elastic and inelastic cross sections are suppressed by external trapping fields, clarify the role of small-angle scattering in trap loss, and may benefit future experiments on collisional cooling of molecules in electromagnetic traps. The calculated cross sections for trap loss in $^{4}\mathrm{He}$ $+$ OH collisions are consistent with recent experimental observations at low beam energies [B. C. Sawyer et al., Phys. Rev. Lett. 101, 203203 (2008)], demonstrating the importance of including the effects of nonuniform trapping fields in theoretical simulations of cold collision experiments with trapped molecules and slow atomic beams.

Physical Review A•Aug 10, 2010•16 citations
Synopsis We decelerate and trap molecular oxygen using time-dependent magnetic fields and superconducting magnets. The density-dependent, non-exponential decay in particle number provides a clear proof of molecule-molecule collisions within the trapped ensemble. The spatial distribution of molecules in the trap is found to change over time, allowing to set limits on the ratio between the elastic and inelastic collision cross sections. Our experimental scheme opens up new possibilities for studying quantum effects in chemistry as well as for evaporative cooling of molecules.
Abstract Collisions between cold molecules are essential for studying fundamental aspects of quantum chemistry, and may enable the formation of quantum degenerate molecular matter by evaporative cooling. However, collisions between trapped, naturally occurring molecules have not been directly observed so far owing to the low collision rates of dilute samples. Here we report the direct observation of collisions between cold trapped molecules, without the need for laser cooling. We magnetically capture molecular oxygen in an 800-millikelvin-deep superconducting trap and set bounds on the ratio between the elastic- and inelastic-scattering rates—the key parameter determining the feasibility of evaporative cooling. We further co-trap atoms and molecules and identify collisions between them, paving the way for studies of cold interspecies collisions in a magnetic trap.
Abstract Trapping of atoms and molecules in electrostatic, magnetic and optical traps has enabled studying atomic and molecular interactions on a timescale of many seconds, allowing observations of ultra-cold collisions and reactions. Here we report the first magnetic deceleration and trapping of neutral carbon atoms in a static magnetic trap. When co-trapping the carbon atoms with oxygen molecules in a superconducting trap, the carbon signal decays in a non-exponential manner, consistent with the decay model describing losses resulting from atom-molecule collisions. Our findings pave the way to studying both elastic and inelastic collisions of species that cannot be laser cooled, and specifically may facilitate the observation of reactions at low temperatures, such as C + O2 → CO + O, which is important in interstellar chemistry.
Collision cross sections and rate constants between two ground-state oxygen molecules are investigated theoretically at translational energies below $\ensuremath{\sim}1$ K and in zero magnetic field. We present calculations for elastic and spin-changing inelastic collision rates for different isotopic combinations of oxygen atoms as a prelude to understanding their collisional stability in ultracold magnetic traps. A numerical analysis has been made in the framework of a rigid-rotor model that accounts fully for the singlet, triplet, and quintet potential-energy surfaces in this system. The results offer insights into the effectiveness of evaporative cooling and the properties of molecular Bose-Einstein condensates, as well as estimates of collisional lifetimes in magnetic traps. Specifically, 17O2{}^{17}{\mathrm{O}}_{2}17O2​ looks like a good candidate for ultracold studies, while 16O2{}^{16}{\mathrm{O}}_{2}16O2​ is unlikely to survive evaporative cooling. Since 17O2{}^{17}{\mathrm{O}}_{2}17O2​ is representative of a wide class of molecules that are paramagnetic in their ground state we conclude that many molecules can be successfully magnetically trapped at ultralow temperatures.
Research in the field of cold polar molecules is progressing rapidly. An array of interesting\ntopics is being developed including precision measurement and fundamental tests, quantum phase transitions, and ultracold chemistry. In particular, dipolar molecules in well-defined quantum states enable exquisite control of their interactions via applied electric fields. The long-range, anisotropic interaction between dipolar molecules leads to new collision dynamics that could be used for novel collective effects, quantum state engineering, and information processing. The focus of this Thesis is the production of cold samples of neutral OH molecules via Stark deceleration and magnetic trapping for novel collision experiments. This novelty results from our combination of cold external beams and trapped target molecules which facilitates observation of dipolar effects as well as low temperature collision resonances. The large permanent electric dipole moment of OH allows us to precisely tune the lab-frame velocity of the molecular packets from ∼ 500 m/s to rest. We have magnetically trapped OH packets at the terminus of our Stark decelerator at a temperature of 70 mK and density of 106 cm−3. With improved understanding of Stark deceleration, we optimize the decelerator efficiency and its coupling to the magnetic trap. Our latest trap design uses permanent ring magnets to create a three-dimensional magnetic quadrupole field. Use of magnetically trapped OH molecules for collision experiments with external beams allow us the unique opportunity of observing both elastic and inelastic collisions. In addition, the trap confinement yields sensitivity to differential elastic cross sections at low collision energies. This open magnetic trap has allowed measurement of collision cross sections between trapped OH and external supersonic beams of He and D2, the latter of which is of astrophysical interest due to the role of H2-OH collisions in pumping interstellar OH megamasers. The combination of trapped OH molecules and temperature tuned beams of He and D2 has facilitated measurement of the lowest-energy D2-OH collision cross sections yet reported. More recently, we report the first observation of electric-field dependent cross sections between two different species of cold polar molecules - OH and ND3 - thereby demonstrating control over molecular scattering in the cold regime. By combining for the first time the production techniques of Stark deceleration and buffer gas cooling, we increase the molecular interaction time by∼ 105 over traditional crossed-beam experiments to gain enhanced sensitivity at the characteristic densities of cold molecule production.
We present a theoretical study of molecular-trap loss induced by collisions with slow atomic beams based on an explicit analysis of collision kinematics in the laboratory frame and a rigorous quantum description of atom-molecule scattering in external fields. The theory is applied to elucidate the effects of nonuniform magnetic and optical trapping fields on low-temperature collisions of OH (J=3/2,MJ=3/2,fJ=3/2,{M}_{J}=3/2,fJ=3/2,MJ​=3/2,f) molecules with 4He^{4}\mathrm{He}4He atoms. Our calculations quantify the extent to which both elastic and inelastic cross sections are suppressed by external trapping fields, clarify the role of small-angle scattering in trap loss, and may benefit future experiments on collisional cooling of molecules in electromagnetic traps. The calculated cross sections for trap loss in 4He^{4}\mathrm{He}4He +++ OH collisions are consistent with recent experimental observations at low beam energies [B. C. Sawyer et al., Phys. Rev. Lett. 101, 203203 (2008)], demonstrating the importance of including the effects of nonuniform trapping fields in theoretical simulations of cold collision experiments with trapped molecules and slow atomic beams.