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Nonlinear bulk absorption in Y 3 - x Er x Al 5 O 12 crystals

V I Zhekov, T. M. Murina, А. В. Попов, Alexander M. Prokhorov

Published Mar 1, 1987• 1 citation
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This Letter presents results of analysis of the absorption spectra of AlN:Er 3+ bulk crystals. In the spectral of 370–700 nm, absorption lines responsible for intraconfiguration electron transition from the ground state 4 I 15/2 to the excited states of Er 3+ ions are found. Transitions to the levels of the 4 F 9/2 , 2 H 11/2 , and 4 G 11/2 states at 2 K are studied in detail. The number of observed lines for these transitions fully agrees with that theoretically possible for f – f electron transitions in Er 3+ ions found in a noncubic crystal field. The small width of the observed lines and their number indicate that erbium ions displace mostly one regular crystal position. Most probably, Er 3+ occupies the position of Al. Energy positions of excited states for the considered transitions are determined.