The fine-structure splitting of the
4F state of atomic sodium is determined using the technique of two-photon spectroscopy with a resonant intermediate state. The sensitivity of this Doppler-free technique allows observation of the electric-dipole-forbidden $3S\ensuremath{\rightarrow}4F$ two-photon transition. The
4F fine-structure splitting is found to be 229\ifmmode\pm\else\textpm\fi{}4 MHz. Its sign and magnitude are hydrogenic, in complete contrast to the
D levels of Na.