The Wave Mechanics of an Atom with a non-Coulomb Central Field. Part III. Term Values and Intensities in Series in Optical Spectra
Douglas Rayner Hartree
In two recent papers the writer has given an account of a practical method of finding the characteristic values and functions of Schrödinger's wave equations for a given non-Coulomb central field. For terms of optical spectra the method is effectively the following. We take the wave equation in the form and require the values of ɛ for the solutions which are zero at the origin and at r = ∞. We consider the result of integrating this equation outwards from P = 0 at r = 0 to a radius r0 at which the deviation from a Coulomb field is negligible, and inwards from P = 0 at r = ∞ to the same radius, with a given value of ɛ; the characteristic values are those values for which these two solutions join smoothly on to one another, i.e. for which they have the same value of η = −P′/P at this radius. For a given ɛ, the solution zero at the origin depends on the particular atom; the solution zero at infinity can be expressed in a form independent of any particular atom.
Mathematical Proceedings of the Cambridge Philosophical Society•Jul 1, 1928•232 citations