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APS

Dissociative Ionization of Na 2 via Repulsive Rydberg States

Hong Chen, Lutz Hüwel

Published May 1, 2003• 0 citations
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Ionization of sodium and rubidium nS , nP , and nD Rydberg atoms by blackbody radiation

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Results of theoretical calculations of ionization rates of Rb and Na Rydberg atoms by blackbody radiation (BBR) are presented. Calculations have been performed for $nS$, $nP$, and $nD$ states of Na and Rb, which are commonly used in a variety of experiments, at principal quantum numbers $n=8--65$ and at three ambient temperatures of 77, 300, and $600\phantom{\rule{0.3em}{0ex}}\mathrm{K}$. A peculiarity of our calculations is that we take into account the contributions of BBR-induced redistribution of population between Rydberg states prior to photoionization and field ionization by extraction electric field pulses. The obtained results show that these phenomena affect both the magnitude of measured ionization rates and shapes of their dependences on $n$. The calculated ionization rates are compared with the results of our earlier measurements of BBR-induced ionization rates of Na $nS$ and $nD$ Rydberg states with $n=8--20$ at $300\phantom{\rule{0.3em}{0ex}}\mathrm{K}$. A good agreement for all states except $nS$ with $n>15$ is observed. We also present the useful analytical formulas for the quick estimation of BBR ionization rates of Rydberg atoms.

arXiv:physics/0702192•Physical Review A•May 30, 2007•47 citations
Results of theoretical calculations of ionization rates of Rb and Na Rydberg atoms by blackbody radiation (BBR) are presented. Calculations have been performed for nSnSnS, nPnPnP, and nDnDnD states of Na and Rb, which are commonly used in a variety of experiments, at principal quantum numbers n=8−−65n=8--65n=8−−65 and at three ambient temperatures of 77, 300, and 600K600\phantom{\rule{0.3em}{0ex}}\mathrm{K}600K. A peculiarity of our calculations is that we take into account the contributions of BBR-induced redistribution of population between Rydberg states prior to photoionization and field ionization by extraction electric field pulses. The obtained results show that these phenomena affect both the magnitude of measured ionization rates and shapes of their dependences on nnn. The calculated ionization rates are compared with the results of our earlier measurements of BBR-induced ionization rates of Na nSnSnS and nDnDnD Rydberg states with n=8−−20n=8--20n=8−−20 at 300K300\phantom{\rule{0.3em}{0ex}}\mathrm{K}300K. A good agreement for all states except nSnSnS with n>15n>15n>15 is observed. We also present the useful analytical formulas for the quick estimation of BBR ionization rates of Rydberg atoms.