Microwave multiphoton excitation of helium Rydberg atoms: The analogy with atomic collisions
Willem van de Water, K. A. H. van Leeuwen, Suzanne Yoakum +5 more
We study multiphoton transitions in helium Rydberg atoms subjected to a microwave electric field of fixed frequency but varying intensity. For each principal quantum number in the range n=25--32, the ${n}^{3}$S to ${n}^{3}$(L>2), n=25--32, transition probability exhibits very sharp structures as a function of the field amplitude. Their positions could be reproduced precisely using a Floquet Hamiltonian for the interaction between atom and field. Their shapes are determined by the transients of field turn-on and turn-off in a way that makes a close analogy with the theory of slow atomic collisions.
Physical Review Letters•Aug 14, 1989•14 citations