Effects of Electric Fields upon Autoionizing States of Sr
Richard R. Freeman, Gary C. Bjorklund
We report the first observation of significant perturbations by external fields of the autoionizing resonance structure of a two-electron atoms. The effects of electric fields up to 20 kV/cm on autoionizing resonances in Sri were observed by three-photon ionization spectroscopy in an atomic beam. In addition to effects analogous to those for bound Stark states of a one-electron Rydberg atom, we observed a new effect: The characteristic shapes and widths of autoionizing resonances (Fano-Beutler profiles) can be strongly influenced by electric fields.
Physical Review Letters•Jan 9, 1978•45 citations