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The Journal of Chemical Physics

Temporally stable rotational coherent states for molecular simulations. I. Spherical and linear rotor cases

Christopher J. Stopera, Jorge A. Morales

Published Apr 7, 2020• 4 citations
Publisher

Abstract

We reformulate a previous rotational coherent state (CS) to obtain temporally stable (TS) CSs for the spherical rotor (SR) and linear rotor (LR): TSSR and TSLR CSs, respectively. Being TS, the new CSs remain within their own classes during dynamics by evolving exclusively through their CS parameters. The new TS CSs are now appropriate to reconstruct quantum rotational properties from classical-mechanics simulations of chemical reactions. Following literature precedents, we enforce temporal stability by incorporating action-angle-related phase factors into the parameters of the original CS. In addition, to elucidate CS quantum reconstruction procedures, we derive one more rotational CS from a quantum electron nuclear dynamics description of a diatomic rotor (DR). The DR CS and the TSLR CS are not identical but display similar structures and properties. We rigorously demonstrate and examine the key properties of the three CSs: continuity, resolution of unity, temporal stability, action identity, minimum uncertainty relationships, and quasi-classical behavior. Finally, we present computer simulations of the CSs dynamics and an application of them to predict CO rotational excitation probabilities in the Li+ + CO reaction. CS results agree satisfactorily with experimental ones and encourage future applications in chemical dynamics, statistical mechanics, spectroscopy, nuclear physics, quantum coherence, and quantum computing.

DOI
10.1063/5.0002424

Related papers

Temporally stable rotational coherent states for molecular simulations. II. Symmetric rotor case

Christopher J. Stopera, Jorge A. Morales

Following our preceding work on spherical and linear rotors [C. Stopera and J. A. Morales, J. Chem. Phys. 152, 134112 (2020)], we reformulate an earlier rotational coherent state (CS) set to obtain a temporally stable (TS) CS set for symmetric rotors. Being TS, the new CSs remain within its own set during dynamics by evolving exclusively through their parameters. The TS CS set is now appropriate to reconstruct quantum rotational properties from classical-mechanics simulations of chemical reactions. Following literature precedents, we enforce temporal stability by incorporating action-angle-related phase factors into two parameters of the original CS set. Proofs and final expressions of the symmetric-rotor CS turn out more intricate than those of its spherical-rotor counterpart. We demonstrate and examine the key properties of the new CS set: continuity, resolution of unity, temporal stability, action identity, minimum uncertainty relationships, and quasi-classical behavior. Regarding the last property, we demonstrate that the body-fixed z-component of the CS angular momentum average evolves exactly as its classical counterpart, and that the x- and y-components display an astonishing analogy with their classical counterparts in terms of functional form, precession angular velocities, amplitudes, and phases. We elucidate some of these properties via computer simulations of a rotating benzene molecule represented with the CS set. We discuss the utilization of this CS set to reconstruct quantum rotational properties of symmetric-rotor molecules from classical-mechanics simulations. The new CS set is appropriate to establish quantum-classical connections for rotational properties in chemical dynamics, statistical mechanics, spectroscopy, nuclear physics, and quantum computing.

The Journal of Chemical Physics•May 16, 2022•0 citations

A new class of coherent states and it's properties.

Abdlgader Mohamed

The study of coherent states (CS) for a quantum mechanical system has \nreceived a lot of attention. The definition, applications, generalizations of \nsuch states have been the subject of work by researchers. A common starting \npoint of all these approaches is the observation of properties of the original \nCS for the harmonic oscillator. It is well-known that they are described \nequivalently as (a) eigenstates of the usual annihilation operator, (b) from \na displacement operator acting on a fundamental state and (c) as minimum \nuncertainty states. What we observe in the different generalizations proposed \nis that the preceding definitions are no longer equivalent and only some of \nthe properties of the harmonic oscillator CS are preserved. \nIn this thesis we propose to study a new class of coherent states and \nits properties. We note that in one example our CS coincide with the ones \nproposed by Glauber where a set of three requirements for such states has \nbeen imposed. The set of our generalized coherent states remains invariant \nunder the corresponding time evolution and this property is called temporal \nstability. Secondly, there is no state which is orthogonal to all coherent states (the coherent states form a total set). The third property is that we \nget all coherent states by acting on one of these states [¿fiducial vector¿] with \noperators. They are highly non-classical states, in the sense that in general, \ntheir Bargmann functions have zeros which are related to negative regions of \ntheir Wigner functions. Examples of these coherent states with Bargmann \nfunction that involve the Gamma and also the Riemann ¿ functions are represented. \nThe zeros of these Bargmann functions and the paths of the zeros \nduring time evolution are also studied.

•Jan 1, 2011•0 citations

On rotational coherent states in molecular quantum dynamics

Jorge A. Morales, Erik Deumens, Yngve Öhrn

Coherent states suitable for the description of molecular rotations are developed and their connection to similar coherent states in the literature are explored. In particular their quasiclassical properties are developed. The use of such coherent states in time-dependent electron nuclear dynamics studies of molecular collision processes is discussed.

Journal of Mathematical Physics•Feb 1, 1999•38 citations

Construction of the dual family of Gazeau–Klauder coherent states via temporally stable nonlinear coherent states

R. Roknizadeh, Mohammad Kazem Tavassoly

Using the analytic representation of the so-called Gazeau–Klauder coherent states (CSs), we shall demonstrate that how a new class of generalized CSs, namely the family of dual states associated with theses states, can be constructed through viewing these states as temporally stable nonlinear CSs. Also we find that the ladder operators, as well as the displacement type operator corresponding to these two pairs of generalized CSs, may be easily obtained using our formalism, without employing the supersymmetric quantum mechanics (SUSYQM) techniques. Then, we have applied this method to some physical systems with known spectrum, such as Pöschl–Teller, infinite well, Morse potential and hydrogenlike spectrum as some quantum mechanical systems. Finally, we propose the generalized form of the Gazeau–Klauder CS and the corresponding dual family.

arXiv:quant-ph/0411094•Journal of Mathematical Physics•Mar 28, 2005•49 citations

Coherent states: a contemporary panorama

S. Twareque Ali, Jean-Pierre Antoine, Fabio Bagarello +1 more

Coherent states (CS) of the harmonic oscillator (also called canonical CS) were introduced in 1926 by Schrödinger in answer to a remark by Lorentz on the classical interpretation of the wave function. They were rediscovered in the early 1960s, first (somewhat implicitly) by Klauder in the context of a novel representation of quantum states, then by Glauber and Sudarshan for the description of coherence in lasers. Since then, CS have grown into an extremely rich domain that pervades almost every corner of physics and have also led to the development of several flourishing topics in mathematics. Along the way, a number of review articles have appeared in the literature, devoted to CS, notably the 1985 reprint volume of Klauder and Skagerstam [1], the 1990 review paper by Zhang et al [2], the 1993 Oak Ridge Conference [3] and the 1995 review paper by Ali et al [4]. Textbooks also have been published, among which one might mention the ground breaking text of Perelomov [5] focusing on the group-theoretical aspects, that of Ali et al [6] 1 analyzing systematically the mathematical structure beyond the group-theoretical approach and also the relation to wavelet analysis, that of Dodonov and Man'ko [7] mostly devoted to quantum optics, that of Gazeau [8] more oriented towards the physical, probabilistic and quantization aspects, and finally the very recent one by Combescure and Robert [9]. In retrospect, one can see that the development of CS has gone through a two-phase transition. First, the (simultaneous) discovery in 1972 by Gilmore and Perelomov that CS were rooted in group theory, then the realization that CS can be defined in a purely algebraic way, as an eigenvalue problem or by a series expansion (Malkin and Man'ko 1969, Barut and Girardello 1971, Gazeau and Klauder 1999; references to the original articles may be found in the textbooks quoted above). Both facts resulted in an explosive expansion of the CS literature. We thought, therefore, that the time was ripe to devote a special issue of Journal of Physics A: Mathematical and Theoretical to CS. However, because of limitations of space and time, it would have been impossible to get a fully representative cross-section of papers, covering all the different facets of the subject. Consequently, we have selected 37 articles, including some by a few of the originators of the field. We thank all the authors for submitting their up-to-date thoughts on this fascinating subject. The contents of this special issue are subdivided into five categories: (1) review papers; (2) physics-oriented CS; (3) physics and quantum information; (4) mathematics, general topics; and (5) mathematics, particular problems. (1) Review papers We start with five review papers. The first paper, by Klauder, surveys the many possible applications of affine variables, both in classical and quantum physics. The second, by Sanders, proposes a grand tour of entangled CS, which are present in many fields, such as quantum optics, quantum information processing, etc. The next paper, by Rowe, surveys the field of vector CS and the attendant group representation problems (including induced representations). Then Oriti et al describe a particular class of CS relevant to (loop) quantum gravity. Finally, Combescure and Robert present a comprehensive review of fermionic CS, including all mathematical details. (2) Physics-oriented CS The six contributions in this section deal with specific physical problems: (i) Dajka–Luczka study Gazeau–Klauder cat states associated with a nonlinear Kerr oscillator, instead of the usual canonical CS leading to Schrödinger cat states; (ii) Angelova et al discuss squeezed CS associated with a 1D Morse potential, used in molecular physics; (iii) Bagrov et al study CS in a magnetic solenoid field and prove their completeness; (iv) Blasone–Jizba treat Nambu–Goldstone dynamics in spontaneously broken symmetries, using CS functional integrals; (v) Calixto et al describe accelerated relativistic particles in the context of spontaneous breakdown of conformal SU(2,2) symmetry, using SU(2,2) CS; and (vi) Mortazavi–Tavassoly study f -deformed charge CS and their physical properties (nonclassical features, sub-Poissonian statistical behavior, etc). (3) Physics and quantum information The second group of physically related CS contains four contributions with a distinct quantum information theoretic flavor. First, Thilagam describes the dynamical behavior of entanglement of a pair of qubits (excitons), using a CS basis. Next, Lavoie–de Guise study SU(3) intelligent states (i.e., minimal uncertainty states), of interest in the quantum information community. Then Muñoz constructs discrete CS for n qubits. Finally, Wagner–Kendon explore the continuous variable Deutsch–Jozsa algorithm known in quantum computing in a discrete formulation. (4) Mathematics, general topics In this subgroup, there are eight papers dealing with general properties of CS, independently of any particular system or application. A whole series discusses the interaction between CS and various mathematical objects: pseudodifferential operators and Weyl calculus (Unterberger); induced representations of the affine group and intertwining operators (Elmabrok–Hutnik); measure-free CS and reproducing kernels (Horzela–Szafraniec); extremal POV measures (Heinosaari–Pellonpää); Hilbert W*-modules (Bhattacharyya–Roy); Toeplitz operators (Hutníková–Hutník); and operator localization and homogeneous structure of nilpotent Lie groups (Kisil). In addition, Balazs et al consider multipliers for continuous frames, including CS or wavelet frames. (5) Mathematics, particular problems The second group of mathematically oriented papers contains 14 contributions, devoted to CS in particular systems. We start with a paper by Gilmore, which explores the (sometimes chaotic) evolution of atomic CS under a time-periodic driving field, using sphere maps S 2 → S 2 . Next, we include a paper on CS on the 2-sphere in a magnetic field (Hall–Mitchell); a paper on CS for a quantum particle on a Möbius strip (Cirilo–Lombardo); a discussion of quantization on the circle (Chadzitaskos et al ); SUSY CS for Pöschl–Teller potentials (Bergeron et al ); generalized Bargmann functions and von Neumann lattices (Vourdas et al ); partial reconstruction for a finite CS system, using the Fock–Bargmann representation (Calixto et al ); phase operators for SU(3) irreps, thus for finite quantum systems (de Guise); semiclassical CS in periodic potentials (Carles–Sparber); complexified CS with non-Hermitian Hamiltonians (Graefe–Schubert); minimal uncertainty states in the context of (semisimple) group representation theory (Oszmaniec); localization operators in the time-frequency domain, i.e., in Gabor analysis (Muzhikyan–Avanesyan); and, finally, two papers about fermionic CS (Daoud–Kibler and Trifonov). This brief description illustrates perfectly the extreme versatility of the CS concept. As already stressed, coherent states constitute nowadays a flourishing research topic, with applications to a wide spectrum of domains. Indeed, CS are everywhere in physics: condensed matter physics, atomic physics, nuclear and particle physics, quantum optics, dynamics—both quantum and classical potentials—quantum gravity, quantization and quantum information theory. On the other hand, CS have grown into a fully-fledged domain in mathematics, incorporating many tools such as group representations, POV measures, frames, holomorphic functions, orthogonal polynomials and so on. Interestingly enough, the majority of contributions to this special issue (22 out of 37) are mathematically minded, demonstrating the widespread interest CS have generated in various areas of mathematics. A third field related to CS (but almost not represented in the present collection) is signal processing. Indeed both Gabor analysis and wavelet analysis derive in the first place from CS theory, namely, CS associated to the Weyl–Heisenberg and the ax + b group, respectively. Here too, a tremendous development has taken place in recent years, another testimony to the richness of the notion of CS. We leave it to the jury of public opinion to judge whether the call for a special issue of the journal, devoted to coherent states, has been justified. References [1] Klauder J R and Skagerstam B S 1985 Coherent States—Applications in Physics and Mathematical Physics (Singapore: World Scientific) [2] Zhang W-M, Feng D H and Gilmore R 1990 Coherent states: theory and some applications Rev. Mod. Phys. 62 867–927 [3] Feng D H, Klauder J R and Strayer M (ed) 1994 Coherent States: Past, Present and Future (Singapore: World Scientific) [4] Ali S T, Antoine J-P, Gazeau J-P and Mueller U A 1995 Coherent states and their generalizations: a mathematical overview Rev. Math. Phys. 7 1013–104 [5] Perelomov A M 1986 Generalized Coherent States and Their Applications (New York: Springer) [6] Ali S T, Antoine J-P and Gazeau J-P 2000 Coherent States, Wavelets and Their Generalizations (New York: Springer) [7] Dodonov V V and Man'ko V I (ed) 2003 Theory of Nonclassical States of Light (London: Taylor & Francis) [8] Gazeau J-P 2009 Coherent States in Quantum Physics (Berlin: Wiley) [9] Combescure M and Robert D 2012 Coherent States and Applications in Mathematical Physics (New York: Springer) 1 A second edition of that volume is in preparation.

Journal of Physics A Mathematical and Theoretical•May 30, 2012•9 citations

The asymmetric rotor as a model for localization

A. R. P. Rau

Together with the pendulum, the symmetric and asymmetric rotors are standard models, well studied in both classical and quantum physics. In the limit of high angular momentum $J$, the quantum problem of an asymmetric rotor approaches the classical limit, which is characterized by one unstable and two stable motions. Rotations with respect to the axes with maximum and minimum moments of inertia are stable, while the rotations about the intermediate axis are unstable. Upon diagonalization of the rotor's Hamiltonian at fixed $J$, most eigenvectors are seen to be localized around the directions of maximum and minimum moment of inertia. The asymmetric rotor displays in this regard localization similar to that in many atomic and nuclear few-body systems, wherein external interactions mix degenerate states, particularly at high excitation. Indeed, there is a complete one-to-one correspondence between the rotor and these systems, with the principal ($n$) and angular momentum ($l$) quantum numbers mapping onto $J$, and its azimuthal projection $M$, respectively, for the rotor. Localization at a maximum or a saddle point of a potential is of considerable significance in a variety of problems.

Reviews of Modern Physics•Apr 1, 1992•16 citations
We reformulate a previous rotational coherent state (CS) to obtain temporally stable (TS) CSs for the spherical rotor (SR) and linear rotor (LR): TSSR and TSLR CSs, respectively. Being TS, the new CSs remain within their own classes during dynamics by evolving exclusively through their CS parameters. The new TS CSs are now appropriate to reconstruct quantum rotational properties from classical-mechanics simulations of chemical reactions. Following literature precedents, we enforce temporal stability by incorporating action-angle-related phase factors into the parameters of the original CS. In addition, to elucidate CS quantum reconstruction procedures, we derive one more rotational CS from a quantum electron nuclear dynamics description of a diatomic rotor (DR). The DR CS and the TSLR CS are not identical but display similar structures and properties. We rigorously demonstrate and examine the key properties of the three CSs: continuity, resolution of unity, temporal stability, action identity, minimum uncertainty relationships, and quasi-classical behavior. Finally, we present computer simulations of the CSs dynamics and an application of them to predict CO rotational excitation probabilities in the Li+ + CO reaction. CS results agree satisfactorily with experimental ones and encourage future applications in chemical dynamics, statistical mechanics, spectroscopy, nuclear physics, quantum coherence, and quantum computing.
Following our preceding work on spherical and linear rotors [C. Stopera and J. A. Morales, J. Chem. Phys. 152, 134112 (2020)], we reformulate an earlier rotational coherent state (CS) set to obtain a temporally stable (TS) CS set for symmetric rotors. Being TS, the new CSs remain within its own set during dynamics by evolving exclusively through their parameters. The TS CS set is now appropriate to reconstruct quantum rotational properties from classical-mechanics simulations of chemical reactions. Following literature precedents, we enforce temporal stability by incorporating action-angle-related phase factors into two parameters of the original CS set. Proofs and final expressions of the symmetric-rotor CS turn out more intricate than those of its spherical-rotor counterpart. We demonstrate and examine the key properties of the new CS set: continuity, resolution of unity, temporal stability, action identity, minimum uncertainty relationships, and quasi-classical behavior. Regarding the last property, we demonstrate that the body-fixed z-component of the CS angular momentum average evolves exactly as its classical counterpart, and that the x- and y-components display an astonishing analogy with their classical counterparts in terms of functional form, precession angular velocities, amplitudes, and phases. We elucidate some of these properties via computer simulations of a rotating benzene molecule represented with the CS set. We discuss the utilization of this CS set to reconstruct quantum rotational properties of symmetric-rotor molecules from classical-mechanics simulations. The new CS set is appropriate to establish quantum-classical connections for rotational properties in chemical dynamics, statistical mechanics, spectroscopy, nuclear physics, and quantum computing.
The study of coherent states (CS) for a quantum mechanical system has \nreceived a lot of attention. The definition, applications, generalizations of \nsuch states have been the subject of work by researchers. A common starting \npoint of all these approaches is the observation of properties of the original \nCS for the harmonic oscillator. It is well-known that they are described \nequivalently as (a) eigenstates of the usual annihilation operator, (b) from \na displacement operator acting on a fundamental state and (c) as minimum \nuncertainty states. What we observe in the different generalizations proposed \nis that the preceding definitions are no longer equivalent and only some of \nthe properties of the harmonic oscillator CS are preserved. \nIn this thesis we propose to study a new class of coherent states and \nits properties. We note that in one example our CS coincide with the ones \nproposed by Glauber where a set of three requirements for such states has \nbeen imposed. The set of our generalized coherent states remains invariant \nunder the corresponding time evolution and this property is called temporal \nstability. Secondly, there is no state which is orthogonal to all coherent states (the coherent states form a total set). The third property is that we \nget all coherent states by acting on one of these states [¿fiducial vector¿] with \noperators. They are highly non-classical states, in the sense that in general, \ntheir Bargmann functions have zeros which are related to negative regions of \ntheir Wigner functions. Examples of these coherent states with Bargmann \nfunction that involve the Gamma and also the Riemann ¿ functions are represented. \nThe zeros of these Bargmann functions and the paths of the zeros \nduring time evolution are also studied.
Using the analytic representation of the so-called Gazeau–Klauder coherent states (CSs), we shall demonstrate that how a new class of generalized CSs, namely the family of dual states associated with theses states, can be constructed through viewing these states as temporally stable nonlinear CSs. Also we find that the ladder operators, as well as the displacement type operator corresponding to these two pairs of generalized CSs, may be easily obtained using our formalism, without employing the supersymmetric quantum mechanics (SUSYQM) techniques. Then, we have applied this method to some physical systems with known spectrum, such as Pöschl–Teller, infinite well, Morse potential and hydrogenlike spectrum as some quantum mechanical systems. Finally, we propose the generalized form of the Gazeau–Klauder CS and the corresponding dual family.
Coherent states (CS) of the harmonic oscillator (also called canonical CS) were introduced in 1926 by Schrödinger in answer to a remark by Lorentz on the classical interpretation of the wave function. They were rediscovered in the early 1960s, first (somewhat implicitly) by Klauder in the context of a novel representation of quantum states, then by Glauber and Sudarshan for the description of coherence in lasers. Since then, CS have grown into an extremely rich domain that pervades almost every corner of physics and have also led to the development of several flourishing topics in mathematics. Along the way, a number of review articles have appeared in the literature, devoted to CS, notably the 1985 reprint volume of Klauder and Skagerstam [1], the 1990 review paper by Zhang et al [2], the 1993 Oak Ridge Conference [3] and the 1995 review paper by Ali et al [4]. Textbooks also have been published, among which one might mention the ground breaking text of Perelomov [5] focusing on the group-theoretical aspects, that of Ali et al [6] 1 analyzing systematically the mathematical structure beyond the group-theoretical approach and also the relation to wavelet analysis, that of Dodonov and Man'ko [7] mostly devoted to quantum optics, that of Gazeau [8] more oriented towards the physical, probabilistic and quantization aspects, and finally the very recent one by Combescure and Robert [9]. In retrospect, one can see that the development of CS has gone through a two-phase transition. First, the (simultaneous) discovery in 1972 by Gilmore and Perelomov that CS were rooted in group theory, then the realization that CS can be defined in a purely algebraic way, as an eigenvalue problem or by a series expansion (Malkin and Man'ko 1969, Barut and Girardello 1971, Gazeau and Klauder 1999; references to the original articles may be found in the textbooks quoted above). Both facts resulted in an explosive expansion of the CS literature. We thought, therefore, that the time was ripe to devote a special issue of Journal of Physics A: Mathematical and Theoretical to CS. However, because of limitations of space and time, it would have been impossible to get a fully representative cross-section of papers, covering all the different facets of the subject. Consequently, we have selected 37 articles, including some by a few of the originators of the field. We thank all the authors for submitting their up-to-date thoughts on this fascinating subject. The contents of this special issue are subdivided into five categories: (1) review papers; (2) physics-oriented CS; (3) physics and quantum information; (4) mathematics, general topics; and (5) mathematics, particular problems. (1) Review papers We start with five review papers. The first paper, by Klauder, surveys the many possible applications of affine variables, both in classical and quantum physics. The second, by Sanders, proposes a grand tour of entangled CS, which are present in many fields, such as quantum optics, quantum information processing, etc. The next paper, by Rowe, surveys the field of vector CS and the attendant group representation problems (including induced representations). Then Oriti et al describe a particular class of CS relevant to (loop) quantum gravity. Finally, Combescure and Robert present a comprehensive review of fermionic CS, including all mathematical details. (2) Physics-oriented CS The six contributions in this section deal with specific physical problems: (i) Dajka–Luczka study Gazeau–Klauder cat states associated with a nonlinear Kerr oscillator, instead of the usual canonical CS leading to Schrödinger cat states; (ii) Angelova et al discuss squeezed CS associated with a 1D Morse potential, used in molecular physics; (iii) Bagrov et al study CS in a magnetic solenoid field and prove their completeness; (iv) Blasone–Jizba treat Nambu–Goldstone dynamics in spontaneously broken symmetries, using CS functional integrals; (v) Calixto et al describe accelerated relativistic particles in the context of spontaneous breakdown of conformal SU(2,2) symmetry, using SU(2,2) CS; and (vi) Mortazavi–Tavassoly study f -deformed charge CS and their physical properties (nonclassical features, sub-Poissonian statistical behavior, etc). (3) Physics and quantum information The second group of physically related CS contains four contributions with a distinct quantum information theoretic flavor. First, Thilagam describes the dynamical behavior of entanglement of a pair of qubits (excitons), using a CS basis. Next, Lavoie–de Guise study SU(3) intelligent states (i.e., minimal uncertainty states), of interest in the quantum information community. Then Muñoz constructs discrete CS for n qubits. Finally, Wagner–Kendon explore the continuous variable Deutsch–Jozsa algorithm known in quantum computing in a discrete formulation. (4) Mathematics, general topics In this subgroup, there are eight papers dealing with general properties of CS, independently of any particular system or application. A whole series discusses the interaction between CS and various mathematical objects: pseudodifferential operators and Weyl calculus (Unterberger); induced representations of the affine group and intertwining operators (Elmabrok–Hutnik); measure-free CS and reproducing kernels (Horzela–Szafraniec); extremal POV measures (Heinosaari–Pellonpää); Hilbert W*-modules (Bhattacharyya–Roy); Toeplitz operators (Hutníková–Hutník); and operator localization and homogeneous structure of nilpotent Lie groups (Kisil). In addition, Balazs et al consider multipliers for continuous frames, including CS or wavelet frames. (5) Mathematics, particular problems The second group of mathematically oriented papers contains 14 contributions, devoted to CS in particular systems. We start with a paper by Gilmore, which explores the (sometimes chaotic) evolution of atomic CS under a time-periodic driving field, using sphere maps S 2 → S 2 . Next, we include a paper on CS on the 2-sphere in a magnetic field (Hall–Mitchell); a paper on CS for a quantum particle on a Möbius strip (Cirilo–Lombardo); a discussion of quantization on the circle (Chadzitaskos et al ); SUSY CS for Pöschl–Teller potentials (Bergeron et al ); generalized Bargmann functions and von Neumann lattices (Vourdas et al ); partial reconstruction for a finite CS system, using the Fock–Bargmann representation (Calixto et al ); phase operators for SU(3) irreps, thus for finite quantum systems (de Guise); semiclassical CS in periodic potentials (Carles–Sparber); complexified CS with non-Hermitian Hamiltonians (Graefe–Schubert); minimal uncertainty states in the context of (semisimple) group representation theory (Oszmaniec); localization operators in the time-frequency domain, i.e., in Gabor analysis (Muzhikyan–Avanesyan); and, finally, two papers about fermionic CS (Daoud–Kibler and Trifonov). This brief description illustrates perfectly the extreme versatility of the CS concept. As already stressed, coherent states constitute nowadays a flourishing research topic, with applications to a wide spectrum of domains. Indeed, CS are everywhere in physics: condensed matter physics, atomic physics, nuclear and particle physics, quantum optics, dynamics—both quantum and classical potentials—quantum gravity, quantization and quantum information theory. On the other hand, CS have grown into a fully-fledged domain in mathematics, incorporating many tools such as group representations, POV measures, frames, holomorphic functions, orthogonal polynomials and so on. Interestingly enough, the majority of contributions to this special issue (22 out of 37) are mathematically minded, demonstrating the widespread interest CS have generated in various areas of mathematics. A third field related to CS (but almost not represented in the present collection) is signal processing. Indeed both Gabor analysis and wavelet analysis derive in the first place from CS theory, namely, CS associated to the Weyl–Heisenberg and the ax + b group, respectively. Here too, a tremendous development has taken place in recent years, another testimony to the richness of the notion of CS. We leave it to the jury of public opinion to judge whether the call for a special issue of the journal, devoted to coherent states, has been justified. References [1] Klauder J R and Skagerstam B S 1985 Coherent States—Applications in Physics and Mathematical Physics (Singapore: World Scientific) [2] Zhang W-M, Feng D H and Gilmore R 1990 Coherent states: theory and some applications Rev. Mod. Phys. 62 867–927 [3] Feng D H, Klauder J R and Strayer M (ed) 1994 Coherent States: Past, Present and Future (Singapore: World Scientific) [4] Ali S T, Antoine J-P, Gazeau J-P and Mueller U A 1995 Coherent states and their generalizations: a mathematical overview Rev. Math. Phys. 7 1013–104 [5] Perelomov A M 1986 Generalized Coherent States and Their Applications (New York: Springer) [6] Ali S T, Antoine J-P and Gazeau J-P 2000 Coherent States, Wavelets and Their Generalizations (New York: Springer) [7] Dodonov V V and Man'ko V I (ed) 2003 Theory of Nonclassical States of Light (London: Taylor & Francis) [8] Gazeau J-P 2009 Coherent States in Quantum Physics (Berlin: Wiley) [9] Combescure M and Robert D 2012 Coherent States and Applications in Mathematical Physics (New York: Springer) 1 A second edition of that volume is in preparation.
Together with the pendulum, the symmetric and asymmetric rotors are standard models, well studied in both classical and quantum physics. In the limit of high angular momentum JJJ, the quantum problem of an asymmetric rotor approaches the classical limit, which is characterized by one unstable and two stable motions. Rotations with respect to the axes with maximum and minimum moments of inertia are stable, while the rotations about the intermediate axis are unstable. Upon diagonalization of the rotor's Hamiltonian at fixed JJJ, most eigenvectors are seen to be localized around the directions of maximum and minimum moment of inertia. The asymmetric rotor displays in this regard localization similar to that in many atomic and nuclear few-body systems, wherein external interactions mix degenerate states, particularly at high excitation. Indeed, there is a complete one-to-one correspondence between the rotor and these systems, with the principal (nnn) and angular momentum (lll) quantum numbers mapping onto JJJ, and its azimuthal projection MMM, respectively, for the rotor. Localization at a maximum or a saddle point of a potential is of considerable significance in a variety of problems.