The isotropic Hamiltonian ${\mathcal{H}}^{(\ensuremath{\nu})}=\ensuremath{-}J\ensuremath{\Sigma}{j=1}^{}^{N\ensuremath{-}1}\mathrm{S}_{j}\ifmmode\cdot\else\textperiodcentered\fi{}{\mathrm{S}}_{j+1}$ is considered for an open linear chain of
N $\ensuremath{\nu}$-dimensional vector spins
Sj;${\mathcal{H}}^{(\ensuremath{\nu})}$ reduces to the
S=21 Ising, planar, and Heisenberg models for $\ensuremath{\nu}=1,2,\mathrm{and} 3$. The thermodynamic properties (including the susceptibility) of ${\mathcal{H}}^{(\ensuremath{\nu})}$ are found for ferromagnetic (
J>0) and antiferromagnetic (
J<0) exchange interactions for all temperatures
T and all spin dimensionalities $\ensuremath{\nu}$. The manner in which the various properties depend upon
T and $\ensuremath{\nu}$ is studied; in particular we find (a) that although the chain of spins does not display long-range order except at
T=0 for any value of $\ensuremath{\nu}$ most of the properties vary monotonically with $\ensuremath{\nu}$ (in such a way that, e.g., the degree of "short-range order" decreases with increasing $\ensuremath{\nu}$; and (b) that as the spin dimensionality increases without limit, all of the calculated properties approach precisely those predicted by the Berlin-Kac spherical model.
We consider a “generalized Heisenberg model”, with a Hamiltonian given by ℋ︁(D) = –JΣij S(D)j, where the quantities Si are isotropically-interacting D-dimensional classical spins and the summation is restricted to nearest-neighbor pairs of sites <i,j>. Thus when D = 1, 2, and 3, this model reduces to the S = 1/2 Ising, plane rotator, and classical Heisenberg models which are useful for describing phase transitions in, respectively, liquid-gas systems, Bose fluids, and magnetic materials. Unfortunately this Hamiltonian is exactly soluble only in the limit D → ∞, in which case the solution corresponds to the spherical model of Berlin and Kac. For finite D, we must consider approximation procedures in order to obtain any useful information. In this paper we develop a diagrammatic representation, valid for arbitrary D, for successive terms in the high-temperature expansions of the free energy and the spin-spin correlation function—from which we can obtain series expansions for all the thermodynamic properties of the system.
A model Hamiltonian H=−JΣ(ij)Si·Sj is considered, where Si are isotropically interacting D-dimensional classical spins. Thus the S=½ Ising, classical planar, and classical Heisenberg models are obtained if D=1, 2, and 3, respectively; moreover, as D→∞, the free energy corresponding to H approaches the free energy of the exactly-soluble spherical model of Berlin and Kac. H can also be solved exactly providing the lattice dimensionality d=1. For lattices of higher dimensionality, we must resort to approximation techniques; hence we calculate high-temperature expansions for arbitrary D and d of the susceptibility, internal energy (specific heat), and the second moment. (With a few exceptions, such expansions have been available in the past only for D=1, 3 and d=1–3.) Somewhat smoother series to facilitate more reliable extrapolation are then obtained by re-expanding all of the series in terms of the nearest-neighbor spin correlation function for a one-dimensional lattice. We then study the dependence on spin and lattice dimensionality of the critical temperatures Tc(D, d) and the critical exponents γ(D, d) [(χ∼(T-Tc)−γ], α(D, d) [C∼(T-Tc)−α], ν(D, d) [inverse correlation range κ∼(T-Tc)−v]. These ``critical properties'' are all found to vary monotonically (and in most cases, smoothly) with D and d. The assumptions behind making critical phenomena predictions from a dozen or so terms (of an infinite series!) are given increased plausibility by the fact that we have extended the various expansions for the spherical model to 80–100 terms and find that none of the predictions based upon ∼10 terms is changed [e.g., Tc(∞, 2)=0, γ(∞, 3)=2, etc.].