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Work as an external quantum observable and an operational quantum Jarzynski equality

Konstantin Beyer, Kimmo Luoma, Walter T. Strunz

Published Mar 13, 2020• 0 citations
OpenAlex

Abstract

In this Letter we propose a framework to define work as a quantum observable on a control device which is driving a system. Motivated by the conceptual difference between well known quantum versions of the Jarzynski equality (JE), where the initial and final system Hamiltonian have to be known in advance, and their classical counterparts where such knowledge is not needed, we construct a scheme where a work increment is given by an expectation value of a quantum observable on an external system. We further show that such a definition of work satisfies a fluctuation theorem which allows the free energy difference to be estimated operationally without knowledge about the Hamiltonian of the system at the end of the driving protocol. However, knowledge about the basis of the initial Hamiltonian is in general still needed. Providing two examples we describe how bounds on free energy differences could approximately be determined in experiments.

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Operational Work Fluctuation Theorem for Open Quantum Systems

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The classical Jarzynski equality establishes an exact relation between the stochastic work performed on a system driven out of thermal equilibrium and the free energy difference in a corresponding quasistatic process. This fluctuation theorem bears experimental relevance, as it enables the determination of the free energy difference through the measurement of externally applied work in a nonequilibrium process. In the quantum case, the Jarzynski equality only holds if the measurement procedure of the stochastic work is drastically changed: it is replaced by a so-called two-point measurement scheme that requires the knowledge of the initial and final Hamiltonian and therefore lacks the predictive power for the free energy difference that the classical Jarzynski equation is known for. Here, we propose a quantum fluctuation theorem that is valid for externally measurable quantum work determined during the driving protocol. In contrast to the two-point measurement case, the theorem also applies to open quantum systems and the scenario can be realized without knowing the system Hamiltonian. Our fluctuation theorem comes in the form of an inequality and therefore only yields bounds to the true free energy difference. The inequality is saturated in the quasiclassical case of vanishing energy coherences at the beginning and at the end of the protocol. Thus, there is a clear quantum disadvantage.

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We propose a definition of externally measurable quantum work in driven systems.Work is given as a quantum observable on a control device which is forcing the system and can be determined without knowledge of the system Hamiltonian ĤS .We argue that quantum work fluctuation theorems which rely on the knowledge of ĤS are of little practical relevance, contrary to their classical counterparts.Using our framework, we derive a fluctuation theorem which is operationally accessible and could in principle be implemented in experiments to determine bounds on free energy differences of unknown systems.

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Estimation of work at the quantum scale remains a central challenge in quantum thermodynamics. Canonical approaches have a fundamental drawback: they assume classical control of the quantum system, as implicit in a time-dependent Hamiltonian. Yet the energetic cost of implementing this control is omitted and can exceed the system's energy scale by orders of magnitude, calling into question the operational significance of work values. We address this by autonomizing the controlled energy transfer, embedding the driven dynamics into an energy-conserving evolution on a larger quantum system. Work is then unambiguously identified with the energy transferred between the two systems, singling out a unique observable on the driven system: the work operator. We show that the quantum work operator evades a no-go theorem by deriving a quantum fluctuation theorem that recovers the Jarzynski equality in classical scenarios. We incorporate imperfect control and quantify corrections to work statistics. Extending the framework to open quantum systems, we obtain an operatorial first law in which work, heat, and internal-energy changes are represented by distinct operators on the reduced system. Together, these results settle the long-standing debate over whether work is a quantum observable: it is, once the controlling system is included in the description rather than treated as external.

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Abstract Work is a process-based quantity, and its measurement typically requires interaction with a measuring device multiple times. While classical systems allow for non-invasive and accurate measurements, quantum systems present unique challenges due to the influence of the measuring device on the final value of work. As recent studies have shown, among these challenges is the impossibility of formulating a universal definition of work that respects energy conservation for coherent quantum systems and is compatible with the Jarzynski equality—a fluctuation relation linking the equilibrium free energy difference to the non-equilibrium work. Here, we overcome this challenge by introducing a genuinely quantum, positive correction to the Jarzynski equality stemming from imposing energy conservation. When sufficiently large, this correction forces quantum work to violate the second law more often. Moreover, we construct modified two-point measurement (TPM) schemes for work, along with circuit implementations for them. These measurement schemes correctly certify energy conservation and remain consistent with our quantum-corrected fluctuation relation.

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Energy conservation and Jarzynski equality are incompatible for quantum work

Karen V. Hovhannisyan, Alberto Imparato

Measuring the fluctuations of work in coherent quantum systems is notoriously problematic. Aiming to reveal the ultimate source of these problems, we demand of work measurement schemes the sheer minimum and see if those demands can be met at all. We require ($\mathfrak{A}$) energy conservation for arbitrary initial states of the system and ($\mathfrak{B}$) the Jarzynski equality for thermal initial states. By energy conservation we mean that the average work must be equal to the difference of initial and final average energies, and that untouched systems must exchange deterministically zero work. Requirement $\mathfrak{B}$ encapsulates the second law of thermodynamics and the quantum--classical correspondence principle. We prove that work measurement schemes that do not depend on the system's initial state satisfy $\mathfrak{B}$ if and only if they coincide with the famous two-point measurement scheme, thereby establishing that state-independent schemes cannot simultaneously satisfy $\mathfrak{A}$ and $\mathfrak{B}$. Expanding to the realm of state-dependent schemes allows for more compatibility between $\mathfrak{A}$ and $\mathfrak{B}$. However, merely requiring the state-dependence to be continuous still effectively excludes the coexistence of $\mathfrak{A}$ and $\mathfrak{B}$, leaving the theoretical possibility open for only a narrow class of exotic schemes.

•Apr 19, 2021•3 citations

Jarzynski equality for conditional stochastic work

Akira Sone, Sebastian Deffner

It has been established that the inclusive work for classical, Hamiltonian dynamics is equivalent to the two-time energy measurement paradigm in isolated quantum systems. However, a plethora of other notions of quantum work has emerged, and thus the natural question arises whether any other quantum notion can provide motivation for purely classical considerations. In the present analysis, we propose the conditional stochastic work for classical, Hamiltonian dynamics, which is inspired by the one-time measurement approach. This novel notion is built upon the change of expectation value of the energy conditioned on the initial energy surface. As main results we obtain a generalized Jarzynski equality and a sharper maximum work theorem, which account for how non-adiabatic the process is. Our findings are illustrated with the parametric harmonic oscillator.

•Jan 1, 2020•13 citations
In this Letter we propose a framework to define work as a quantum observable on a control device which is driving a system. Motivated by the conceptual difference between well known quantum versions of the Jarzynski equality (JE), where the initial and final system Hamiltonian have to be known in advance, and their classical counterparts where such knowledge is not needed, we construct a scheme where a work increment is given by an expectation value of a quantum observable on an external system. We further show that such a definition of work satisfies a fluctuation theorem which allows the free energy difference to be estimated operationally without knowledge about the Hamiltonian of the system at the end of the driving protocol. However, knowledge about the basis of the initial Hamiltonian is in general still needed. Providing two examples we describe how bounds on free energy differences could approximately be determined in experiments.
The classical Jarzynski equality establishes an exact relation between the stochastic work performed on a system driven out of thermal equilibrium and the free energy difference in a corresponding quasistatic process. This fluctuation theorem bears experimental relevance, as it enables the determination of the free energy difference through the measurement of externally applied work in a nonequilibrium process. In the quantum case, the Jarzynski equality only holds if the measurement procedure of the stochastic work is drastically changed: it is replaced by a so-called two-point measurement scheme that requires the knowledge of the initial and final Hamiltonian and therefore lacks the predictive power for the free energy difference that the classical Jarzynski equation is known for. Here, we propose a quantum fluctuation theorem that is valid for externally measurable quantum work determined during the driving protocol. In contrast to the two-point measurement case, the theorem also applies to open quantum systems and the scenario can be realized without knowing the system Hamiltonian. Our fluctuation theorem comes in the form of an inequality and therefore only yields bounds to the true free energy difference. The inequality is saturated in the quasiclassical case of vanishing energy coherences at the beginning and at the end of the protocol. Thus, there is a clear quantum disadvantage.
We propose a definition of externally measurable quantum work in driven systems.Work is given as a quantum observable on a control device which is forcing the system and can be determined without knowledge of the system Hamiltonian ĤS .We argue that quantum work fluctuation theorems which rely on the knowledge of ĤS are of little practical relevance, contrary to their classical counterparts.Using our framework, we derive a fluctuation theorem which is operationally accessible and could in principle be implemented in experiments to determine bounds on free energy differences of unknown systems.
Estimation of work at the quantum scale remains a central challenge in quantum thermodynamics. Canonical approaches have a fundamental drawback: they assume classical control of the quantum system, as implicit in a time-dependent Hamiltonian. Yet the energetic cost of implementing this control is omitted and can exceed the system's energy scale by orders of magnitude, calling into question the operational significance of work values. We address this by autonomizing the controlled energy transfer, embedding the driven dynamics into an energy-conserving evolution on a larger quantum system. Work is then unambiguously identified with the energy transferred between the two systems, singling out a unique observable on the driven system: the work operator. We show that the quantum work operator evades a no-go theorem by deriving a quantum fluctuation theorem that recovers the Jarzynski equality in classical scenarios. We incorporate imperfect control and quantify corrections to work statistics. Extending the framework to open quantum systems, we obtain an operatorial first law in which work, heat, and internal-energy changes are represented by distinct operators on the reduced system. Together, these results settle the long-standing debate over whether work is a quantum observable: it is, once the controlling system is included in the description rather than treated as external.
Abstract Work is a process-based quantity, and its measurement typically requires interaction with a measuring device multiple times. While classical systems allow for non-invasive and accurate measurements, quantum systems present unique challenges due to the influence of the measuring device on the final value of work. As recent studies have shown, among these challenges is the impossibility of formulating a universal definition of work that respects energy conservation for coherent quantum systems and is compatible with the Jarzynski equality—a fluctuation relation linking the equilibrium free energy difference to the non-equilibrium work. Here, we overcome this challenge by introducing a genuinely quantum, positive correction to the Jarzynski equality stemming from imposing energy conservation. When sufficiently large, this correction forces quantum work to violate the second law more often. Moreover, we construct modified two-point measurement (TPM) schemes for work, along with circuit implementations for them. These measurement schemes correctly certify energy conservation and remain consistent with our quantum-corrected fluctuation relation.
Measuring the fluctuations of work in coherent quantum systems is notoriously problematic. Aiming to reveal the ultimate source of these problems, we demand of work measurement schemes the sheer minimum and see if those demands can be met at all. We require (A\mathfrak{A}A) energy conservation for arbitrary initial states of the system and (B\mathfrak{B}B) the Jarzynski equality for thermal initial states. By energy conservation we mean that the average work must be equal to the difference of initial and final average energies, and that untouched systems must exchange deterministically zero work. Requirement B\mathfrak{B}B encapsulates the second law of thermodynamics and the quantum--classical correspondence principle. We prove that work measurement schemes that do not depend on the system's initial state satisfy B\mathfrak{B}B if and only if they coincide with the famous two-point measurement scheme, thereby establishing that state-independent schemes cannot simultaneously satisfy A\mathfrak{A}A and B\mathfrak{B}B. Expanding to the realm of state-dependent schemes allows for more compatibility between A\mathfrak{A}A and B\mathfrak{B}B. However, merely requiring the state-dependence to be continuous still effectively excludes the coexistence of A\mathfrak{A}A and B\mathfrak{B}B, leaving the theoretical possibility open for only a narrow class of exotic schemes.
It has been established that the inclusive work for classical, Hamiltonian dynamics is equivalent to the two-time energy measurement paradigm in isolated quantum systems. However, a plethora of other notions of quantum work has emerged, and thus the natural question arises whether any other quantum notion can provide motivation for purely classical considerations. In the present analysis, we propose the conditional stochastic work for classical, Hamiltonian dynamics, which is inspired by the one-time measurement approach. This novel notion is built upon the change of expectation value of the energy conditioned on the initial energy surface. As main results we obtain a generalized Jarzynski equality and a sharper maximum work theorem, which account for how non-adiabatic the process is. Our findings are illustrated with the parametric harmonic oscillator.