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Nonlinear phase resonance of quantum beats in the dimer ground state

Marcis P. Auzinsh

Published Jun 1, 1990• 1 citation
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A method is described which allows the detection of atomic quantum beats or wave-packet evolution in low-lying states, phenomena which are usually difficult to observe. The excitation method consists of a phase-sensitive two-pulse technique. Detection of the excited-state population after the two pulses is achieved by monitoring rubidium dimer ions which are formed in the associative ionization reaction, Rb*(n)p+Rb \ensuremath{\rightarrow}Rb2+{\mathrm{Rb}}_{2}^{+}Rb2+​+${\mathit{e}}^{\mathrm{\ensuremath{-}}}$. The dimer ion yield as a function of the wavelength showed strong features, which coincided with the 8p to 15p atomic resonances. The two-pulse technique revealed atomic fine-structure quantum beats due to the coherent excitation of the np2{\mathit{np}}^{2}np2P1/2,3/2{\mathit{P}}_{1/2,3/2}P1/2,3/2​ fine-structure states of the atom. \textcopyright{} 1996 The American Physical Society.
The spin-orbital model for triply degenerate t2g{t}_{2g}t2g​ electrons on a triangular lattice has been shown to be dominated by dimers. The phase diagram contains both strongly resonating, compound spin-orbital dimer states and quasistatic, spin-singlet valence-bond (VB) states. To elucidate the nature of the true ground state in these different regimes, the model is mapped to a number of quantum dimer models (QDMs), each of which has three dimer colors. The generic multicolored QDM, illustrated for the two- and three-color cases, possesses a topological color structure, ``color vison'' excitations, and broad regions of resonating VB phases. The specific models are analyzed to gain further insight into the likely ground states in the superexchange and direct-exchange limits of the electronic Hamiltonian, and they suggest a strong tendency toward VB order in all cases.