We study magnetization transport in anisotropic spin-
21 chains governed by the integrable XXZ model with and without integrability-breaking perturbations at high temperatures $(T\ensuremath{\rightarrow}\ensuremath{\infty})$ using a hybrid approach that combines exact sum rules with judiciously chosen Ans\"atze. In the integrable XXZ model we find (i) superdiffusion at the isotropic (Heisenberg) point, with frequency dependent conductivity ${\ensuremath{\sigma}}^{\ensuremath{'}}(\ensuremath{\omega}\ensuremath{\rightarrow}0)\ensuremath{\sim}{|\ensuremath{\omega}|}^{\ensuremath{\alpha}}$, where $\ensuremath{\alpha}=\ensuremath{-}3/7$ in close numerical agreement with recent
t-DMRG computations; (ii) a continuously drifting exponent from $\ensuremath{\alpha}=\ensuremath{-}{1}^{+}$ in the XY (gapless) limit of the model to $\ensuremath{\alpha}>0$ within the Ising (gapped) regime; and (iii) a diffusion constant saturating in the XY coupling deep in the Ising limit. We consider two kinds of next-nearest-neighbor integrability breaking perturbations---a simple spin-flip term
(J2) and a three-spin assisted variant
(t2), natural in the fermion particle representation of the spin chain. In the first case we discover a remarkable sensitivity of ${\ensuremath{\sigma}}^{\ensuremath{'}}(\ensuremath{\omega})$ to the sign of
J2, with enhanced low frequency spectral weight and a pronounced upward shift in the magnitude of $\ensuremath{\alpha}$ for
J2>0. Perhaps even more surprising, we find subdiffusion $(\ensuremath{\alpha}>0)$ over a range of
J2<0. By contrast, the effects of the ``fermionic'' three-spin perturbation are sign symmetric; this perturbation produces a clearly observable hydrodynamic relaxation. At large strength of the integrability breaking term ${J}_{2}\ensuremath{\rightarrow}\ifmmode\pm\else\textpm\fi{}\ensuremath{\infty}$ the problem is effectively noninteracting (fermions hopping on odd and even sublattices) and we find $\ensuremath{\alpha}\ensuremath{\rightarrow}\ensuremath{-}1$ behavior reminiscent of the XY limit of the integrable XXZ chain. Exact diagonalization studies largely corroborate these findings over accessible frequencies.