We present an experimental study of cw degenerate four-wave mixing (DFWM) in Doppler-broadened rubidium atoms coupled by an additional coherent field. The coupling field and the DFWM fields were arranged in a \ensuremath{\Lambda}-type configuration from the rubidium
D2 transitions. We found that the presence of the coherent coupling field modifies the DFWM emission:mfat lower intensities of the coupling field, the DFWM emission is enhanced; at higher intensities of the coupling field, the DFWM is reduced. The observed effect of the coupling laser on the DFWM emission may be explained by the direct competition between the resonance-enhanced two-photon Raman scattering and the optical-pumping-enhanced DFWM emission.
We present a study of atomic coherence effects in resonant degenerate four-wave mixing. We find for energy levels having magnetic degeneracies, the third-order nonlinear response resulting from two counterpropagating pump waves orthogonally polarized to an incident probe wave generates a signal whose polarization is phase conjugate to that of the incident probe wave. This effect is due to the coupling of different magnetic states resulting from coherent excitation giving rise to a net electric quadrupole. Experimental studies in Na on the D2 line at 5890 Å confirm the analysis.