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Frequency selection of Nd 3+ ions in glass excited by monochromatic laser radiation at the resonant transition 4/{9/2}→ 4 F 3/2

T. T. Basiev, Yu. K. Voron’ko, Sergey Mirov, Alexander M. Prokhorov

Published Jun 1, 1979• 0 citations
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Abstract A history of the development of selective laser spectroscopy is presented, beginning with a pioneering work by Yu. V. Denisov and V. A. Kizel in 1967, who were the first to demonstrate the possibility of removing the inhomogeneous broadening of luminescence spectra of impurity ions in glasses upon monochromatic resonance excitation. Selective excitation of optical centers can be achieved due to existence of zero-phonon transitions corresponding to narrow homogeneous zero-phonon lines in the spectra of impurity centers in solids, which are hidden in broad inhomogeneous optical bands upon usual nonselective excitation. The fundamentals of zero-phonon transition spectroscopy are considered and the mechanism of removing the inhomogeneous broadening of optical spectra of ions and molecules in crystals and amorphous solids under selective laser excitation of luminescence and persistent hole burning in absorption spectra is presented in detail. Various applications of selective laser spectroscopy for fundamental and applied studies are discussed.
Isotopically selective resonance ionization of mercury atoms has been accomplished by three-step excitation via the 6 3P1 and 8 1S0 excited states. Three collinear beams, respectively 254, 286, and 532 nm, from two dye lasers and a pulsed neodymium:yttrium aluminum garnet (ND:YAG) pump laser, were passed through a closed mercury vapor cell containing electrodes to which the ions were drawn by an electric field. The ion current and the 254-nm fluorescence radiation were measured as a function of laser wavelengths. Hyperfine structures for the 254- and 286-nm transitions were observed.