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Oxford University Press eBooks

De Broglie’s Derivation of λ = h/p

Jim Baggott

Published Jan 10, 2020• 0 citations
Publisher

Abstract

Whatever was going to replace classical physics in the description of radiation and atomic phenomena had to confront the difficult task of somehow reconciling the wave-like and particle-like aspects of light in a single structure. An important clue would come from Einstein’s E=mc2. We tend to want to associate mass (and linear momentum) with material particles. But the Planck–Einstein relation E=hν connects energy with frequency, a determinedly wave-like property. So, here are two very simple yet fundamental equations connecting energy to mass and energy to frequency. Can they be combined? Louis de Broglie thought so, and in 1923 he generalized the discovery made by Einstein in 1905 by extending it to all material particles, and most notably to electrons. The de Broglie relation λ=h/p can be derived quite straightforwardly by comparing the Lorentz transformations for energy and momentum with those for a system of plane waves.

DOI
10.1093/oso/9780198827856.003.0005

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Whatever was going to replace classical physics in the description of radiation and atomic phenomena had to confront the difficult task of somehow reconciling the wave-like and particle-like aspects of light in a single structure. An important clue would come from Einstein’s E=mc2. We tend to want to associate mass (and linear momentum) with material particles. But the Planck–Einstein relation E=hν connects energy with frequency, a determinedly wave-like property. So, here are two very simple yet fundamental equations connecting energy to mass and energy to frequency. Can they be combined? Louis de Broglie thought so, and in 1923 he generalized the discovery made by Einstein in 1905 by extending it to all material particles, and most notably to electrons. The de Broglie relation λ=h/p can be derived quite straightforwardly by comparing the Lorentz transformations for energy and momentum with those for a system of plane waves.
The famous 1927 Solvay Conference was considered a turning point in the world of Physics. The scientific realists like Albert Einstein had lost and the instrumentalists like Niels Bohr had won the fundamental conflict. Since then Physics has followed the path of the instrumentalists in which Quantum Physics has been determined by the concept of Elementary Particles and Probability Waves. Until May 2013, when for the first time a photo had been made of the Probability Waves Inside the Hydrogen Atom . It should be impossible to make a photo of a non-existing complex probability wave with mass zero But the fact could not be denied anymore that scientists had succeeded to make the “complex” and the “non-existing” quantum mechanical “Probability Wave” visible. Since the Copenhagen Interpretation there is still no clarity about the physical interpretation of the Quantum Mechanical “Probability Wave Function”This Manuscript describes a third unknown interpretation of the Quantum Mechanical “Probability Wave Function”. A fundamental physical interpretation that will change the generally accepted Copenhagen Interpretation. This Manuscript will answer the fundamental question: Does an alternative theory exist in which the existence of this particular photo, of the Quantum Mechanical Probability Wave within the Hydrogen Atom, could be explained. And that the famous photo of the Hydrogen Atom can be explained in a logical and a simple way. To find the answer, we have to go back in time. Back 300 years in time to the moment when Isaac Newton discovered the beauty and one of the many secrets of the light. The moment when science walked away from light. And we return to the fundamental question: “Is it possible to build Matter out of Light (confined electromagnetic waves)?” To answer this question if it is possible to build Matter out of Light, we first have to answer the question how we have come to this world of Probability Waves and Elementary Particles and Quantum Physics.Louis de Broglie described in 1924 in his PhD thesis the wave properties of matter. Erwin Schrödinger published in 1926 the well-known Schrödinger wave equation with the characteristic spherical and elliptical wave solutions. To describe these material waves, the immediately and first explanation was: “There is only one possibility. These are “Electromagnetic Waves”. De Broglie Waves are ” Light Waves”. Because these were the only waves, known in the world of Physics, that could travel through vacuum. But there was a fundamental problem. These material waves, discovered by Louis de Broglie and mathematically described by Erwin Schrödinger could never be solutions of the well-known 4 linear equations of James Clerk Maxwell. The material waves were spherical and elliptical solutions of confinement and that was impossible for the solutions of the linear Maxwell Equations. According to the linear Maxwell Equations, superposition is possible but Electromagnetic Interaction and Electromagnetic Confinement can only be described by a set of non-linear differential equations. To solve this fundamental problem a new set of 3 non-linear Electromagnetic Equations (Equation 5 in this manuscript) has been developed which replaces the well-known 4 linear Maxwell Equations and the possible solutions of Equation (5) are also Spherical and Elliptical solutions of confinement. Table 1 in this manuscript presents a number of Electromagnetic Spherical Confinements as solutions of Equation 5a .A second problem was that the model of the atom of Bohr could not hold. How could an electron be everywhere at the same time in a kind of a spherical shell surrounding the nucleus. And be a particle at the same time. And Bohr found a compromise to declare the “De Broglie” waves to be the probability waves. Two problems were solved. Bohr’s planetary model could hold. And there was a name for the unknown material waves, discovered by Louis de Broglie and mathematically described by Erwin Schrödinger. The theory of “Probability Waves, Elementary Particles and Quantum Physics” had been created. To find a possibility, to create matter out of light we have to go back to the Equations of James Clerk Maxwell. The only possibility to declare the probability waves, discovered by Louis de Broglie, to be electromagnetic waves, to be light, and to be the building element of our universe, is to find evidence that he Maxwell Equations are not complete and that it is possible to confine light (electromagnetic waves) in spherical and elliptical shapes. A new equation has to be found. In this article it has been claimed that this missing equation is Equation (5). Because the Theory of General Relativity has been built on the Einstein-Maxwell Equation, a new equation has to be found that describes in a generalized way the interaction between light and matter. This missing equation is Equation (5-a).
Louis-Victor de Broglie secured his place in the history of quantum physics by proposing the existence of matter waves. Following the concept accepted early in the twentieth century that light waves could display properties characteristic of particles (photons), de Broglie suggested the complementary principle that particles could display properties characteristic of waves. Within a few years, this far-reaching proposal was experimentally verified. The well-known formula for the wavelength λ of the wave associated with a particle of momentum p, namely λ=h/p, does not appear in de Broglie’s original paper, which was published in this journal in 1924. What is derived from the starting assumption that the frequency of the wave is the rest energy of the particle divided by Planck’s constant h, is the wave's velocity, which turns out to be c2/v, where v is the particle’s velocity. This velocity, being superluminal, means that the wave cannot transport energy. De Broglie called it a phase wave and postulated a group of such waves having virtually, but not exactly, the same velocity and wavelength. The group velocity of such a large number of almost identical phase waves is then shown, very satisfactorily, to be equal to the velocity of the particle. The proposal by de Broglie inspired Schrödinger to develop the mathematical foundations of wave mechanics. Whereas in conventional quantum theory, phase waves are considered fictional, de Broglie considered them to have a certain physical reality, renaming them pilot or guiding waves – a concept developed later by Bohm in 1952.
The famous 1927 Solvay Conference was considered a turning point in the world of Physics. The scientific realists like Albert Einstein had lost and the instrumentalists like Niels Bohr had won the fundamental conflict. Since then Physics has followed the path of the instrumentalists in which Quantum Physics has been determined by the concept of Elementary Particles and Probability Waves. Until May 2013, when for the first time a photo had been made of the Probability Waves Inside the Hydrogen Atom . It should be impossible to make a photo of a non-existing complex probability wave with mass zero But the fact could not be denied anymore that scientists had succeeded to make the complex and non-existing visible. This will be the fundamental question in this article. Does an alternative theory exist in which the existence of this particular photo could be explained. And that the famous photo of the Hydrogen Atom can be explained in a logical and a simple way. To find the answer, we have to go back in time. Back 300 years in time to the moment when Isaac Newton discovered the beauty and one of the many secrets of the light. The moment when science walked away from light. And we return to the fundamental question: “Is it possible to build matter out of Light (confined electromagnetic waves)?” To answer this question we first have to answer the question how we have come to this world of Probability Waves and Elementary Particles and Quantum Physics.Louis de Broglie described in 1924 in his PhD thesis the wave properties of matter. Erwin Schrödinger published in 1926 the well-known Schrödinger wave equation with the characteristic spherical and elliptical wave solutions. To describe these material waves, the immediately and first explanation was: “There is only one possibility. These are “electromagnetic waves”. De Broglie waves are ” Light Waves”. Because these were the only waves, known in the world of Physics. But there was a fundamental problem. These material waves, discovered by Louis de Broglie and mathematically described by Erwin Schrödinger could never be solutions of the well-known 4 equations of James Clerk Maxwell. The material waves were spherical and elliptical solutions and that was impossible for the solutions of the Maxwell Equations. According to the Maxwell Equations, light always travels along a straight path. A second problem was that the model of the atom of Bohr could not hold. How could an electron be everywhere at the same time in a kind of a spherical shell surrounding the nucleus. And be a particle at the same time. And Bohr found a compromise to declare the “De Broglie” waves to be the probability waves. Two problems were solved. Bohr’s planetary model could hold. And there was a name for the unknown material waves, discovered by Louis de Broglie and mathematically described by Erwin Schrödinger. The theory of “Probability Waves, Elementary Particles and Quantum Physics” had been created. To find a possibility, to create matter out of light we have to go back to the Equations of James Clerk Maxwell. The only possibility to declare the probability waves, discovered by Louis de Broglie, to be electromagnetic waves, to be light, and to be the building element of our universe, is to find evidence that he Maxwell Equations are not complete and that it is possible to confine light (electromagnetic waves) in spherical and elliptical shapes. A new equation has to be found. In this article it has been claimed that this missing equation is equation (5). Because the Theory of General Relativity has been built on the Einstein-Maxwell Equation, a new equation has to be found that describes in a generalized way the interaction between light and matter. This missing equation is equation (5-a).
Abstract We have seen that it took about two decades to fully realize that light or, generally, electromagnetic radiation has both wave and particle properties. The final proof came with the discovery of the Compton effect (Episode 31). Even Compton himself needed years before he saw that the particle picture of radiation was unavoidable in view of the experimental evidence. Still in the year of Compton’s publications, Louis de Broglie [1] on purely theoretical grounds proposed that the particle–wave duality not only holds for radiation but also for material particles, i.e., for particles with a rest mass such as the electron.
In 1924 a young PhD student submitted a thesis containing the germ of an idea that would revolutionize our understanding of the material world.3 e student was Louis De Broglie4 (pronounced De Broy), and for a while he had been meditating on the wave/particle nature of light. In a moment of insight he suddenly realized that the odd behavior of light might extend to other aspects of nature as well. Perhaps particles, such as electrons, could have a wavelike nature to balance the particlelike nature of light, which had been thought of as a wave. Echoing the Planck-Einstein formulas for photons, De Broglie proposed that electrons should have a ‘pilot wave’ with frequency ( f ) and wavelength (λ) given by h mv f E h His thesis also contains an explanation for Bohr’s quantized orbits in hydrogen. If an orbiting electron had a ‘corresponding’ wave, it would have to close on itself around the circular arc of the orbit. is forces the circumference of a satisfactory orbit to be a whole number multiple of the wavelength (see Figure 18.1).
Special Relativity sets tight constraints on the form of the possible relations between the four-momentum of a particle and the wave four-vector. In fact, we demonstrate that there is just one way, according to Special Relativity, to relate the energy and the momentum of a corpuscle with the characteristics of a plane wave, frequency and wave vector, if the momentum has to flow in the same direction of the wave propagation: the laws must be of direct proportionality like de Broglie and Planck-Einstein equations.