With a limit on the small number of problems that admit exact solutions, we turn in this chapter to approximation methods that can be used for bound state problems. The most commonly used method is the perturbation theory for which one use a small parameter to form the basis of a systematic expansion, or a variational method in which one hopes to set the best limit on the energy of a system. We will consider both of these approximation methods with applications to problems in atomic and molecular physics.
We develop a method for treating the N-fermion problem as a system of correlated pairs of particles. Coherent pair states are introduced and a variational as well as a secular method are discussed for providing upper bounds to the exact ground state and approximations to the low lying spectra. Specific applications to two soluble models are presented. For these models the coherent correlated pair method is superior to the Bardeen-Cooper-Schrieffer approximation and to the Hartree-Fock approximation and in fact yields the exact solutions for all particle numbers and sufficiently large coupling constants.NUCLEAR STRUCTURE Correlated pairs; coherent states; upper bound to ground state energy; applications to soluble N-fermion models.
This thesis investigates methods to approximate convex sets which involve minimizing the Hausdorff metric between a set and certain subsets. We begin by giving a lower bound for the Hausdorff metric between a hypersphere and a circumscribed simplex. We show that this bound is achieved by the regular simplex. Next, we form a lower bound on the Hausdorff distance between the convex hull of the joint numerical range of positive operator valued-measures and the probability simplex. An entanglement witness is a linear functional that separates the convex compact set of separable states from certain entangled states in the Hilbert space. We investigate the applications of our methods by exploring the problem of finding a polytope generated by entanglement witnesses that has minimal distance to the set of separable states.