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The Self-Energy and Effective Mass of the Polaron.

John T. Marshall

Published Jan 1, 1962• 1 citation
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A Variational Calculation of the Polaron Self-Energy and Effective Mass.

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An approximate calculation is made of the polaron self-energy and effective mass as defined by Frohlich.The approach taken is a variational one based on an ex tended version of Hohler's ansatz in which the trial state function employed is an exact eigenfunction of the total wave vector of the polaron.The effective mass obtained simulates the Feynmann-Schultz result while the corresponding polaron self-energy is fairly accurate but inferior to the result of Feynman and Schultz.CONTENTS Chapters « -« T -| > £ ( l ^' (1'2) n in which n is the optical refractive index, k is the static dielectric constant, e is the electronic charge and 2 t\& is Plank's constant.The limit S->°° is to be taken with lim I = -~ S-*oo v 8tt d 3v .(1,3) A natural unit system is employed in which 2^=o)=2m=l.The first term in the Hamiltonian is the quantum mechanical operator corresponding to the kinetic energy of the electron.The second term represents the energy of the polarization field resulting from the long wave length longitudinal optical crystal modes in the absence of interaction with the electron.The last term represents the energy of interaction between the electron and the phonons.The name "polaron" has been given to the entity consisting of the Bloch conduction electron together with its accompanying nonradiative polarization field.Accordingly Frohlich defines the polaron self-energy, EQ (a), and the (ground-state) polaron effective mass, y(a), by the expansion EQ (a,ic) = Ec (a) + k 2/y(a) + 0(k4 ), (1,4)

Civil War Book Review•Jan 1, 1971•0 citations

Recoil Effects in the Polaron Problem

M. Porsch, J. Röseler

Abstract A general formalism for diagonalizing quadratic forms of boson operators [7], is used to obtain a translationally invariant variational ansatz which is suitable for calculating the polaron self‐energy, effective mass, and energy momentum relation in both coupling limits. The self‐energy and effective mass are calculated in the weak‐coupling limit. The strong coupling limit shows the wellknown α2‐dependence of the self‐energy. Diagonalizing the quadratic part of the recoil term gives rise to an additional self‐energy contribution to the cutoff.

physica status solidi (b)•Jan 1, 1967•20 citations
In the expansion of the ground-state energy of a polaron in a weak magnetic field, the zeroth-order term is the polaron self-energy, while the first-order term is inversely proportional to the polaron effective mass. The effective mass so obtained is exactly equivalent to the freepolaron effective mass as defined by Fr\"ohlich. This equivalence principle is used to approximate the polaron effective mass by employing an approximate expression for the ground-state energy of a polaron in a weak magnetic field obtained by applying Feynman's path-integral variational method. The resultant polaron effective mass is found to be higher than Feynman's result by less than 1%.
An approximate calculation is made of the polaron self-energy and effective mass as defined by Frohlich.The approach taken is a variational one based on an ex tended version of Hohler's ansatz in which the trial state function employed is an exact eigenfunction of the total wave vector of the polaron.The effective mass obtained simulates the Feynmann-Schultz result while the corresponding polaron self-energy is fairly accurate but inferior to the result of Feynman and Schultz.CONTENTS Chapters « -« T -| > £ ( l ^' (1'2) n in which n is the optical refractive index, k is the static dielectric constant, e is the electronic charge and 2 t\& is Plank's constant.The limit S->°° is to be taken with lim I = -~ S-*oo v 8tt d 3v .(1,3) A natural unit system is employed in which 2^=o)=2m=l.The first term in the Hamiltonian is the quantum mechanical operator corresponding to the kinetic energy of the electron.The second term represents the energy of the polarization field resulting from the long wave length longitudinal optical crystal modes in the absence of interaction with the electron.The last term represents the energy of interaction between the electron and the phonons.The name "polaron" has been given to the entity consisting of the Bloch conduction electron together with its accompanying nonradiative polarization field.Accordingly Frohlich defines the polaron self-energy, EQ (a), and the (ground-state) polaron effective mass, y(a), by the expansion EQ (a,ic) = Ec (a) + k 2/y(a) + 0(k4 ), (1,4)
Abstract A general formalism for diagonalizing quadratic forms of boson operators [7], is used to obtain a translationally invariant variational ansatz which is suitable for calculating the polaron self‐energy, effective mass, and energy momentum relation in both coupling limits. The self‐energy and effective mass are calculated in the weak‐coupling limit. The strong coupling limit shows the wellknown α2‐dependence of the self‐energy. Diagonalizing the quadratic part of the recoil term gives rise to an additional self‐energy contribution to the cutoff.