On the basis of the Green’s function method for nonequilibrium systems, the kinetic equation for the density matrix of two-level particles used in laser spectroscopy is derived. The assumptions made in deriving the kinetic equation impose certain restrictions on this equation. In the binary approximation, all diagrams are expressed via the reducible vertex part, which can be expressed in terms of the amplitude of scattering of a two-level atom by a buffer gas.

Optics and SpectroscopyJun 29, 20046 citations

Journal of Experimental and Theoretical Physics

Kinetic Equation for the Density Matrix

É. G. Pestov, Sergey G. Rautian

Published Jan 1, 1969• 1 citation

OpenAlex

Related papers

Quantum Theory of a Laser Model

C. R. Willis

We derive the kinetic equations for the coupled single-particle density matrix $\ensuremath{\rho}$ and the electromagnetic density matrix $R$ to lowest order in the dimensionless coupling constant ${\ensuremath{\beta}}^{2}\ensuremath{\equiv}{(\frac{{\ensuremath{\omega}}_{L}}{{\ensuremath{\omega}}_{D}})}^{2}$. The laser frequency ${\ensuremath{\omega}}_{L}$ is ${(4\ensuremath{\pi})}^{\ensuremath{-}\frac{1}{2}}{(\mathfrak{N}{r}_{0}{\ensuremath{\lambda}}^{2})}^{\frac{1}{2}}{\ensuremath{\omega}}_{0}$ where $\mathfrak{N}$ is the number of two-level systems per unit volume, ${r}_{0}$ is the classical electron radius, $\ensuremath{\lambda}$ is the wavelength of the radiation, and $k{\ensuremath{\omega}}_{0}$ is the two-level energy difference. The Doppler frequency ${\ensuremath{\omega}}_{D}$ characterizes the center-of-mass motion. For gas lasers ${\ensuremath{\beta}}^{2}$ is much less than 1 and, consequently, we generalize and use the Bogoliubov derivation of kinetic equations for weak interactions. We find solutions when the average field vanishes and which include spontaneous emission correctly. The single-particle density matrix and the radiation density matrix are coupled through their second moments. When we substitute the solution of the second-moment equations into the density-matrix equations, we find that each density matrix satisfies an uncoupled linear equation with known time-dependent coefficients. We introduce and discuss dissipation from the density-matrix point of view. With the use of the density-matrix formalism we indicate that the correct expansion parameter for higher order kinetic equations is ${\ensuremath{\beta}}^{2}$.We derive the kinetic equations for the coupled single-particle density matrix $\ensuremath{\rho}$ and the electromagnetic density matrix $R$ to lowest order in the dimensionless coupling constant ${\ensuremath{\beta}}^{2}\ensuremath{\equiv}{(\frac{{\ensuremath{\omega}}_{L}}{{\ensuremath{\omega}}_{D}})}^{2}$. The laser frequency ${\ensuremath{\omega}}_{L}$ is ${(4\ensuremath{\pi})}^{\ensuremath{-}\frac{1}{2}}{(\mathfrak{N}{r}_{0}{\ensuremath{\lambda}}^{2})}^{\frac{1}{2}}{\ensuremath{\omega}}_{0}$ where $\mathfrak{N}$ is the number of two-level systems per unit volume, ${r}_{0}$ is the classical electron radius, $\ensuremath{\lambda}$ is the wavelength of the radiation, and $k{\ensuremath{\omega}}_{0}$ is the two-level energy difference. The Doppler frequency ${\ensuremath{\omega}}_{D}$ characterizes the center-of-mass motion. For gas lasers ${\ensuremath{\beta}}^{2}$ is much less than 1 and, consequently, we generalize and use the Bogoliubov derivation of kinetic equations for weak interactions. We find solutions when the average field vanishes and which include spontaneous emission correctly. The single-particle density matrix and the radiation density matrix are coupled through their second moments. When we substitute the solution of the second-moment equations into the density-matrix equations, we find that each density matrix satisfies an uncoupled linear equation with known time-dependent coefficients. We introduce and discuss dissipation from the density-matrix point of view. With the use of the density-matrix formalism we indicate that the correct expansion parameter for higher order kinetic equations is ${\ensuremath{\beta}}^{2}$.

Physical ReviewJul 8, 196622 citations

The Diffusion Equation for the Density Matrix

T. Andreeva

Journal of Experimental and Theoretical PhysicsAug 1, 19682 citations

Spinorial density matrix equation and gauge covariance

F. C. Khanna, Ademir Eugenio de Santana, A. Matos Neto +2 more

In this work we apply the Lie group representation method introduced in the real time formalism for finite-temperature quantum-field theory, thermofield dynamics, to derive a spinorial density matrix equation. Symmetry properties of such equation are analysed, and as a basic result it is shown that one solution is the generalised density matrix operator proposed by Heinz, to deal with gauge covariant kinetic equations. In the same context, preliminary aspects of a Lagrangian formalism to derive kinetic equations, as well as quantum density matrix equations in curved space-time, are discussed.In this work we apply the Lie group representation method introduced in the real time formalism for finite-temperature quantum-field theory, thermofield dynamics, to derive a spinorial density matrix equation. Symmetry properties of such equation are analysed, and as a basic result it is shown that one solution is the generalised density matrix operator proposed by Heinz, to deal with gauge covariant kinetic equations. In the same context, preliminary aspects of a Lagrangian formalism to derive kinetic equations, as well as quantum density matrix equations in curved space-time, are discussed.

arXiv:hep-th/9812222Dec 23, 19980 citations

The Density Matrix Equations

Mark Linne

Elsevier eBooksJan 1, 20020 citations

The density matrix equations

Mark Linne

Elsevier eBooksJan 1, 20240 citations

Derivation of the Kinetic Equation for the Density Matrix of Two-Level Particles by the Green’S Function Method

Е. А. Титов

Optics and SpectroscopyJun 29, 20046 citations

We derive the kinetic equations for the coupled single-particle density matrix $\ensuremath{\rho}$ and the electromagnetic density matrix

R

to lowest order in the dimensionless coupling constant ${\ensuremath{\beta}}^{2}\ensuremath{\equiv}{(\frac{{\ensuremath{\omega}}_{L}}{{\ensuremath{\omega}}_{D}})}^{2}$. The laser frequency ${\ensuremath{\omega}}_{L}$ is ${(4\ensuremath{\pi})}^{\ensuremath{-}\frac{1}{2}}{(\mathfrak{N}{r}_{0}{\ensuremath{\lambda}}^{2})}^{\frac{1}{2}}{\ensuremath{\omega}}_{0}$ where

\mathfrak{N}

is the number of two-level systems per unit volume,

{r}_{0}

is the classical electron radius, $\ensuremath{\lambda}$ is the wavelength of the radiation, and $k{\ensuremath{\omega}}_{0}$ is the two-level energy difference. The Doppler frequency ${\ensuremath{\omega}}_{D}$ characterizes the center-of-mass motion. For gas lasers ${\ensuremath{\beta}}^{2}$ is much less than 1 and, consequently, we generalize and use the Bogoliubov derivation of kinetic equations for weak interactions. We find solutions when the average field vanishes and which include spontaneous emission correctly. The single-particle density matrix and the radiation density matrix are coupled through their second moments. When we substitute the solution of the second-moment equations into the density-matrix equations, we find that each density matrix satisfies an uncoupled linear equation with known time-dependent coefficients. We introduce and discuss dissipation from the density-matrix point of view. With the use of the density-matrix formalism we indicate that the correct expansion parameter for higher order kinetic equations is ${\ensuremath{\beta}}^{2}$.