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APS

Triple Ionization of Lithium by Electron Impact

M.-T. Huang, W. W. Wong, Mitio Inokuti, Stephen H. Southworth, Linda Young

Published May 1, 2003• 0 citations
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Abstract

Ejection of the three electrons from lithium in a single electron collision has been observed for the first time. Triply charged lithium was observed in an ion time-of-flight spectrum following electron impact on a sample of ultracold, trapped lithium. The higher signal/background afforded by the trap environment made the observation of ${\mathrm{L}\mathrm{i}}^{3+}$ possible. We measured the ratios of triple-to-double and double-to-single ionization at an impact energy of 1000 eV. The $3+/2+$ ratio is $\ensuremath{\approx}0.001$, a value 2 orders of magnitude lower than semiempirical predictions. We present a simple method that uses photoionization data combined with sum-rule analysis to predict the asymptotic charge-state ratios. The sum-rule predictions compare reasonably with experiment and shake calculations, but disagree sharply with the semiempirical estimates.

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Triple Ionization of Lithium by Electron Impact

M.-T. Huang, W. W. Wong, Mitio Inokuti +2 more

Ejection of the three electrons from lithium in a single electron collision has been observed for the first time. Triply charged lithium was observed in an ion time-of-flight spectrum following electron impact on a sample of ultracold, trapped lithium. The higher signal/background afforded by the trap environment made the observation of Li3+ possible. We measured the ratios of triple-to-double and double-to-single ionization at an impact energy of 1000 eV. The 3+/2+ ratio is approximately 0.001, a value 2 orders of magnitude lower than semiempirical predictions. We present a simple method that uses photoionization data combined with sum-rule analysis to predict the asymptotic charge-state ratios. The sum-rule predictions compare reasonably with experiment and shake calculations, but disagree sharply with the semiempirical estimates.

Physical Review Letters•Apr 23, 2003•10 citations

Photon and Electron Impact Ionization of Lithium studied with a MOTReMi

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In the course of this work dynamics in ionization processes of lithium by photon and electron impact were studied. Due to its electronic structure, lithium is an ideal candidate to examine electronic correlation effects and collision dynamics of simple few-body systems. The lithium target is cooled in a magneto-optical trap (MOT) down to the sub-millikelvin regime, which in combination with a reaction microscope (ReMi) allows for the determination of the momentum information of all collision products with unprecedented resolution. An electron gun serving as a new projectile source was implemented in the MOTReMi experiment. From first measurements, which showed that the developed setup is principally operational, time-of-flight and position spectra were analyzed, determining the ratio of Li2+=Li+ ion creation. In a second series of experiments, photoionization of laser-excited lithium has been investigated and fully differential cross sections (FDCS) were examined. As the target and also the laser beam were polarized, orientational effects could be studied. In some cases the electron emission characteristics could directly be deduced from dipole selection rules.

•Jan 1, 2013•0 citations

Triple first for atoms

A group of physicists from Japan and the US has observed the triple photoionization of lithium – in which a single photon simultaneously ejects all three electrons from an atom – for the first time (R Wehlitz et al. 1998 Phys. Rev. Lett. 81 1813). The team used extreme ultraviolet radiation from the Japanese Photon Factory, a synchrotron radiation source at the KEK lab in Tsukuba, to ionize the atoms.

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Reaction microscopes enable kinematically complete measurements of atomic and molecular fragmentation. An ultracold atomic target is usually provided by a supersonic gas jet. The apparatus developed in the course of this thesis for the first time combines the principle of the reaction microscope with a magneto-optical trap. This allows for the preparation of lithium atoms in the sub-mK range. Being a three-electron system, its simple atomic structure makes lithium a model system of great topical interest for all kinds of ionization reactions. In order not to deteriorate the determination of the momenta of the charged fragments by the magnetic field of the trap, a pulsed mode of operation is adopted, creating field-free conditions during data acquisition and making efficient use of the stored target. The novel apparatus provides a versatile target for investigations on fragmentation of lithium by electron, ion and photon impact. For the first time, momentum-resolved measurements on multiphoton ionization in intense laser fields with pulse durations of 25~fs and peak intensities in the range between 10$^{11}$~W/cm$^2$ and 10$^{16}$~W/cm$^2$ were performed. The acquired photoelectron spectra exhibit unexpected structures such as a preferred emission in the direction perpendicular to the laser polarization axis, which are not fully understood yet. Presently, corresponding calculations are being done in several theory groups.

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Electron Impact Ionization of Sodium Rydberg Atoms below 2 eV

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We have observed electron impact ionization of highly excited sodium Rydberg atoms in $ns$ and $nd$ states, $n=35--51$, below $E=2\text{ }\text{ }\mathrm{e}\mathrm{V}$ electron kinetic energy with energy resolution 0.25 eV. Measured absolute cross sections near 0 eV range from ${\ensuremath{\sigma}}_{35d}\ensuremath{\approx}7\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}10}$ to ${\ensuremath{\sigma}}_{50d}\ensuremath{\approx}4\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}9}\text{ }\text{ }{\mathrm{c}\mathrm{m}}^{2}$. The energy dependence is consistent with that of widely used binary encounter approximation cross sections, and ${\ensuremath{\sigma}}_{n}$ follows a power law in $n$. The measured cross sections are 14 to 24 times larger than theoretically predicted values. This enhancement may signal the effect of large polarizabilities of high Rydberg states not yet accounted for in ionization theories.

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Deflection of High-Rydberg Atoms in Collisions at Thermal Energy

Carl A. Kocher, A.J. Smith

Lithium atoms in high Rydberg states, excited in an atomic beam by pulsed electron impact, are passed through a target gas and detected following electric-field state selection. Cross sections obtained from time-of-flight spectra are virtually independent of the principal quantum number and in numerical agreement with calculations for deflection of the core ion alone. This deflection has also been observed directly. These results suggest a new method for very-low-energy ion-atom scattering experiments.

Physical Review Letters•Dec 12, 1977•19 citations
Ejection of the three electrons from lithium in a single electron collision has been observed for the first time. Triply charged lithium was observed in an ion time-of-flight spectrum following electron impact on a sample of ultracold, trapped lithium. The higher signal/background afforded by the trap environment made the observation of Li3+{\mathrm{L}\mathrm{i}}^{3+}Li3+ possible. We measured the ratios of triple-to-double and double-to-single ionization at an impact energy of 1000 eV. The 3+/2+3+/2+3+/2+ ratio is \ensuremath≈0.001\ensuremath{\approx}0.001\ensuremath≈0.001, a value 2 orders of magnitude lower than semiempirical predictions. We present a simple method that uses photoionization data combined with sum-rule analysis to predict the asymptotic charge-state ratios. The sum-rule predictions compare reasonably with experiment and shake calculations, but disagree sharply with the semiempirical estimates.
Ejection of the three electrons from lithium in a single electron collision has been observed for the first time. Triply charged lithium was observed in an ion time-of-flight spectrum following electron impact on a sample of ultracold, trapped lithium. The higher signal/background afforded by the trap environment made the observation of Li3+ possible. We measured the ratios of triple-to-double and double-to-single ionization at an impact energy of 1000 eV. The 3+/2+ ratio is approximately 0.001, a value 2 orders of magnitude lower than semiempirical predictions. We present a simple method that uses photoionization data combined with sum-rule analysis to predict the asymptotic charge-state ratios. The sum-rule predictions compare reasonably with experiment and shake calculations, but disagree sharply with the semiempirical estimates.
In the course of this work dynamics in ionization processes of lithium by photon and electron impact were studied. Due to its electronic structure, lithium is an ideal candidate to examine electronic correlation effects and collision dynamics of simple few-body systems. The lithium target is cooled in a magneto-optical trap (MOT) down to the sub-millikelvin regime, which in combination with a reaction microscope (ReMi) allows for the determination of the momentum information of all collision products with unprecedented resolution. An electron gun serving as a new projectile source was implemented in the MOTReMi experiment. From first measurements, which showed that the developed setup is principally operational, time-of-flight and position spectra were analyzed, determining the ratio of Li2+=Li+ ion creation. In a second series of experiments, photoionization of laser-excited lithium has been investigated and fully differential cross sections (FDCS) were examined. As the target and also the laser beam were polarized, orientational effects could be studied. In some cases the electron emission characteristics could directly be deduced from dipole selection rules.
Reaction microscopes enable kinematically complete measurements of atomic and molecular fragmentation. An ultracold atomic target is usually provided by a supersonic gas jet. The apparatus developed in the course of this thesis for the first time combines the principle of the reaction microscope with a magneto-optical trap. This allows for the preparation of lithium atoms in the sub-mK range. Being a three-electron system, its simple atomic structure makes lithium a model system of great topical interest for all kinds of ionization reactions. In order not to deteriorate the determination of the momenta of the charged fragments by the magnetic field of the trap, a pulsed mode of operation is adopted, creating field-free conditions during data acquisition and making efficient use of the stored target. The novel apparatus provides a versatile target for investigations on fragmentation of lithium by electron, ion and photon impact. For the first time, momentum-resolved measurements on multiphoton ionization in intense laser fields with pulse durations of 25~fs and peak intensities in the range between 1011^{11}11~W/cm2^22 and 1016^{16}16~W/cm2^22 were performed. The acquired photoelectron spectra exhibit unexpected structures such as a preferred emission in the direction perpendicular to the laser polarization axis, which are not fully understood yet. Presently, corresponding calculations are being done in several theory groups.
We have observed electron impact ionization of highly excited sodium Rydberg atoms in nsnsns and ndndnd states, n=35−−51n=35--51n=35−−51, below E=2  eVE=2\text{ }\text{ }\mathrm{e}\mathrm{V}E=2  eV electron kinetic energy with energy resolution 0.25 eV. Measured absolute cross sections near 0 eV range from ${\ensuremath{\sigma}}_{35d}\ensuremath{\approx}7\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}10}$ to ${\ensuremath{\sigma}}_{50d}\ensuremath{\approx}4\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}9}\text{ }\text{ }{\mathrm{c}\mathrm{m}}^{2}$. The energy dependence is consistent with that of widely used binary encounter approximation cross sections, and ${\ensuremath{\sigma}}_{n}$ follows a power law in nnn. The measured cross sections are 14 to 24 times larger than theoretically predicted values. This enhancement may signal the effect of large polarizabilities of high Rydberg states not yet accounted for in ionization theories.
Lithium atoms in high Rydberg states, excited in an atomic beam by pulsed electron impact, are passed through a target gas and detected following electric-field state selection. Cross sections obtained from time-of-flight spectra are virtually independent of the principal quantum number and in numerical agreement with calculations for deflection of the core ion alone. This deflection has also been observed directly. These results suggest a new method for very-low-energy ion-atom scattering experiments.