Resonance Broadening of Spectral Lines.

A new approach is suggested for dealing with the many-body aspects of resonance broadening of spectral lines in gases. A Liouville-space formalism is used in which the absorption by $N$ identical molecules undergoing resonance-exchange collisions is described by an $N$ -dimensional projection operator in Liouville space. In the impact approximation, under conditions in which the Doppler shift of resonance frequencies can be neglected, it is shown that the effect of resonance collisions is to modify the linewidth expression obtained by ordinary foreign-gas-type theories. The shape of isolated lines remains, however, Lorentzian. Only a combined effect of Doppler and collision broadening causes appreciable deviations from the Lorentzian shape near the line center, but these deviations are not peculiar to resonance broadening.A new approach is suggested for dealing with the many-body aspects of resonance broadening of spectral lines in gases. A Liouville-space formalism is used in which the absorption by $N$ identical molecules undergoing resonance-exchange collisions is described by an $N$-dimensional projection operator in Liouville space. In the impact approximation, under conditions in which the Doppler shift of resonance frequencies can be neglected, it is shown that the effect of resonance collisions is to modify the linewidth expression obtained by ordinary foreign-gas-type theories. The shape of isolated lines remains, however, Lorentzian. Only a combined effect of Doppler and collision broadening causes appreciable deviations from the Lorentzian shape near the line center, but these deviations are not peculiar to resonance broadening.

Physical Review ADec 1, 197171 citations

A new approach is suggested for dealing with the many-body aspects of resonance broadening of spectral lines in gases. A Liouville-space formalism is used in which the absorption by

N

identical molecules undergoing resonance-exchange collisions is described by an

N

-dimensional projection operator in Liouville space. In the impact approximation, under conditions in which the Doppler shift of resonance frequencies can be neglected, it is shown that the effect of resonance collisions is to modify the linewidth expression obtained by ordinary foreign-gas-type theories. The shape of isolated lines remains, however, Lorentzian. Only a combined effect of Doppler and collision broadening causes appreciable deviations from the Lorentzian shape near the line center, but these deviations are not peculiar to resonance broadening.