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Applied Optics

Principles of Quantum Electronics. By Dietrich Marcuse

Brian S. Wherrett

Published Mar 1, 1981• 0 citations
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Principles of Quantum Electronics

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Dietrich Marcuse 1980 New York: Academic xvi + 494 pp price $35 The field of quantum electronics has grown enormously over the last 15 years and now encompasses a wide range of research including masers, lasers, nonlinear optics and parametric devices, and photon counting statistics. Unfortunately within this field few good texts are available at graduate or advanced graduate levels.

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A comprehensive description of molecular electron-transfer reactions is essential for our understanding of fundamental phenomena in bioenergetics and molecular electronics.However, experimental studies of molecular systems in condensed-phase environments face difficulties in independently controlling the parameters that govern the transfer mechanism with high precision.We show that, instead, trapped-ion experiments allow us to reproduce and continuously connect vastly different regimes of molecular charge transfer through precise tuning of, e.g., the phonon temperature, electron-phonon interaction, and electronic coupling.Such a setting does not only allow us to reproduce widely used transport models, such as Marcus theory.It also provides access to transfer regimes that are unattainable for molecular experiments, while controlling and measuring the relevant observables on the level of individual quanta.Our numerical simulations predict an unconventional quantum transfer regime, featuring a transition from quantum adiabatic to resonance-assisted transfer as a function of the donor-acceptor energy gap, which can be reached by increasing the electronic coupling at low temperatures.Trapped-ion-based quantum simulations thus promise to enhance our microscopic understanding of molecular electron-transfer processes and may help to reveal efficient design principles for synthetic devices.