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Viewpoint: Equilibration in Quantum Systems

Sebastian Deffner

Published Nov 13, 2019• 0 citations
Publisher

Abstract

Two research groups show that specific contributions to entropy may be the key to understanding how and when quantum systems equilibrate.
DOI
10.13016/m2i2ck-hha7

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The thermodynamic entropy of an isolated system is given by its von Neumann entropy. Over the last few years, there has been an intense activity to understand the thermodynamic entropy from the principles of quantum mechanics. More specifically, is there a relation between the (von Neumann) entropy of entanglement between a system and some (separate) environment and the thermodynamic entropy? It is difficult to obtain the relation for many body systems, hence, most of the work in the literature has focused on small number systems. In this work, we consider black holes—which are simple yet macroscopic systems—and show that a direct connection could not be made between the entropy of entanglement and the Hawking temperature. In this work, within the adiabatic approximation, we explicitly show that the Hawking temperature is indeed given by the rate of change of the entropy of entanglement across a black hole’s horizon with regard to the system energy. This is yet other numerical evidence leading to understanding the key features of black-hole thermodynamics from the viewpoint of quantum information theory.
Understanding how macroscopic thermodynamic behavior emerges from microscopic quantum dynamics remains an open problem. While equilibration of quantum observables is well established, thermodynamics also relies on variables not directly associated with linear operators, but which are defined instead as functions of expectation values. Whether and how such derived quantities inherit equilibration properties is an open question. Here, we establish that any continuously differentiable function of equilibrating expectation values also equilibrates. We apply this result to a bipartite isolated system, showing that the entropy and conjugate variables of each subsystem -- defined through Jaynes' maximum entropy principle -- equilibrate. Moreover, with the assumption that their equilibrium properties depend solely on local conserved quantities, we show the dynamical maximization of the total entropy, enforcing equality of conjugate variables across subsystems. These results provide a direct dynamical justification for entropy maximization and the emergence of thermodynamic equilibrium conditions, showing that fundamental principles of thermodynamics follow from the unitary evolution of quantum systems.