Trapping particles is a key starting point for a range of physics experiments. The ability to confine, manipulate and interrogate a trapped species enables an invaluable degree of control and precision. Each trap offers different advantages and possibilities, and emerging experiments often demand different methods of trapping. This thesis describes a new three-dimensional microwave trap for atoms and molecules. Like an optical dipole trap, it can trap ground state polar molecules, but its depth and volume are larger by factors of 10^3 and 10^9 respectively. The experiment consists of a lithium oven, Zeeman slower, magneto-optical trap (MOT), a moving magnetic trap, and a high-quality Fabry-Perot cavity which serves as the microwave trap. Starting from a MOT of 1×10^8 lithium-7 atoms, the atomic cloud is cooled from a temperature of around 1mK to 41(1)μK with the recently developed Raman grey molasses method. Next, the population is optically pumped to a magnetically trappable state, and up to 85(2)% are loaded into a quadrupole magnetic trap. These atoms are then transferred to a moving magnetic trap and translated 600mm to the centre of the microwave cavity. After optimizing the transport to minimize atom heating and loss, we can produce samples of 2×10^7 atoms in the microwave chamber, at a phase space density of 3.58(15)×10^7. Finally, loading of the microwave trap is demonstrated and its basic properties studied. When the input power to the cavity is 610W, the electric field amplitude at the centre reaches roughly 20kV/cm. At this input power, centre-of-mass oscillation frequencies in the microwave trap were measured as 28.55(5)Hz along the axis of the cavity, and 8.81(8)Hz along the orthogonal direction. The observed lifetime was 1.76(12)s, limited by the vacuum quality. The atomic cloud expands and cools to 22(3)μK when loaded into the microwave trap, with a phase space density of 4(1)×10^7. This is consistent with adiabatic loading from the magnetic trap.
Trapping particles is a key starting point for a range of physics experiments. The ability to confine, manipulate and interrogate a trapped species enables an invaluable degree of control and precision. Each trap offers different advantages and possibilities, and emerging experiments often demand different methods of trapping. This thesis describes a new three-dimensional microwave trap for atoms and molecules. Like an optical dipole trap, it can trap ground state polar molecules, but its depth and volume are larger by factors of 10^3 and 10^9 respectively. The experiment consists of a lithium oven, Zeeman slower, magneto-optical trap (MOT), a moving magnetic trap, and a high-quality Fabry-Perot cavity which serves as the microwave trap. Starting from a MOT of 1×10^8 lithium-7 atoms, the atomic cloud is cooled from a temperature of around 1mK to 41(1)μK with the recently developed Raman grey molasses method. Next, the population is optically pumped to a magnetically trappable state, and up to 85(2)% are loaded into a quadrupole magnetic trap. These atoms are then transferred to a moving magnetic trap and translated 600mm to the centre of the microwave cavity. After optimizing the transport to minimize atom heating and loss, we can produce samples of 2×10^7 atoms in the microwave chamber, at a phase space density of 3.58(15)×10^7. Finally, loading of the microwave trap is demonstrated and its basic properties studied. When the input power to the cavity is 610W, the electric field amplitude at the centre reaches roughly 20kV/cm. At this input power, centre-of-mass oscillation frequencies in the microwave trap were measured as 28.55(5)Hz along the axis of the cavity, and 8.81(8)Hz along the orthogonal direction. The observed lifetime was 1.76(12)s, limited by the vacuum quality. The atomic cloud expands and cools to 22(3)μK when loaded into the microwave trap, with a phase space density of 4(1)×10^7. This is consistent with adiabatic loading from the magnetic trap.
The aim of our experiment is to explore two methods of creating an ultracold dipolar gas which can subsequently be used to simulate quantum phenomena. The first method is to sympathetically cool polar molecules. In this case, the molecules are overlapped with ultracold lithium atoms, thus allowing the two clouds to thermalise through elastic collisions. The second method is to electrically polarise ultracold lithium atoms using an electric field of approximately 1MV/cm. This involves placing the atoms between two high voltage electrodes. This thesis describes and characterises the setup used to produce, trap and transport a cloud of lithium-7 atoms. The setup consists of a lithium oven, Zeeman slower, magneto-optical trap (MOT) and magnetic trap. Up to 2.3×10^8 atoms are loaded into the MOT with an initial temperature of 1.3 mK. By implementing a compressed MOT phase the temperature is reduced to 0.75 mK. Before transport, 23% of the MOT atoms are transferred into the magnetic trap, which has a lifetime of 1.53±0.01 s in the MOT chamber. Using a motorised translation stage to move the magnetic trapping coils, atomic transport over a distance of 44 cm from the MOT chamber to the science chamber has been demonstrated. The transport efficiency is 41%. In the science chamber the lifetime of the magnetic trap has been measured as 18.5±0.7 s. Experiments to optimise the absorption imaging system have also been carried out, highlighting the fact that a time and position dependent magnetic field is present after the trapping coils switch off. The feasibility of producing a 1MV/cm electric field has been investigated. By using indium tin oxide coated glass electrodes in an adjustable electrode mount, an electric field of approximately 0.2MV/cm has been generated. These electrodes were subsequently replaced with super-polished stainless steel electrodes which generated a field of 0.38MV/cm.
Cold polar molecules provide unique opportunities to test fundamental physics and chemistry. Their permanent electric dipole moments and rich internal structure arising from their vibrational and rotational motion, makes them sensitive probes for new physics. These features also make them ideal for studying ultracold chemistry, for simulating the behaviour of strongly interacting many-body quantum systems, and for quantum information science. This thesis describes a number of advances in cold molecule physics. The optimum method for producing an intense, pulsed, supersonic beam of cold CH molecules is investigated, resulting in a beam with 3.5 × 109 ground state CH molecules per steradian per shot. The beam has a translational temperature of 400 mK and a velocity that is tuneable between 400 and 1800 m s−1 . The lowest-lying Λ-doublet transitions of ground state CH, at 3.3 GHz and 0.7 GHz, are exceptionally sensitive to variations in the fine-structure constant α and the electron-to-proton mass ratio µ. Many modern theories predict that these constants may depend on time, position, or local matter density. Using a novel spectroscopic method, the frequencies of these microwave transitions are measured with accuracy down to 3 Hz. By comparing to radio astronomical observations, the hypothesis that fundamental constants may differ between the high and low-density environments of the Earth and the interstellar medium of the Milky Way is tested. These measurements find no variation and set upper limits of |∆α/α| < 2.1 × 10−7 and |∆µ/µ| < 4.3 × 10−7 . The frequency of the lowest millimetre-wave transition of CH, near 533 GHz, is also measured with an accuracy of 0.6 kHz. The development of a novel type of trap for ground-state polar molecules is presented. Trapping polar molecules is a necessary condition to cool them to ultracold temperatures of 1 µK and below. The trap uses a high intensity microwave field in a Fabry-P´erot resonator. Experimental and theoretical investigations are presented that explore the modes of the cavity, how to obtain the highest possible quality factor, and how to optimally couple the microwave power into the cavity. Finally, a cold supersonic beam of BH molecules is developed. This molecule appears to be particularly well-suited to direct laser cooling due to its favourable rotational structure and Franck-Condon factors. The laser cooling concept is described, and a first spectroscopic investigation of the relevant molecular structure is presented.
Integrating two chemically distinct atomic species into a miniaturized, high-flux cold-atom source is a key challenge for modern experiments with ultracold atomic mixtures and polar molecules. Here, we report a compact setup with in-series two-dimensional magneto-optical traps (2D MOTs) that provides high-flux cold lithium and rubidium atoms. Thanks to the efficient short-distance Zeeman slowing, the maximum 3D MOT loading rate of lithium atoms reaches a record value of 6.6 × 10 9 atoms/s at a moderate lithium-oven temperature of 372 degrees Celsius, which is 44 times higher than that without the Zeeman slowing light. The flux of rubidium is also as high as 2.3 × 10 9 atoms/s with the rubidium oven held at room temperature. Meanwhile, the entire vacuum-chamber system, including an ultra-high-vacuum science cell, is within a small volume of 65 × 55 × 70 cm 3 . Our work represents a substantial improvement over traditional bulky and complex dual-species cold-atom setups. It provides a good starting point for the fast production of a double-degenerate lithium-rubidium atomic mixture and large samples of ultracold lithium-rubidium ground-state molecules.
From studies of fundamental physics to quantum technologies the production of ultracold molecules will have a huge impact across a range of applications. For many years laser cooling, which became an invaluable tool in cold atomic physics, was deemed to be too impractical for application to molecules. Nevertheless, laser cooling has now been demonstrated for a few molecular species. Using a frequency-chirped laser slowing technique, the velocity distribution of a pulse of CaF molecules is compressed and slowed from 180 m/s to about 10 m/s. These slow molecules are then captured in a magneto-optical trap. I present measurements that show how the number of molecules, the photon scattering rate, the oscillation frequency, damping constant, temperature, cloud size and lifetime depend on the key parameters of the magneto-optical trap, especially the intensity and detuning of the main cooling laser. The trap contains up to 2*10^4 molecules, the maximum photon scattering rate is 2.5*10^6 s-1 per molecule, the maximum oscillation frequency is 100 Hz, the maximum damping constant is 500 s^-1, and the minimum rms radius of the trapped cloud is 1.5 mm. A minimum temperature of 730 microkelvin is obtained by ramping down the laser intensity to lower values. To reach lower temperatures, the cloud is loaded into a blue-detuned optical molasses, which cools the molecules to 55 microkelvin, well below the Doppler-limiting temperature. I characterise the cooling process and suggest the sub-Doppler mechanisms responsible. These ultracold molecules are the optically pumped into a single quantum state, and coherently transferred between selected hyperfine components of the ground and first-excited rotational states. Finally, the ultracold, state-selected molecules are loaded into a magnetic trap that has a lifetime of about 1 s.
Integrating two chemically distinct atomic species into a miniaturized, high-flux cold-atom source is a key challenge for modern experiments with ultracold atomic mixtures and polar molecules.Here, we report a compact setup with in-series two-dimensional magneto-optical traps (2D MOTs) that provides high-flux cold lithium and rubidium atoms.Thanks to the efficient short-distance Zeeman slowing, the maximum 3D MOT loading rate of lithium atoms reaches a record value of 6.6 × 10 9 atoms/s at a moderate lithium-oven temperature of 372 degrees Celsius, which is 44 times higher than that without the Zeeman slowing light.The flux of rubidium is also as high as 2.3 × 10 9 atoms/s with the rubidium oven held at room temperature.Meanwhile, the entire vacuum-chamber system, including an ultra-high-vacuum science cell, is within a small volume of 65 × 55 × 70 cm 3 .Our work represents a substantial improvement over traditional bulky and complex dual-species cold-atom setups.It provides a good starting point for the fast production of a double-degenerate lithium-rubidium atomic mixture and large samples of ultracold lithium-rubidium ground-state molecules.
Ultracold polar molecules have emerged as promising platforms for quantum simulation, quantum information science, precision measurements of fundamental symmetry violations, and quantum chemistry. Over the past decade, rapid progress in direct laser cooling of molecules has enabled new capabilities such as magneto-optical traps (MOTs), sub-Doppler cooling, and optical dipole traps (ODTs), expanding the quantum toolbox with ultracold molecules of complex internal structures and strong dipolar interactions. This thesis presents the design, construction, and operation of an experiment on ultracold strontium monofluoride (88Sr19F) molecules, demonstrating state-of-the-art techniques for molecular laser cooling and trapping. The apparatus integrates a broad range of technical sub-systems, including cryogenics, ultra-high vacuum, optics, electronics, and automated laboratory control software. SrF molecules produced in a slowed cryogenic buffer gas beam are captured into a dual-frequency MOT. Subsequent Λ-enhanced gray molasses cooling reduces the molecule temperature to as low as 5 μK. A novel blue-detuned MOT is also implemented to further compress the molecular cloud, increasing the density by a factor of ∼ 400. At this high density, SrF molecules are efficiently loaded into an ODT, a tight, conservative trap with long lifetimes. Population transfer between different rotational levels is achieved via optical pumping and coherent microwave control, yielding ∼ 0.8 ms coherence time in Rabi oscillation and ∼ 90 % transfer efficiency. This thesis also describes the development of an ultracold rubidium (87Rb) atom experiment, in which a loading rate of ∼ 10^10 atoms/s into a radio-frequency (RF) MOT is demonstrated. A modular two-dimensional MOT serves as the Rb source and can be seamlessly integrated into the SrF apparatus, opening the possibility for future studies of co-trapping and sympathetic cooling of SrF molecules with atoms. The results presented in this thesis establish an experimental foundation for exploring new frontiers in ultracold molecular physics.