The energy parameter in the stationary Schrödinger equation is primarily continuous. Schrödinger has selected the discrete quantum states by means of boundary conditions. This, however, is mathematics for classical systems like strings and pipes. And, more important, it hides the intrinsic discrete structure of that equation. The latter is represented by the recursion relations between solutions to different values of the energy parameter. These follows from Whittaker’s integral expressions of the solutions and hold true for all solutions, not only for Schrödinger’s eigensolutions. The physically relevant solutions are distinguished by certain mathematical properties as well as physical criteria, in particular, by their compliance with the absence of perpetua mobilia. This non-classical approach is exemplified by means of the model system harmonic oscillator. For this, the chapter starts with a sketch of the classical harmonic oscillator, including quite general topics such as the separation of internal and external system parameters and Huygens’ principle, which will reappear in the quantum realm.
The energy parameter in the stationary Schrödinger equation is primarily continuous. Schrödinger has selected the discrete quantum states by means of boundary conditions. This, however, is mathematics for classical systems like strings and pipes. And, more important, it hides the intrinsic discrete structure of that equation. The latter is represented by the recursion relations between solutions to different values of the energy parameter. These follows from Whittaker’s integral expressions of the solutions and hold true for all solutions, not only for Schrödinger’s eigensolutions. The physically relevant solutions are distinguished by certain mathematical properties as well as physical criteria, in particular, by their compliance with the absence of perpetua mobilia. This non-classical approach is exemplified by means of the model system harmonic oscillator. For this, the chapter starts with a sketch of the classical harmonic oscillator, including quite general topics such as the separation of internal and external system parameters and Huygens’ principle, which will reappear in the quantum realm.
The "quantum equation" should "carry the quantum conditions in itself" (Second Commun., p. 511); 2. There should be a special mathematical method for solving the stationary Schrödinger equation, which accounts for the non-classical character of the quantization problem, ie, which is different from the classical eigenvalue methods for calculating the (eigen)modes of strings, resonators and so on (ibid., p. 513);3. The derivation should uniquely decide, that the energy rather than the frequency values are discretized (ibid., pp.511, 519), since only the former means true quantization, while the latter corresponds to the classical discretization mentioned in requirement 2;4. The use of the classical expressions for the kinetic and potential energies should be justified (Fourth Commun., p. 113).Schrödinger's requirements 1 and 2 mean, that -contrary to the very title of the papersquantization is actually not an eigenvalue problem.For in the latter the discretization is imposed not by the differential equation itself, but by the boundary conditions, and this is the classical discretization for standing waves in organ pipes etc.I will fulfill all four requirements by treating quantization as a selection problem.The number of stationary states of a quantum system is smaller than that of a classical system [6].I will describe, (i), the selection of quantum systems out of the set of all mechanical systems and, (ii), the selection of their stationary states out of the continuum of classical stationary states.Earlier arguing [19][10] is improved and extended in several essential points. Elements of an Eulerian representation of classical mechanics Euler's axiomsLeonhard Euler [20][21][22][23][24][25] was the first to apply the calculus to all areas of mathematics and mechanics of his time, and he developed novel methods, such as the calculus of variations and topology.Moreover, he worked out an axiomatic of mechanics, where only Newton's Law (axiom) 1 concerning the conservation of stationary states is retained as an axiom, while Newton's Laws (axioms) 2 and 3 concerning the change of stationary states are treated as problems to be solved (for a detailed account, see [19][10][45]).This allows for introducing alternative equations of motion without loosing the contact to CM.The existence of stationary states is postulated in the following axioms (as in Newton's axioms, rotatory motion is not considered). Axiom E0: Every body is either resting or moving.This means, that the subsequent axioms E1 and E2 are not independent of each other; they exclude each other and, at once, they are in harmony with each other [22].
This chapter discusses the physical properties of atoms and molecules, which are quantized. This means that they can only take certain discrete values rather than a full range of continuously varying values. The chapter examines the quantized energy levels of a molecule. These are called stationary states, which describe an energy that is independent of time. The chapter also outlines the procedure for constructing a quantum mechanical Hamiltonian, which includes writing down the complete and classical expression for the energy of the system. The chapter reviews the general approach to the determination of energy levels of a physical system. This involves two stages: First, the appropriate Hamiltonian is defined and, in a second step, the eigenfunctions and eigenvalues of the Hamiltonian are determined. The chapter also discusses the Schrödinger equation, which can only be solved for one-body systems.
On the basis of Nelson’s stochastic mechanics derivation of the Schrödinger equation, a formal mathematical structure of non-relativistic quantum mechanics equivalent to the one in classical analytical mechanics has been established in the literature. We recently were able to augment this structure by deriving quantum Hamilton equations of motion by finding the Nash equilibrium of a stochastic optimal control problem, which is the generalization of Hamilton’s principle of classical mechanics to quantum systems. We showed that these equations allow a description and numerical determination of the ground state of quantum problems without using the Schrödinger equation. We extend this approach here to deliver the complete discrete energy spectrum and related eigenfunctions for bound states of one-dimensional stationary quantum systems. We exemplify this analytically for the one-dimensional harmonic oscillator and numerically by analyzing a quartic double-well potential, a model of broad importance in many areas of physics. We furthermore point out a relation between the tunnel splitting of such models and mean first passage time concepts applied to Nelson’s diffusion paths in the ground state.
Chapter 9 is devoted to a detailed study of the harmonic oscillator in one dimension. The time-dependent Schrödinger equation is used to construct the coherent oscillator packet with minimal dispersion, which provides an opportunity to appreciate the similarities and differences between the dynamics of the classical and quantum oscillators. In a second step, we study the stationary solutions of the oscillator, which represent one of the most important orthogonal sets of quantum eigenfunctions because of its many applications, properties, and relative simplicity. Further, the use of raising and lowering (or creation and annihilation) operators is shown to be a powerful way of dealing with both material and field oscillators in general. Finally, the problem of two coupled oscillators is used to generalize the Schrödinger equation to the case of more than one particle.
The study of quantum properties of the harmonic oscillator is important in physics as many real-world systems oscillate harmonically. Motion of systems in a confined space is often modeled as being a quantized harmonic motion or, in first instance, is approximated by a harmonic motion. This chapter helps the reader to solve the equation employing an algebraic operator technique, which is based on the Dirac notation. This approach has several definite advantages and exploits the commutation relations among the operators involved and their properties. The chapter transforms the stationary Schrodinger equation into a second-order differential equation and finds the solution to the equation with the aid of a more advanced mathematical technique that involves special functions. The energy of a harmonic oscillator is quantized, with the sequence of values. The difference in energy between adjacent energy levels is equal to the energy of a single photon, ħω.
This chapter expresses the whole of quantum mechanics in terms of a small set of postulates, which embraces the behaviour of all known forms of matter. It introduces the postulates and illustrates how they are used, including how to apply them to problems of chemical interest, such as atomic and molecular structure and the properties of molecules. It also establishes the full significance of the Hψ=Eψequation and provides a foundation for its application. The chapter includes the solutions of the Schrödinger equation for a particle and the operator, which is a symbol for an instruction to carry out some action on a function. The principal mathematical difference between classical mechanics and quantum mechanics is that whereas in the former physical observables are represented by functions, in quantum mechanics they are represented by mathematical operators.