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On an exact path integral of the hydrogen atom

Kazuo Fujikawa

Published Feb 15, 1996• 0 citations
OpenAlex

Abstract

The path integral evaluation of the hydrogen atom by Duru and Kleinert is studied by recognizing it as a special case of the general treatment of the separable Hamiltonian of Liouville-type. The basic dynamical principle involved is identified as the Jacobi’s principle of least action for given energy which is reparametrization invariant, and thus the appearance of a gauge freedom is naturally understood. Unlike the conventional Feynman path integral,which deals with a space-time picture of particle motion, the path integral on the basis of the Jacobi’s principle sums over orbits in space. We illustrate these properties by evaluating an exact path integral of the hydrogen atom in parabolic coordinates. In 3-dimensions the parabolic coordinates do not quite lead to a Liouville-type Hamiltonian, but we can devise asimple trick which converts it to a Liouville-type Hamiltonian and thus avoiding the use of the Kustaanheimo-Stiefel transformation. In the present formulation, the Hamiltonian for Stark effect is converted to the one for anharmonic oscillators with an unstable quartic coupling. We also study the hydrogen atom path integral from a view point of one-dimensional quantum gravity coupled to matter fields representing the electron coordinates. A simple BRST analysis of the problem is presented. 1 1

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The path integral evaluation of the hydrogen atom by Duru and Kleinert is studied by recognizing it as a special case of the general treatment of the separable Hamiltonian of Liouville-type. The basic dynamical principle involved is identified as the Jacobi’s principle of least action for given energy which is reparametrization invariant, and thus the appearance of a gauge freedom is naturally understood. Unlike the conventional Feynman path integral,which deals with a space-time picture of particle motion, the path integral on the basis of the Jacobi’s principle sums over orbits in space. We illustrate these properties by evaluating an exact path integral of the hydrogen atom in parabolic coordinates. In 3-dimensions the parabolic coordinates do not quite lead to a Liouville-type Hamiltonian, but we can devise asimple trick which converts it to a Liouville-type Hamiltonian and thus avoiding the use of the Kustaanheimo-Stiefel transformation. In the present formulation, the Hamiltonian for Stark effect is converted to the one for anharmonic oscillators with an unstable quartic coupling. We also study the hydrogen atom path integral from a view point of one-dimensional quantum gravity coupled to matter fields representing the electron coordinates. A simple BRST analysis of the problem is presented. 1 1
The general treatment of a separable Hamiltonian of Liouville-type is well-known in operator formalism. A path integral counterpart is formulated if one starts with the Jacobi's principle of least action, and a path integral evaluation of the Green's function for the hydrogen atom by Duru and Kleinert is recognized as a special case. The Jacobi's principle of least action for given energy is reparametrization invariant, and the separation of variables in operator formalism corresponds to a choice of gauge in path integral. The Green's function is shown to be gauge independent,if the operator ordering is properly taken into account. These properties are illustrated by evaluating an exact path integral of the Green's function for the hydrogen atom in parabolic coordinates.
A general path integral analysis of the separable Hamiltonian of Liouville-type is reviewed. The basic dynamical principle used is the Jacobi's principle of least action for given energy which is reparametrization invariant, and thus the gauge freedom naturally appears. The choice of gauge in path integral corresponds to the separation of variables in operator formalism. The gauge independence and the operator ordering are closely related. The path integral in this formulation sums over orbits in space instead of space-time. An exact path integral of the Green's function for the hydrogen atom in parabolic coordinates is ilustrated as an example, which is also interpreted as one-dimensional quantum gravity with a quantized cosmological constant.
The path integral formulation of quantum mechanics generalizes the action principle of classical mechanics. The Feynman path integral is, roughly speaking, a sum over all possible paths that a particle can take between fixed endpoints, where each path contributes to the sum by a phase factor involving the action for the path. The resulting sum gives the probability amplitude of propagation between the two endpoints, a quantity called the propagator. Solutions of the Feynman path integral formula exist, however, only for a small number of simple systems, and modifications need to be made when dealing with more complicated systems involving singular potentials, including the Coulomb potential. We derive a generalized path integral formula, that can be used in these cases, for a quantity called the pseudo-propagator from which we obtain the fixed-energy amplitude, related to the propagator by a Fourier transform. The new path integral formula is then successfully solved for the Hydrogen atom in two and three dimensions, and we obtain integral representations for the fixed-energy amplitude.
The path integral formulation of quantum mechanics constructs the propagator by evaluating the action S for all classical paths in coordinate space. A corresponding momentum path integral may also be defined through Fourier transforms in the endpoints. Although these momentum path integrals are especially simple for several special cases, no one has, to my knowledge, ever formally constructed them from all classical paths in momentum space. I show that this is possible because there exists another classical mechanics based on an alternate classical action R. Hamilton's Canonical equations result from a variational principle in both S and R. S uses fixed beginning and ending spatial points while R uses fixed beginning and ending momentum points. This alternative action's classical mechanics also includes a Hamilton-Jacobi equation. I also present some important points concerning the beginning and ending conditions on the action necessary to apply a Canonical transformation. These properties explain the failure of the Canonical transformation in the phase space path integral. It follows that a path integral may be constructed from classical position paths using S in the coordinate representation or from classical momentum paths using R in the momentum representation. Several example calculations are presented that illustrate the simplifications and practical advantages made possible by this broader view of the path integral. In particular, the normalized amplitude for a free particle is found without using the Schrodinger equation, the internal spin degree of freedom is simply and naturally derived, and the simple harmonic oscillator is calculated.