We report on a precision measurement of the
D line tune-out wavelength of
87Rb in the hyperfine ground state $\left|F=1,{m}_{F}=0,\ifmmode\pm\else\textpm\fi{}1\right\ensuremath{\rangle}$ manifold at
790nm, where the scalar ac Stark shifts of the
D1 and the
D2 lines cancel. This wavelength is sensitive to usually neglected contributions from vector and tensor ac Stark shifts, transitions to higher principle quantum numbers, and core electrons. The ac Stark shift is probed by Kapitza-Dirac scattering of a rubidium Bose-Einstein condensate in a one-dimensional optical lattice in free space and controlled magnetic environment. The tune-out wavelength of the magnetically insensitive
mF=0 state was determined to
790.01858(23)nm with sub-pm accuracy. An in situ absolute polarization, and magnetic background field measurement is performed by employing the ac vector Stark shift for the ${m}_{F}=\ifmmode\pm\else\textpm\fi{}1$ states. Comparing our findings to theory, we get quantitative insight into atomic physics beyond commonly used two-level atom approximations or the neglect of inner shell contributions.
The static and dynamic polarizabilities and the tune-out wavelengths of the ground state of Rb and the hyperfine ground states of
87,85Rb have been calculated by using the relativistic configuration interaction plus core polarization (RCICP) approach. It is found that the first primary tune-out wavelengths of the
5s1/2,F=1,2 states of
87Rb are 790.018187(193) and 790.032602(193) nm, respectively, where the calculated result for the
5s1/2,F=2 state is in good agreement with the latest high-precision measurement 790.032388(32) nm [R. H. Leonard et al., Phys. Rev. A 92, 052501 (2015)]. Similarly, the first primary tune-out wavelengths of the
5s1/2,F=2,3 states of
85Rb are 790.023515(218) and 790.029918(218) nm, respectively. Furthermore, the tune-out wavelengths for the different magnetic sublevels
MF of each hyperfine level
F are also determined by considering the contributions of tensor polarizabilities.