A Fermi degenerate gas of polar molecules

Antun Balaž, Vladimir Veljić, Axel Pelster

Hui Zhai

Luigi De Marco, Giacomo Valtolina, Kyle Matsuda +3 more

Experimental realization of a quantum degenerate gas of molecules would provide access to a wide range of phenomena in molecular and quantum sciences. However, the very complexity that makes ultracold molecules so enticing has made reaching degeneracy an outstanding experimental challenge over the past decade. We now report the production of a degenerate Fermi gas of ultracold polar molecules of potassium-rubidium. Through coherent adiabatic association in a deeply degenerate mixture of a rubidium Bose-Einstein condensate and a potassium Fermi gas, we produce molecules at temperatures below 0.3 times the Fermi temperature. We explore the properties of this reactive gas and demonstrate how degeneracy suppresses chemical reactions, making a long-lived degenerate gas of polar molecules a reality.

Michael G. Bowler

Peiru He, Thomas Bilitewski, Chris H. Greene +1 more

A recent experiment [L. De Marco, G. Valtolina, K. Matsuda, W. G. Tobias, J. P. Covey, and J. Ye, A degenerate Fermi gas of polar molecules, Science 363, 853 (2019)] reported for the first time the preparation of a Fermi degenerate gas of polar molecules and observed a suppression of their chemical reaction rate compared to the one expected from a treatment assuming classical Maxwell-Boltzmann statistics. While it was hypothesized that the suppression in the ultracold regime had its roots in the Fermi statistics of the molecules, this argument is inconsistent with the fact that the Fermi pressure should set a lower bound for the chemical reaction rate. Here we develop a simple model of chemical reactions that occur via the formation and decay of molecular complexes. We indeed find that pure two-body molecule losses are unable to explain the observed suppression. Instead we extend our description beyond two-body physics by including multibody complex-molecule interactions. Although our model is able to quantitatively reproduce recent experimental observations, it requires parameters physically unlikely for direct microscopic interactions. The underlying processes, however, might emerge effectively from many-body or medium effects. A detailed understanding of the direct microscopic mechanisms responsible for these higher-order interaction processes is therefore still pending.

D. Baillie, R. N. Bisset, P. B. Blakie

We calculate the stability diagram for a trapped normal Fermi or Bose gas with dipole-dipole interactions. Our study characterizes the roles of trap geometry and temperature on the stability using Hartree-Fock theory. We find that exchange appreciably reduces stability and that, for bosons, the double instability feature in oblate trapping geometries predicted previously is still predicted by the Hartree-Fock theory. Our results are relevant to current experiments with polar molecules and will be useful in developing strategies to obtain a polar molecule Bose-Einstein condensate or degenerate Fermi gas.