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Point and surface interactions in quantum mechanics

Rutger‐Jan Lange

Published Jan 29, 2014• 0 citations
OpenAlex

Abstract

Much of the literature on point interactions in quantum mechanics has focused on the differential form of Schrodinger's equation. This paper, in contrast, investigates the integral form of Schrodinger's equation. While both forms are known to be equivalent for smooth potentials, this is not true for distributional potentials. Here, we assume that the potential is given by a distribution defined on the space of discontinuous test functions. First, by using Schrodinger's integral equation, we confirm a seminal result by Kurasov, which was originally obtained in the context of Schrodinger's differential equation. This hints at a possible deeper connection between both forms of the equation. We also sketch a generalisation of Kurasov's result to hypersurfaces. Second, we derive a new closed-form solution to Schrodinger's integral equation with a delta prime potential. This potential has attracted considerable attention, including some controversy. Interestingly, the derived propagator satisfies boundary conditions that were previously derived using Schrodinger's differential equation. Third, we derive boundary conditions for `super-singular' potentials given by higher-order derivatives of the delta potential. These boundary conditions cannot be incorporated into the normal framework of self-adjoint extensions. We show that the boundary conditions depend on the energy of the solution, and that probability is conserved. This paper thereby confirms several seminal results and derives some new ones. In sum, it shows that Schrodinger's integral equation is viable tool for studying singular interactions in quantum mechanics.

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Much of the literature on point interactions in quantum mechanics has focused on the differential form of Schrodinger's equation. This paper, in contrast, investigates the integral form of Schrodinger's equation. While both forms are known to be equivalent for smooth potentials, this is not true for distributional potentials. Here, we assume that the potential is given by a distribution defined on the space of discontinuous test functions. First, by using Schrodinger's integral equation, we confirm a seminal result by Kurasov, which was originally obtained in the context of Schrodinger's differential equation. This hints at a possible deeper connection between both forms of the equation. We also sketch a generalisation of Kurasov's result to hypersurfaces. Second, we derive a new closed-form solution to Schrodinger's integral equation with a delta prime potential. This potential has attracted considerable attention, including some controversy. Interestingly, the derived propagator satisfies boundary conditions that were previously derived using Schrodinger's differential equation. Third, we derive boundary conditions for `super-singular' potentials given by higher-order derivatives of the delta potential. These boundary conditions cannot be incorporated into the normal framework of self-adjoint extensions. We show that the boundary conditions depend on the energy of the solution, and that probability is conserved. This paper thereby confirms several seminal results and derives some new ones. In sum, it shows that Schrodinger's integral equation is viable tool for studying singular interactions in quantum mechanics.
Much of the literature on point interactions in quantum mechanics has focused on the differential form of Schrödinger’s equation. This paper, in contrast, investigates the integral form of Schrödinger’s equation. While both forms are known to be equivalent for smooth potentials, this is not true for distributional potentials. Here, we assume that the potential is given by a distribution defined on the space of discontinuous test functions. First, by using Schrödinger’s integral equation, we confirm a seminal result by Kurasov, which was originally obtained in the context of Schrödinger’s differential equation. This hints at a possible deeper connection between both forms of the equation. We also sketch a generalisation of Kurasov’s [J. Math. Anal. Appl. 201(1), 297–323 (1996)] result to hypersurfaces. Second, we derive a new closed-form solution to Schrödinger’s integral equation with a delta prime potential. This potential has attracted considerable attention, including some controversy. Interestingly, the derived propagator satisfies boundary conditions that were previously derived using Schrödinger’s differential equation. Third, we derive boundary conditions for “super-singular” potentials given by higher-order derivatives of the delta potential. These boundary conditions cannot be incorporated into the normal framework of self-adjoint extensions. We show that the boundary conditions depend on the energy of the solution and that probability is conserved. This paper thereby confirms several seminal results and derives some new ones. In sum, it shows that Schrödinger’s integral equation is a viable tool for studying singular interactions in quantum mechanics.
In this paper we study the time dependent Schrödinger equation with all possible self-adjoint singular interactions located at the origin, which include the δ and δ′-potentials as well as boundary conditions of Dirichlet, Neumann, and Robin type as particular cases. We derive an explicit representation of the time dependent Green's function and give a mathematical rigorous meaning to the corresponding integral for holomorphic initial conditions, using Fresnel integrals. Superoscillatory functions appear in the context of weak measurements in quantum mechanics and are naturally treated as holomorphic entire functions. As an application of the Green's function we study the stability and oscillatory properties of the solution of the Schrödinger equation subject to a generalized point interaction when the initial datum is a superoscillatory function.
The Schrödinger equation, in hyperspherical coordinates, is solved in closed form for a system of three particles on a line, interacting via pair delta functions. This is for the case of equal masses and potential strengths. The interactions are replaced by appropriate boundary conditions. This leads then to requiring the solution of a free-particle Schrödinger equation subject to these boundary conditions. A generalized Kontorovich–Lebedev transformation is used to write this solution as an integral involving a product of Bessel functions and pseudo-Sturmian functions. The coefficient of the product is obtained from a three-term recurrence relation, derived from the boundary condition. The contours of the Kontorovich–Lebedev representation are fixed by the asymptotic conditions. The scattering matrix is then derived from the exact solution of the recurrence relation. The wavefunctions that are obtained are shown to be equivalent to those derived by McGuire. The method can clearly be applied to a larger number of particles and hopefully might be useful for unequal masses and potentials.
When dealing with singular potentials, such as point interactions, the term V ( x )ψ( x ) in Schrödinger's equation is, in general, mathematically ill-defined. The traditional way of dealing with this difficulty, by employing regularization techniques, has led to some ambiguous results for the δ'( x ) potential in the literature. Here we propose a mathematically consistent approach to deal with the one-dimensional version of this problem by considering from the beginning the distributional nature of the whole interaction term. We show that the interaction is univocally determined from two simple mathematical requirements on the interaction distribution, together with the physical requirement of probability flux conservation and considerations of symmetry.
We consider the one-dimensional quantum mechanical problem of defining interactions concentrated at a single point in the framework of the theory of distributions. The often ill-defined product which describes the interaction term in the Schr\"odinger and Dirac equations is replaced by a well-defined distribution satisfying some simple mathematical conditions and, in addition, the physical requirement of probability current conservation is imposed. A four-parameter family of interactions thus emerges as the most general point interaction both in the non-relativistic and in the relativistic theories (in agreement with results obtained by self-adjoint extensions). Since the interaction is given explicitly, the distributional method allows one to carry out symmetry investigations in a simple way, and it proves to be useful to clarify some ambiguities related to the so-called δ′\delta^\primeδ′ interaction.
There is much discussion in the mathematical physics literature as well as in quantum mechanics textbooks on spherically symmetric potentials. Nevertheless, there is no consensus about the behavior of the radial function at the origin, particularly for singular potentials. A careful derivation of the radial Schrödinger equation leads to the appearance of a delta function term when the Laplace operator is written in spherical coordinates. As a result, regardless of the behavior of the potential, an additional constraint is imposed on the radial wave function in the form of a vanishing boundary condition at the origin.