This Letter sets a road map towards an experimental realization of strong coupling between free electrons and photons and analytically explores entanglement phenomena that emerge in this regime. The proposed model unifies the strong-coupling predictions with known electron-photon interactions. Additionally, this Letter predicts a non-Columbic entanglement between freely propagating electrons. Since strong coupling can map entanglements between photon pairs onto photon-electron pairs, it may harness electron beams for quantum communication, thus far exclusive to photons.
Strong light-matter coupling gives rise to polaritons - hybrid excitations whose mixed photonic and matter character enables control over optical, electronic and chemical properties. This Feature Article surveys the main architectures supporting polariton formation, including photonic microcavities, plasmonic nanostructures, open cavities and metasurfaces, and outlines how inorganic semiconductors, organic aggregates and hybrid systems access strong and ultrastrong coupling. Key phenomena such as coherent dynamics, vibronic interactions, dark-state reservoirs and polariton-mediated energy and electron transport are discussed, together with the experimental and theoretical tools used to study them. We highlight examples where strong coupling modifies charge transport, energy flow and chemical reactivity, and we summarize emerging regimes, including intermediate and dark-strong coupling, that broaden the landscape of hybrid light-matter physics.