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Oxford University Press eBooks

5. The quantum world of the atom

Geoff A. Cottrell

Published Mar 28, 2019• 0 citations
Publisher

Abstract

‘The quantum world of the atom’ considers the profound discoveries of the early twentieth century that exposed the inner structure of the atom and the revolutionary new physics of quantum mechanics—the behaviour of matter on very small scales. At the microscopic level, ‘particles’ of matter resemble waves, a feature that enables us to understand the structure, stability, and properties of atoms. Key discoveries and concepts are described: the fundamental constant of nature, Planck’s constant; Heisenberg’s uncertainty principle; the Schrödinger equation; quantum tunnelling; the wavelike characteristics of microscopic particles; and the two types of particles, fermions and bosons.

DOI
10.1093/actrade/9780198806547.003.0005

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‘The quantum world of the atom’ considers the profound discoveries of the early twentieth century that exposed the inner structure of the atom and the revolutionary new physics of quantum mechanics—the behaviour of matter on very small scales. At the microscopic level, ‘particles’ of matter resemble waves, a feature that enables us to understand the structure, stability, and properties of atoms. Key discoveries and concepts are described: the fundamental constant of nature, Planck’s constant; Heisenberg’s uncertainty principle; the Schrödinger equation; quantum tunnelling; the wavelike characteristics of microscopic particles; and the two types of particles, fermions and bosons.
The Quantum theory deals with the microscopic structure of the Universe that describes the finer details of nature at the subatomic domain.To a physicist, quantum mechanics is one of the three great pillars supporting our intuition of evocative, bewildering and fascinating natural World as we continuously struggle with the inescapable strangeness of the subatomic domain as if something strange is always afoot.It is well accepted fact that quantum mechanics is a physical theory that describes the way things behave at subatomic level which is quite dazzling in its precision and explanatory power.A test of quantum electrodynamics, the oldest and best understood of the modern quantum theory that involves measuring the way an electron behaves in the vicinity of a magnetic force. Many of the technological and social changes that have revolutionized our lives have actually risen out of the fundamental theoretical research carried out with only motivation to understand the World in a better way than ever. For example, the invention of transistor actually came with the fundamental theoretical research on the Uncertainty Principle which states that the uncertainty of the position of a particle times the uncertainty of its velocity is always a constant. If we double the certainty of the position of the particle, we have to make half the certainty of its velocity and vice versa. Quantum theory is perhaps the prime example of the infinitely esoteric in the sense that it describes a World in which a particle really can be in several places at once and it moves from one place to another by exploring the entire Universe simultaneously-the theory of simultaneity. The diverse and complex Universe is actually made of a few tiny particles according to the rules of quantum theory which is so simple that can be summarized on the back of an envelope. The more we understand about the elemental nature of the Universe, the simpler it looks. We have already discovered that everything in the diverse and complex Universe is nothing but the different assemblies of atoms, and the wide variety of atoms are constructed using the three building blocks at the sub-atomic domain i.e. subatomic particles: protons, neutrons and electrons. We have also discovered that protons and neutrons ate made up of combination of three entities called quarks. And that is where things stop as far as recent discovery is concerned. But the recent progress in particle physics inspiring the quest for the ultimate unified theory of physics that can describe everything in the Universe in one go. The discovery of Boson particle certainty will revolutionaries the Newton's mass concept and gravity into whole new looks. To an optimistic point of view, we must hope the best out of the progress in physics.
The early twentieth century was a revolutionary time in the history of physics. People often think of Einstein's special theory of relativity of 1905, which changed our conceptions of time and space. But among physicists, quantum mechanics is usually regarded as an even more radical change in our thinking about the physical world. Quantum mechanics, which was developed between 1900 and 1926, began as a theory of atoms and light but has now become the framework in terms of which all basic physical theories are expected to be cast. We need quantum ideas not only to understand atoms, molecules, and elementary particles, but also to understand the electronic properties of solids and even certain astronomical phenomena such as the stability of white dwarf stars. The theory was radical in part because it introduced probabilistic behavior as a fundamental aspect of the world, but even more because it seems to allow mutually exclusive situations to exist simultaneously in a “quantum superposition.” We will see later that the possibility of quantum superposition is largely responsible for a quantum computer's distinctive advantage over an ordinary computer. The present chapter is devoted to introducing the basic principles of quantum mechanics. There are essentially four components of the mathematical structure of quantum mechanics. We need to know how to represent (i) states, (ii) measurements, (iii) reversible transformations, and (iv) composite systems. We will develop the first three in stages, starting with a very simple case – linear polarization of photons – and working toward the most general case.
Quantum mechanics deals with the behaviour of matter and light on the atomic and subatomic scale. It attempts to describe and account for the properties of molecules and atoms and their constituents--electrons, protons, neutrons, and other more esoteric particles such as quarks and gluons. Its concepts frequently conflict with common-sense notions derived from observations of the everyday world. Quantum mechanics has attracted some of the ablest scientists of the 20th century, and they have erected what is perhaps the finest intellectual edifice of the period. Quantum mechanics is concerned with phenomena that are so small-scale that they cannot be described in classical terms. The history of quantum mechanics may be divided into three main periods. The first began with Planck's theory of black-body radiation in 1900; it may be described as the period in which the validity of Planck's constant was demonstrated but its real meaning was not fully understood. The second period began with the quantum theory of atomic structure and spectra proposed by Niels Bohr in 1913. True quantum mechanics appeared in 1926, reaching fruition nearly simultaneously in a variety of forms--namely, the matrix theory of Max Born and Werner Heisenberg, the wave mechanics of Louis V. de Broglie and Erwin Schrodinger, and the transformation theory of P.A.M. Dirac and Pascual Jordan.
For over nine decades, quantum mechanics has profoundly shaped our understanding of nature, offering explanations for the stability of atoms, the formation of mole cules, the properties of materials, and phenomena such as light or radioactivity. It is essential to modern technologies—from microchips to lasers—and underpins the physics of elementary particles. Yet, despite its successes, it remains a deeply mysterious theory, confronting a central enigma: why does the quantum world behave so differently from everyday reality? Elements such as superposition and quantum entanglement—which allow particles to exist simultaneously in multiple states or remain interconnected regardless of distance—contradict classical world intuitions. This gap between microscopic and macroscopic behavior has given rise to what is known as the “measurement problem,” raising fundamental questions about the nature of reality. Diverging interpretations have led to two major schools of thought: anti-realism, promoted by Niels Bohr, which holds that reality depends on the observer and their interaction with measurement instruments; and realism, supported by Albert Einstein, which argues that quantum mechanics is incomplete and that eality exists independently of observation. Bohr’s complementary philosophy and Heisenberg’s uncertainty principle were central to the formulation of the “Copenhagen interpretation,” which became dominant in the 20th century. However, the persistent opposition of scientists like Einstein and Schrödinger inspired generations of physicists to seek a unification between quantum mechanics and relativity, culminating in new theories such as loop quantum gravity and string theory. Thus, the debate between realism and anti-realism remains alive, and philosophy continues to play a crucial role in exploring the new foundations of physics.
The development of quantum mechanics in the early twentieth century marked one of the most profound conceptual revolutions in physics. Beginning with Planck's quantization of radiation and Einstein's interpretation of the photoelectric effect, followed by Bohr's atomic model, and later formalized by Heisenberg and Schrödinger, the theory provided a new description of nature—one in which probability amplitudes replaced deterministic trajectories. Within this framework, microscopic systems such as atoms, electrons, and photons are characterized by wavefunctions and operators rather than by points in phase space.
An easy-to-understand guide to the complex subject of quantum physics. Quantum physics is how scientists describe the world of the very small. For other people, however, the rules of quantum physics seem to violate all logic: How can a particle be in more than one place at the same time? How can it tunnel through an impenetrable barrier? How can a cat in a box be both alive and dead? This book explains the complexities of quantum physics in bite-sized "lessons" that make it clear and accessible to all readers. The sections and chapters are: 1. Atoms -- quantum; quantum physics in everyday life; the periodic table; atoms and nuclei; isotopes; hydrogen atom (energy levels and spectra) 2. Photons -- photoelectric effect; thermal emission and the Planck distribution; wave particle duality (Young's slit experiment) 3. Quantum devices -- superconductors; transistor, diode; light-emitting diode; laser 4. Spin -- spin; fermions; exclusion principle; Fermi Dirac distribution; Bose-Einstein statistics 5. Wave Mechanics -- Heisenberg uncertainty principle; wave functions; standing waves; wave particle duality 6. Subatomic Particles -- radioactivity; atomic particles; protons; neutrons; electrons 7. Particle Physics -- elementary particles; quarks; leptons; electron and electron neutrino; muon and muon neutrino; tauon and tau neutrino; bosons; photon; W and Z boson; gluon; Higgs boson; composite particles; hadrons; matter-anti-matter 8. Quantum Physics in Medicine and industry -- magnetic resonance imaging; superfluidity; cancer treatment by radiation 9. Into the Future -- quantum physics of space; quantum gravity; graviton; Hawking radiation (grand unified theory); dark matter; strings; dark energy. Throughout the book, there are timelines and profiles about the scientists who developed the theories and made important discoveries in quantum physics, including Dmitri Rutherford, Albert Einstein, Heike Kamerlingh Onnes, William Shockley, Isama Akasaki, Stephen Hawking, Enrico Fermi, and Max Born.