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Review of Scientific Instruments

Manipulating hydrogen atoms using permanent magnets: Characterisation of a velocity-filtering guide

Jutta Toscano, Michal Hejduk, Henry G. McGhee, Brianna R. Heazlewood

Published Mar 1, 2019• 5 citations
Publisher

Abstract

A Halbach array composed of 12 permanent magnets in a hexapole configuration is employed to deflect hydrogen atoms as they exit a Zeeman decelerator. The ability to preferentially manipulate H atoms is very useful, as there are currently very few techniques that are appropriate for purifying a beam of H atoms from precursor molecules (such as molecular hydrogen or ammonia), seed gases, and other contaminant species. The extent to which hydrogen atoms are deflected by a single Halbach array when it is tilted or shifted off the main beam axis is characterised experimentally and interpreted with the aid of a simple mathematical model. A radical beam filter is subsequently introduced, where four Halbach arrays arranged in series serve to deflect H atoms away from the main beam axis and around skimming blades; all other components of the incoming beam are blocked by the blades and are thus not transmitted through the magnetic guide. The properties of the guide, as established by experimental measurements and complemented by detailed simulations, confirm that it is a highly effective beam filter-successfully generating a pure and velocity-selected beam of H atoms.

DOI
10.1063/1.5078573

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•Jan 1, 2014•2 citations
A Halbach array composed of 12 permanent magnets in a hexapole configuration is employed to deflect hydrogen atoms as they exit a Zeeman decelerator. The ability to preferentially manipulate H atoms is very useful, as there are currently very few techniques that are appropriate for purifying a beam of H atoms from precursor molecules (such as molecular hydrogen or ammonia), seed gases, and other contaminant species. The extent to which hydrogen atoms are deflected by a single Halbach array when it is tilted or shifted off the main beam axis is characterised experimentally and interpreted with the aid of a simple mathematical model. A radical beam filter is subsequently introduced, where four Halbach arrays arranged in series serve to deflect H atoms away from the main beam axis and around skimming blades; all other components of the incoming beam are blocked by the blades and are thus not transmitted through the magnetic guide. The properties of the guide, as established by experimental measurements and complemented by detailed simulations, confirm that it is a highly effective beam filter-successfully generating a pure and velocity-selected beam of H atoms.
Generating a controllable and pure source of molecular free-radicals or open-shell atoms has been one of the primary barriers hindering the detailed study of radical processes in the laboratory. Here, we introduce a novel magnetic guide for the generation of a pure beam of velocity-selected radicals-a tuneable source that will enable the study of radical interactions with exceptional control over the properties of the radical species. Only radicals with a selected velocity are transmitted through the guide; all other components of the incoming beam (radical species traveling at other velocities, precursor molecules, and seed gas) are removed. The guide is composed of four Halbach arrays-hexapolar focusing elements-and two skimming blades. The relative positions of these components can be adjusted to tune the properties of the resulting beam and to optimise transmission for a given velocity. Experimental measurements of Zeeman-decelerated H atoms transmitted through the guide, combined with extensive simulations, show that the magnetic guide removes 99% of H-atoms traveling outside the narrow target velocity range.
An original design of magnetic guide is presented, suitable for use with Zeeman-decelerated supersonic beams of ground-state hydrogen atoms and other light paramagnetic species. Three-dimensional particle trajectory simulations show that, by combining a series of permanent-magnet Halbach arrays with pulsed high-current wire electromagnets, this guide can be used to efficiently transmit the slow, decelerated atoms and discard the faster, undecelerated atoms and other species in the gas beam. The curved guide would be suitable for guiding hydrogen atoms into an ion trap to investigate low temperature ion-molecule collisions. It is also shown that the device could be used for the guiding or velocity selection from an undecelerated supersonic or effusive beam.
Generating a controllable and pure source of molecular free-radicals or open-shell atoms has been one of the primary barriers hindering the detailed study of radical processes in the laboratory. In this thesis, a novel source of state-selected radicals -- composed of a Zeeman decelerator interfaced with a newly-designed magnetic guide -- is introduced. This tuneable source generates a pure beam of velocity-selected hydrogen atoms that will enable the study of radical interactions with exceptional control over the properties of the radical species. In Zeeman deceleration, time-varying spatially inhomogeneous magnetic fields are used to create packets of translationally cold, quantum-state-selected paramagnetic particles with a tuneable forward velocity, which are ideal for cold reaction dynamics studies. In a proof-of-principle experiment, the Zeeman deceleration of nitrogen atoms in the metastable 2D5/2 state from 460 to 410 m/s is demonstrated for the first time. The covariance matrix adaptation evolutionary strategy (CMA-ES) is adopted in order to optimise deceleration switching sequences for the operation of a 12-stage Zeeman decelerator. Using the optimised sequences, a 40% increase in the number of decelerated H(2S1/2) atoms is observed compared to standard sequences for the same final velocity, imposing the same experimental boundary conditions. Furthermore, up to 98% of the initial kinetic energy of particles in the incoming beam is removed by the optimised sequences, compared to the removal of a maximum of 83% of kinetic energy with standard sequences. Three-dimensional particle-trajectory simulations show that the optimal solution uncovered by the evolutionary algorithm is not merely a local optimisation of the experimental parameters -- it is a new mode of operation that goes beyond the standard periodic phase stability approach typically adopted. A novel magnetic guide is designed and constructed to purify the post-deceleration beam. Only radicals with a selected velocity are transmitted through the guide; all other components of the incoming beam (radical species travelling at other velocities, precursor molecules and seed gases) are removed. The guide is composed of four Halbach arrays -- hexapolar focusing elements -- and two skimming blades. The relative positions of these components can be adjusted to tune the properties of the resulting beam and to optimise transmission for a given velocity. Experimental measurements of Zeeman-decelerated H atoms transmitted through the guide, combined with extensive simulations, show that the magnetic guide successfully removes 99% of H atoms travelling outside the narrow target velocity range.
Zeeman deceleration is a relatively new technique used to obtain full control over the velocity of paramagnetic atoms or molecules in a molecular beam. We present a detailed description of a multistage Zeeman decelerator that has recently become operational in our laboratory [Cremers et al., Phys. Rev. A 98, 033406 (2018)] and that is specifically optimized for crossed molecular beams scattering experiments. The decelerator consists of an alternating array of 100 solenoids and 100 permanent hexapoles to guide or decelerate beams of paramagnetic atoms or molecules. The Zeeman decelerator features a modular design that is mechanically easy to extend to arbitrary length and allows for solenoid and hexapole elements that are convenient to replace. The solenoids and associated electronics are efficiently water cooled and allow the Zeeman decelerator to operate at repetition rates exceeding 10 Hz. We characterize the performance of the decelerator using various beams of metastable rare gas atoms. Imaging of the atoms that exit the Zeeman decelerator reveals the transverse focusing properties of the hexapole array in the Zeeman decelerator.
Zeeman deceleration is an experimental technique which allows for the manipulation of open-shell atoms and molecules in a supersonic beam thus producing mK-cold, velocity-tunable beams of particles in selected quantum states. The method relies on the Zeeman interaction between paramagnetic particles and time-varying, inhomogeneous magnetic fields generated by pulsing high currents through an array of solenoid coils. This thesis describes the construction and implementation of a supersonic beam setup including a 12-stage Zeeman decelerator. The Zeeman decelerator follows an original design that makes it possible to replace individual deceleration coils. Using ground-state hydrogen atoms as a test system, it is shown that the transverse acceptance in a Zeeman decelerator can be significantly increased by generating a rather low, temporally varying quadrupole field in one of the solenoid coils. An electron-impact source was constructed and optimised enabling, for the first time, the Zeeman deceleration of metastable helium atoms in the 23S1 state, with an up to 40 % decrease in the kinetic energy of the beam. It is shown that the pulse duration for electron-impact excitation needs to be matched to the acceptance of the decelerator in order to attain a good contrast between the decelerated and undecelerated parts of the beam. Experimental results are rigorously analysed and interpreted using three-dimensional numerical particle trajectory simulations. A phase-space model provides, for the first time, a means to estimate the six-dimensional phase-space acceptance in a Zeeman decelerator and to find optimum parameter sets for improved Zeeman deceleration schemes. The approach also reveals a hitherto unconsidered velocity dependence of the phase stability which is ascribed mainly to the rise and fall times of the current pulses that generate the magnetic fields inside the deceleration coils. In the future, it is planned to combine the Zeeman decelerator with a source of cold atomic and molecular ions to study chemical collisions at low temperatures. A hybrid magnetic guide consisting of permanent magnet assemblies (Halbach arrays) in hexapole configuration and a set of current-carrying wires is proposed and simulated as an interface between these setups. The design promises very efficient velocity selection, a high degree of quantum-state selection and a nearly complete removal of residual carrier gas. Prospects for using magnetic hexapole focusing in front of the Zeeman decelerator are discussed. The work represents a major step towards the study and control of chemical reactivity of paramagnetic species in the low-temperature regime and it will help in the testing of fundamental chemical reaction theories.