This chapter presents a modernized version of a method originally due to Dirac. This approach depends on a straightforward expansion in powers of the perturbing interaction. The chapter examines a problem where the unperturbed Hamiltonian had a discrete spectrum, and the perturbation was explicitly time dependent. The situation where the spectrum is continuous and the perturbation is independent of time is encountered much more frequently in physics. The chapter explores the derivations of some rather general formulas for collision cross sections. The photo-effect in hydrogen constitutes a very interesting example of a perturbation problem. The dramatic behavior of the matrix element demonstrates that at low energy the Coulomb attraction is very effective in keeping the slow photo-electron near the origin. The chapter examines the result of a collision experiment. It aims to illustrate the power and limitations of the technique, and to establish its relationship to the treatment of elastic scattering.
This chapter presents a modernized version of a method originally due to Dirac. This approach depends on a straightforward expansion in powers of the perturbing interaction. The chapter examines a problem where the unperturbed Hamiltonian had a discrete spectrum, and the perturbation was explicitly time dependent. The situation where the spectrum is continuous and the perturbation is independent of time is encountered much more frequently in physics. The chapter explores the derivations of some rather general formulas for collision cross sections. The photo-effect in hydrogen constitutes a very interesting example of a perturbation problem. The dramatic behavior of the matrix element demonstrates that at low energy the Coulomb attraction is very effective in keeping the slow photo-electron near the origin. The chapter examines the result of a collision experiment. It aims to illustrate the power and limitations of the technique, and to establish its relationship to the treatment of elastic scattering.
Throughout our discussion of the general principles of quantum mechanics we have emphasized the importance of the eigenvalues and eigenfunctions of the operators representing physical quantities. However, we have seen that solving the basic eigenvalue equations determining these is often not straightforward. In the early chapters discussing the energy eigenvalue equation (or time-independent Schro¨dinger equation) for example, we found that this could often not be solved exactly and that, even when a solution was possible, it frequently required considerable mathematical analysis. Because of this, methods have been developed to obtain approximate solutions to eigenvalue equations. One of the most important of such techniques is known as time-independent perturbation theory and will be the first method to be discussed in the present chapter. Another, known as the variational principle, will be discussed later. We shall confine our discussion to the timeindependent Schro¨dinger equation, but generalization to other eigenvalue equations is quite straightforward. We shall mainly use the wave function representation, but we shall restate some of the important results in Dirac notation so that they can be readily transformed to a matrix representation if desired.
The subject of perturbation theory in non-relativistic quantum mechanics is introduced. First, perturbation theory for stationary states in the absence of degeneracy is studied. The case of nearby levels, perturbations of a one-dimensional harmonic oscillator, the occurrence of degeneracy, Stark and Zeeman effects are then described in detail. After a brief outline of the variational method, the Dyson series for time-dependent perturbation theory is derived, with application to harmonic perturbations. The Fermi golden rule is also presented. The chapter ends with an assessment of four branches of the subject: regular perturbation theory, asymptotic perturbation theory, and summability methods, spectral concentration and singular perturbations. Approximate methods for stationary states It is frequently the case, in physical problems, that the full Hamiltonian operator H consists of an operator H 0 whose eigenvalues and eigenfunctions are known exactly, and a second term V resulting from a variety of sources (e.g. the interaction with an electric field, or a magnetic field, or the relativistic corrections to the kinetic energy, or the effects of spin). The problems and aims of perturbation theory for stationary states can be therefore summarized as follows. (i) Once the domain of (essential) self-adjointness of the ‘unperturbed’ Hamiltonian H 0 is determined, find on which domain the ‘sum’ H = H 0 + V represents an (essentially) self-adjoint operator (the reader should remember from appendix 4. A that in general, once some operators A and B are given, the intersection of their domains, on which their sum is defined, might be the empty set). […]
We now consider systems for which the Hamiltonian contains time-dependent interaction terms. In such cases we cannot reduce the time-dependent Schro¨dinger equation to an eigenvalue equation. However, if the time-dependent terms can be regarded as small perturbations, we can develop a form of perturbation theory that can be used to calculate the effects of time-dependent terms. Consider a system for which the Hamiltonian may be written as the sum of a dominant unperturbed part Hˆ0 and a small perturbation Hˆ ′ as Hˆ = Hˆ0 + λHˆ ′(t) , (10.1.1) where the unperturbed Hamiltonian Hˆ0 is independent of time, whereas the perturbation Hˆ ′ may depend on time. The parameter 0 < λ < 1 has been introduced to keep track of various orders of approximations as in the case of time-independent perturbation theory discussed in Chapter 8. The basic idea is that a small perturbation to the Hamiltonian will produce a small change in the wave function. For a time-dependent perturbation, this change means that a system, initially in a particular eigenstate of Hˆ0, will find itself in a time-dependent admixture of the eigenstates. Thus the time-dependent perturbation causes the system to undergo transition to different eigenstates of Hˆ0. So for time-dependent perturbations our interest lies in calculating the probabilities for transition to different states.
Almost any of the great textbooks available on scattering theory continues to explain how a collision experiment measures scattering cross sections for different events, and relates the relevant S-matrix elements, or the scattering amplitudes (onshell T-matrix), to those cross sections. We highly recommend Taylor’s book in this respect. In this volume and the volume that will follow, however, our motivation does not lie in (although discussions can be extended to) the theoretical description of collision experiments. We are mostly interested in applications of scattering theory in few-body physics and effective interactions in few- and many-body physics. Therefore, we consider a method that is having huge success in the theoretical and numerical description of collisions in nuclear physics and quantum chromodynamics, as well as ultracold atomic and condensed matter physics recently. The method allows for an estimation of low-energy scattering parameters and binding energies from exact diagonalisation, in the low-energy sector, of the system’s Hamiltonian, and is originally due to Lüscher [2]. Lacking another term for it, we have decided to simply label this and related methods ‘modern scattering theory’.
Aims and problems of quantum scattering theory Scattering theory is the branch of physics concerned with interacting systems on a scale of time and/or distance that is large compared with the scale of the interaction itself, and it provides the most powerful tool for studying the microscopic nature of the world. In quantum mechanics, a typical scattering process involves a beam of particles prepared with a given energy and with a more or less defined linear momentum. One then studies either the collision with a similar wave packet, or the collision of the given wave packet against a fixed target. In particular, for a two-body elastic scattering problem with conservative forces, we work in the centre of mass frame, hence reducing the original problem to the analysis of a particle in an external field of forces. Indeed, in Section 7.2 we already used such a technique in the investigation of the hydrogen atom. The crucial difference with respect to Section 7.2 is that, in scattering problems, the continuous spectrum and its perturbations are studied, whereas the Balmer formula has to do with bound states. In the following section we outline the basic aspects of what is called time-dependent scattering. Time-dependent scattering The physical situation we would like to study is as follows: a beam of particles is prepared in a state that is approximately free and allowed to evolve towards the scatterer. After the collision we detect the scattered beam far away from the interaction region.
This chapter examines applications drawn from perturbation theory. The main topic in perturbation theory is the energy and spontaneous decay rate of the 21-cm hyperfine line in atomic hydrogen. Before there were electronic computers, people had quite an accurate theoretical understanding of the energy levels in helium and more complicated systems. The trick was (and is) to find approximation schemes that treat unimportant parts of a physical system in quite crude approximations while reducing the interesting parts to a problem simple enough that it is feasible to compute but yet detailed enough to yield accurate results. The approximation methods in the chapter deal with the effects of small changes in the Hamiltonian, resulting for example from the application of a static or time variable electric or magnetic field. This may cause small changes in energy levels, and it may induce transitions among eigenstates of the original Hamiltonian.