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Pramana

Mayer’s convergence and thermodynamics of ideal Bose gas

T. P. Suresh, K. M. Udayanandan, Vishnu M. Bannur

Published Feb 4, 2019• 1 citation
Publisher
DOI
10.1007/s12043-018-1699-6

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It has been shown that Mayer's theory of imperfect gases can be handled approximately as a problem in association in which the actual gas is replaced by a mixture of ideal gases consisting of clusters of all sizes and between which dissociative equilibrium exists. Kahn and Uhlenbeck have shown how Mayer's theory can be generalized to apply to quantum degenerate gases. The purpose of the present paper is to examine the clustering approximation to such a theory of the quantum degenerate Bose-Einstein gas. The symmetrized wave functions for the clustering assembly are set up and the partition function evaluated for all ways of clustering. Equations of state are deduced that include condensation into the liquid phase as a clustering avalanche at the saturation pressure. It is found that clustering has the effect of lowering the lambda-temperature due to statistical degeneracy right down to the saturated vapor line, so that the lambda-transition is entirely inhibited from the gas phase.
We study a system of a heavy quantum particle, from now on called tracer particle, coupled to an ideal gas of NNN light Bose particles with a ratio between the masses of the tracer particle and of a gas particle being proportional to the gas particle density. While all particles obey the non-relativistic dispersion relation, the tracer particle is also driven by an external potential and couples to the gas particles through a pair potential. We compare the corresponding quantum dynamics to effective dynamics, given by a Newtonian equation for the tracer particle and a corresponding effective equation for the Bose gas. We quantify the closeness of these two dynamics depending on the gas particle density and the volume of the support of their wave function. The provided estimates are such that we get convergence in any limit taking the density and the volume to infinity. In particular, they allow to interchange the thermodynamic with the mean field limit.