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CRC Press eBooks

Classical and quantum scattering

C. A. Bertulani, Paweł Danielewicz

Published Jan 4, 2019• 0 citations
Publisher

Abstract

Figure 1.1 represents schematically a typical scattering experiment, in fact this is the sketch of E. Rutherford experiment in 1910 [ 1 ]. Projectiles (here, α -particles) from a source go through a collimator and collide with a target (gold foil in Rutherford’s experiment). Some projectiles are scattered by the target and reach the detector (here, a fluorescent screen). Rutherford expected them to go straight through with perhaps a minor deflection. Most did go straight through, but to his surprise some particles bounced directly off the gold sheet! What did this mean? Rutherford hypothesized that the positive alpha particles had hit a concentrated mass of positive particles, which he termed the nucleus. We shall describe the Rutherford scattering theoretically later in this chapter.

DOI
10.1201/9781315274577-1

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Figure 1.1 represents schematically a typical scattering experiment, in fact this is the sketch of E. Rutherford experiment in 1910 [ 1 ]. Projectiles (here, α -particles) from a source go through a collimator and collide with a target (gold foil in Rutherford’s experiment). Some projectiles are scattered by the target and reach the detector (here, a fluorescent screen). Rutherford expected them to go straight through with perhaps a minor deflection. Most did go straight through, but to his surprise some particles bounced directly off the gold sheet! What did this mean? Rutherford hypothesized that the positive alpha particles had hit a concentrated mass of positive particles, which he termed the nucleus. We shall describe the Rutherford scattering theoretically later in this chapter.
There are several ways of gathering experimental evidence about microscopic systems. Spectral analysis gives information about the bound states of the system, while scattering experiments probe their inner structure. Rutherford's pioneering alpha scattering experiments yielded the first glimpse into the structure of atoms. Such experiments opened the door to modern collider experiments, allowing us to peer deeper into the structure of matter. In this chapter, we will study only elastic collisions, in which the nature of the scattered particles does not change. This is expected for low energies in the non-relativistic regime. We first introduce the concept of cross-section and then study two complementary approaches to scattering: the Born approximation, which is suitable when the energy of the incoming particles is high in comparison with the potential energy of the target, and the partial waves method, which applies best when the two energies are comparable.
Most of our knowledge about the structure of matter and interaction between particles is derived from scattering experiments. From a theoretical point of view, scattering problems are concerned with the continuous (and positive) energy eigenvalues and unbound eigenfunctions of the Schro¨dinger equation. We have already encountered one-dimensional examples of scattering in Chapter 4, in the discussion of reflection and transmission of an incident particle with definite momentum from a potential step or barrier. In this chapter we consider scattering from a more formal point of view. We will confine our discussion to elastic scattering (scattering without loss or gain of energy by the projectile) from central potentials although many of the concepts and results are applicable to inelastic scattering.
In 1897, Thomson demonstrated that cathode rays (observed to be emitted from the cathodes of vacuum tubes) were in fact charged particles which he called electrons. Thomson proposed that the atom consisted of a positively charged sphere in which were embedded negatively charged electrons. Rutherford subsequently found in 1911 that the electrons orbited at some distance from a central positively charged nucleus. Rutherford proposed that electrostatic attraction between the nucleus and the electron was balanced by the centrifugal force arising from the orbital motion. However, if this were the case, then the electrons (being accelerated inwards towards the center of rotation) would continuously radiate all their energy as electromagnetic waves and very quickly fall into the nucleus. In 1913, Bohr postulated two important additions to Rutherford’s theory of atomic structure: 1. Electrons can orbit the nucleus in what are called stationary states in which no emission of radiation occurs and in which the angular momentum L is constrained to have values: 2. Electrons can make transitions from one state to another accompanied by the emission or absorption of a single photon of energy E = hf thus leading to absorption and emission spectra.
Quantum Rutherford scattering and scattering of classical waves off Coulomb-like potentials have similar formal structures and can be studied using the same mathematical techniques. In both contexts, the long-range nature of the interaction leads to a divergent total cross-section, which has been interpreted and regularized in various ways in the past literature. We review in detail the origin of this divergence, in both real and multipole spaces, and show that it arises from incorrectly using approximations out of their domain of validity. We also stress that although classical and quantum Rutherford scattering share the same formalism, the natures of the associated physical observables differ. We comment on the role of interference: while interference can be safely neglected in a quantum context (due to the fact that the observable quantity is a flux, and the incoming flux is collimated), in a classical context one expects to see a superposition of transmitted and scattered waves in a broad region downstream of the target, hence a cross-section is not connected to any physically observable quantity.
The interaction between incident and target particles is inferred from the numbers and angular distribution of scattered particles and from their energy distribution. It is important to recognize that a scattering region, as represented for example by a rectangular barrier, is a region where, in classical terms, forces are applied to the incident particles. A full analysis of scattering events must, in principle, embody the description of a localized free particle that travels toward a center of force and is scattered by it. Quantum-mechanically, that implies a theoretical analysis in terms of packet states, with an explicit account of their change of position with time. One of the most striking effects described by quantum mechanics is the transmission of incident particles across a potential barrier whose height is greater than the particle energy. Classically, these particles lack the energy to get over the barrier, yet for quantum-mechanical systems some fraction of incident particles are transmitted.
Chapter 18 is entirely devoted to the quantum theory of scattering, which is normally covered in more detail in a course on quantum field theory. We introduce the main concepts, including scattering amplitude, differential and total cross sections, and form factors, and derive the main formulas for elastic scattering, in a nonrelativistic framework; this allows us to appreciate how the information obtained from scattering experiments is used to explore the intricacies of quantum particles that are otherwise inaccessible. The Born approximation is studied and applied to scattering by a periodic potential, a weak potential, and Rutherford scattering. The partial wave expansion is derived and applied to obtain the optical theorem. The chapter concludes with a complementary section on resonant scattering.