In this thesis, we introduce new methodologies for the visualization, evaluation, and optimal control of spin systems based on four publications appended in Appendix A -D. Essential parts are established on the DROPS representation, a phase-space method which exploits generalized Wigner functions, denoted as droplets, to represent and visualize quantum systems.In the first publication "Wigner tomography of multispin quantum states" in Appendix A, a general sampling theorem for spherical functions is derived.This is evolved to a novel Wigner quantum state tomography: A technique to reconstruct the surface of the droplets representing quantum states by measuring expectation values of rotated axial tensor operators.This concept is extended in the second publication "Wigner process tomography: Visualization of spin propagators and their spinor properties" in Appendix B to experimentally recover the phase space representation of propagators by mapping these operators to density matrices of an augmented system with an additional ancillar qubit and by applying a modified form of the Wigner quantum state tomography.Both techniques are experimentally demonstrated for quantum states of systems up to three qubits and for standard 1 qubit gates using nuclear magnetic resonance spectroscopy.In doing so, the droplets are associated to measurable quantities, which were originally the mere result of an abstract mathematical mapping, and an interpretation in form of multipoles is provided.Those tomography schemes can be regarded as universally applicable validation methods for quantum systems.They are particularly well suited for the characterization of spin operators, pulse sequence elements, or entire pulse sequences in spectroscopy and in quantum information processing.In a third publication "Symmetry-adapted decomposition of tensor operators and the visualization of coupled spin systems" in Appendix C, the concept of the DROPS representation, which is in its original form restricted to systems of up to four spins 1/2 due to computational challenges, is generalized to any number of coupled spins 1/2 and to two coupled spins with arbitrary spin numbers.These obstacles are circumvented by extending and introducing two different approaches based on explicit projection operators and coefficients of fractional parentage.This results in a powerful and versatilely applicable visualization tool for the analysis of highly diverse spin topologies and paves the way for the Wigner tomography schemes in such quantum systems.This thesis is complemented by proposing novel optimal control strategies, which, combined with the previous techniques, provide a rich toolbox for the control, analysis, and verification of spin systems.In a last publication "Linking the rotation of a rigid body to the Schrödinger equation: The quantum tennis racket effect and beyond" in Appendix D, efficient and robust control strategies are introduced by linking the free rotation of a classical rigid body to the control of two-level quantum systems using external electromagnetic fields.In the case of state to state transfer and gate implementation, a new class of optimal controls is derived.This relies on two free parameters and allows for a variable efficiency, time, and robustness of the transfer process.An experimental demonstration is presented using techniques of nuclear magnetic resonance.
We study the tomography of propagators for spin systems in the context of finite-dimensional Wigner representations, which completely characterize and visualize operators using shapes assembled from linear combinations of spherical harmonics. The Wigner representation of a propagator can be experimentally recovered by measuring expectation values of rotated axial spherical tensor operators in an augmented system with an additional ancilla qubit. The methodology is experimentally demonstrated for standard one-qubit quantum gates using nuclear magnetic resonance spectroscopy. In particular, this approach provides a direct and compelling visualization of the spinor property of the propagators corresponding to the rotation of a spin-1/2 particle.
We study the tomography of multispin quantum states in the context of finite-dimensional Wigner representations. An arbitrary operator can be completely characterized and visualized using multiple shapes assembled from linear combinations of spherical harmonics [A. Garon, R. Zeier, and S. J. Glaser, Phys. Rev. A 91, 042122 (2015)]. We develop a general methodology to experimentally recover these shapes by measuring expectation values of rotated axial spherical tensor operators and provide an interpretation in terms of fictitious multipole potentials. Our approach is experimentally demonstrated for quantum systems consisting of up to three spins using nuclear magnetic resonance spectroscopy.
The first part of this thesis focuses on the problem of visualization of quantum systems. We develop a method to visualize any operators in these systems, based on a generalization of Wigner representations. We demonstrate its intuitive character by illustrating a series of concepts in NMR spectroscopy for systems consisting of two spin-1/2 particles.
The second part is concerned with a problem of optimal control, where the problem of creating a propagator in the shortest amount of time is considered.
Abstract We present an experimental scanning-based tomography approach for near-term quantum devices. The underlying method has previously been introduced in an ensemble-based NMR setting. Here we provide a tutorial-style explanation along with suitable software tools to guide experimentalists in its adaptation to near-term pure-state quantum devices. The approach is based on a Wigner-type representation of quantum states and operators. These representations provide a rich visualization of quantum operators using shapes assembled from a linear combination of spherical harmonics. These shapes (called droplets in the following) can be experimentally tomographed by measuring the expectation values of rotated axial tensor operators. We present an experimental framework for implementing the scanning-based tomography technique for circuit-based quantum computers and showcase results from IBM quantum experience. We also present a method for estimating the density and process matrices from experimentally tomographed Wigner functions (droplets). This tomography approach can be directly implemented using the Python-based software package .
Abstract We study the representation and visualization of finite-dimensional, coupled quantum systems. To establish a generalized Wigner representation, multi-spin operators are decomposed into a symmetry-adapted tensor basis and are mapped to multiple spherical plots that are each assembled from linear combinations of spherical harmonics. We explicitly determine the corresponding symmetry-adapted tensor basis for up to six coupled spins 1/2 (qubits) using a first step that relies on a Clebsch–Gordan decomposition and a second step which is implemented with two different approaches based on explicit projection operators and coefficients of fractional parentage. The approach based on explicit projection operators is currently only applicable for up to four spins 1/2. The resulting generalized Wigner representation is illustrated with various examples for the cases of four to six coupled spins 1/2. We also treat the case of two coupled spins with arbitrary spin numbers (qudits) not necessarily equal to 1/2 and highlight a quantum system of a spin 1/2 coupled to a spin 1 (qutrit). Our work offers a much more detailed understanding of the symmetries appearing in coupled quantum systems.
This thesis addresses aspects of quantum phase and sets out to draw attention to a collection of new and extend some not so new techniques utilizing Weyl's correspondence rule and its inverse. The phase formulation of quantum mechanics is as old as quantum mechanics itself and evolved over a period of two decades due to the contributions of H. Weyl \cite{Weyl1950}, E. P. Wigner \cite{Wigner1932}, H. Groenewold \cite{Groenewold1946} and J. E. Moyal \cite{Moyal1949}. Over the ensuing years the phase picture has matured into a practical analytical tool, and has generated a multitude of technical papers, reports, reviews, and expositions from many authors and commentators. One reason for its success is that it offers an intuitive picture of quantum mechanics owing to its \it{classical look and feel}, and it has made an impression, in one way or another, in many fields such as mathematical physics, quantum optics, and physical chemistry.The thesis opens with a brief history of classical phase space, tracing the possible origin of the term ``phase space itself, and chronicles the events leading to the conceptualization (and generalization) of quantum phase space. In Chapter 2 the Weyl correspondence is recast in terms of von Neumann's integral kernel transform and a heuristic analysis is given from this perspective. A characteristic of Weyl's correspondence rule and its inverse is that there are two inherent representations of the same operator. These have been referred to as the Weyl representation and Wigner representation and are related by a symplectic Fourier transform. For an arbitrary outer dyadic operator it is shown that the Weyl representation leads to the \it{modified} Gabor transform (known to Signal Processing), while the Wigner representation specializes to the Bargmann transform and a representation in terms of analytic functions. Calculating Weyl-Wigner (WW) transforms of products of
n operators, from first principles, has proved to be a technically difficult problem. However, with the machinery developed in Chapter 2 the problem is reduced to a straightforward algebraic exercise. Finally, forming an
s-parametrized generalization of Weyl's correspondence rule and focusing on the Weyl representation it is shown to lead to an intimate relationship with the relative state formalism \cite{Ban1998}. Weyl's correspondence rule is only applicable to operators and consequently state vectors
∣ψ⟩ are not represented in the usual formulation of quantum phase space. This problem is circumvented in Chapter 3 by introducing the notion of a normalized fixed state (or window) vector
∣φ0⟩ to form an outer dyadic product $\wh{\Psi} = |\psi\rangle\langle\varphi_0|$. The WW transform of this product under the action of the Weyl's rule is a complex valued function of real variables called a phase amplitude and denoted by the symbol
Ψ. The phase amplitudes have many (and sometimes surprising) properties. For example they: \begin{itemize} \item form the building blocks of Wigner functions
W by admitting a generalized Born rule
W=Ψ⋆Ψˉ, and as such can be considered to be a more fundamental objects than Wigner functions; \item superpose and interfere like the state vectors they represent; \item specialize to the Bargmann and Gabor transforms when a Gaussian window is chosen; \end{itemize} \ni In Chapter 4 further aspects of phase amplitudes are explored and discussed. For example it is shown that they: \begin{itemize} \item define phase state vectors which form an over complete set and are elements of a reproducing kernel Hilbert space; \item allow unitary ray representations of the group symmetries of translation, rotation and time reversal; \item evolve in phase under the influence of a propagator
R which is intimately related to the Wigner propagator
P. \end{itemize} Chapter 5 considers an extension of phase amplitudes to include systems with finitely many degrees of freedom. These are called spin amplitudes and are obtained by first forming the outer dyadic product of a spin state vector with an arbitrary fixed spin state vector, and then applying a finite-dimensional analogue of the WW transform. The spin amplitude operator is represented as an
n×n matrix, whose elements are products of the spin components of the spin and fixed state vectors. Two kinds of spin amplitudes are considered, arising on the sphere
S2 or on a
(2j+1) dimensional lattice. In the special case of spin-$\half$ systems it is shown that the spin amplitudes transform as spinors under rotations on both the sphere and lattice. As a physical application the spin amplitudes for a spin-$\half$ magnetic dipole are found for a Nuclear Magnetic Resonance (NMR) environment. Chapter 6 considers Schwinger's abstract approach to quantum mechanics which takes into account the inability to indefinitely compensate for fluctuations in the measurement process. The resulting measurement algebra provides a symbolic representation of the physical laws as opposed to the mathematical abstraction (of von Neumann and Dirac) that was justified \it{\'a posteriori} by being in agreement with experiment. Despite Schwinger's prolific work on the subject of measurement algebra, its interpretation in quantum phase remained an open issue. It is shown that the key to formulating a quantum phase in terms of the measurement operators and transformation functions is the determination of a suitable set of basis operators for an arbitrary measurement operator. Many new results follow as a consequence of expanding an arbitrary measurement operator in this basis. In Chapter 7 the quantum-classical interface is explored by considering Hamilton's principal function or action
S(q,v,t). Starting from a purely heuristic classical argument, a phase function
U(p,q,t) is derived in terms of the classical action and is shown to be proportional to the WW transform of the quantum evolution operator. This association leads to the transform \be U(p,q,t) = A(t) \int e^{ipv/\hbar} e^{iS(q,v,t)/\hbar} \; \rm{d}v, \ee which enables one, in principle, to deduce the Wigner functions of a given system when only the classical action is known. Simple physical systems are used to provide examples illustrating this approach.