Interaction of Radiation with Matter: Absorption, Emission, and Lasers

Helen S. Freedhoff

Axel Donges, Reinhard Noll

Г. М. Ермолаева, В. А. Смирнов, В. Б. Шилов

This paper discusses how the degree of coherence of intense resonance radiation affects the evolution process of collective photoinduced luminescence, which determines the absorption-emission dynamics in concentrated molecular systems. It is shown that the partial breakdown of coherence reduces the radius of the volume in which effective collective interaction occurs in the field-matter system and in which the relative role of classical mechanisms in the absorption-emission cycle increases.

Murray, Iii Sargent

The phenomena which are principally responsible for the interaction of radiation with matter in everyday life are absorption and spontaneous emis­ sion. Light falling on matter is absorbed, leaving atoms in excited states which spontaneously emit radiation with a spread of frequency inversely proportional to the decay time. The situation is modified when the atomic decay times are sufficiently long and the radiation sufficiently intense, for then radiation may fall on excited atoms, resulting in stimulated emission rather than absorption. We saw in Chap. 2 that this third process was required to obtain the Planck blackbody radiation law in Einstein’s derivation. It is stimulated emission which enables an atomic medium to amplify incident radiation, and therefore is an essential ingredient in light amplifiers and oscillators. In fact, the word LASER is an acronym for Light Amplification by Stimulated Emission of Radiation.

H. Baltes, A. Quattropani, Pierre Meystre

W. A. Tiefenbrunner

In 1916, A. Einstein developed a model of the absorption and emission of radiation from which he derived M. Planck’s radiation law. He postulated light-induced (stimulated) emission, because within the framework of classical physics an oscillator can, depending on the phase difference, both extract energy from the electromagnetic field and transfer energy to it. In a non-coherent field, α = β should hold, where α denotes the kinetic constant of absorption and β that of stimulated emission. This assumption is indispensable for deriving the radiation law from his model. In this context, it is problematic that a certain degree of field coherence follows necessarily from his model, which implies that α ≠ β. Moreover, the model cannot readily be generalised to fields of arbitrary coherence. An alternative model for the absorption and emission of radiation by matter is therefore developed here. On the one hand, it is based on the assumption that, within a blackbody, quanta of different energies may recombine freely; on the other hand, it employs the “pairwise interference model of quantum theory” (PIMOQ). The alternative model of the interaction between light and matter allows the radiation law to be derived for thermal equilibrium in a non-coherent field, under which conditions, according to the model, no stimulated emissions occur. It also describes the behaviour of systems with a coherent field (interference experiment, laser). Furthermore, considerations are presented regarding the energy distribution within a blackbody and the explanatory scope of A. Einstein’s model in this respect.