Quantum Langevin approach to cavity quantum electrodynamics with molecules

Michael Reitz, Christian Sommer, Claudiu Genes

Published Dec 20, 2018• 0 citations

Abstract

We investigate the interaction between light and molecular systems modeled as quantum emitters coupled to a multitude of vibrational modes via a Holstein-type interaction. We follow a quantum Langevin equations approach that allows for analytical derivations of absorption and fluorescence profiles of molecules driven by classical fields or coupled to quantized optical modes. We retrieve analytical expressions for the modification of the radiative emission branching ratio in the Purcell regime and for the asymmetric cavity transmission associated with dissipative cross-talk between upper and lower polaritons in the strong coupling regime. We also characterize the Forster resonance energy transfer process between donor-acceptor molecules mediated by the vacuum or by a cavity mode.

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